Intercomparison study of sensitivities from commercial OSL readers and a newly developed OSL reader.

In this study, we compared the sensitivities of a newly designed OSL system with two commercial systems, performing OSL readouts of Al2O3:C irradiated with doses ranging from mGy to a few Gy. It is our first prototype, and we used a cluster of three blue LEDs (5 W each and approximately wavelength 450 nm) for the optical stimulation in the modes continuous wave (CW-OSL) and pulsed (POSL). The detection window used a bandpass filter, allowing the detection of OSL signal with a wavelength shorter than 360 nm. For detection, we have a photodetector module with a photomultiplier tube. We compared the readouts with commercial readers, respecting each reader's different characteristics, which present different wavelengths for optical stimuli (blue and green, respectively) in CW-OSL and POSL modes. The obtained results concluded that the developed reader could be applied for OSL readouts of detectors exposed to a few hundred of mGy in POSL mode and high doses (up to a few Gy) in CW-OSL mode.

Silver nanoparticles nucleated in NaOH-treated halloysite: a potential antimicrobial material.

Despite all recent advances in medical treatments, infectious diseases remain dangerous. This has led to intensive scientific research on materials with antimicrobial properties. Silver nanoparticles (Ag-NPs) are a well-established solution in this area. The present work studied the nucleation of silver on halloysite substrates modified by chemical treatment with NaOH. The resulting stabilized Ag-NPs were characterized by X-ray diffraction, transmission electron microscopy, and energy-dispersive X-ray spectroscopy. The nucleation was characterized by thermogravimetric analysis and differential scanning calorimetry. The antimicrobial properties of the Ag-NPs were investigated against E. coli and S. aureus. The potential of the Ag-NPs for industrial application was tested by dispersing them into low-density polyethylene. The importance of the chemical affinity between matrix and additive was tested through coating the Ag-NPs with dodecanethiol, a non-polar surfactant. The resulting composites were characterized by scanning electron microscopy and in terms of surface antimicrobial activity. The results demonstrate that the Ag-NPs synthesized in this work are indeed antimicrobial, and that it is possible to imbue a polymeric matrix with the antimicrobial properties of Ag-NPs.

Promoting a Significant Increase in the Photoluminescence Quantum Yield of Terbium(III) Complexes by Ligand Modification.

Two discrete mononuclear complexes, [Tb(bbpen)(NO3)] (I) and [Tb(bbppn)(NO3)] (II), for which H2bbpen = N,N'-bis(2-hydroxybenzyl)-N,N'-bis(pyridin-2-ylmethyl)ethylenediamine and H2bbppn = N,N'-bis(2-hydroxylbenzyl)-N,N'-bis(pyridin-2-ylmethyl)-1,2-propanediamine, were synthesized and characterized by FTIR, Raman, and photoluminescence (PL, steady-state and time-resolved modes) spectroscopy. The attachment of a methyl group to the ethylenediamine portion of the ligand backbone differentiates II from I and acts as a determining feature to both the structural and optical properties of the former. The single-crystal X-ray structure of H2bbppn is described here for the first time, while that of complex II has been redetermined in the monoclinic C2 space group in light of new diffraction data. In II, selective crystallization leads to spontaneous resolution of enantiomeric molecules in different crystals. Absolute emission quantum yields (ϕ) and luminescence excited-state lifetimes (at room temperature and 11 K) were measured for both complexes. Despite their similar molecular structures, I and II exhibit remarkably different ϕ values of 21 ± 2% and 67 ± 7%, respectively, under UV excitation at room temperature. Results of quantum-mechanical (DFT and TD-DFT) calculations and experimental PL measurements also performed for H2bbpen and H2bbppn confirmed that both ligands are suitable to work as "antennas" for TbIII. Considering the 5D4 lifetime profiles and the significantly higher absolute quantum yield of II, it appears that thermally active nonradiative pathways present in I are minimized in II due to differences in the conformation of the ethylenediamine bridge.

High-resolution parameter space of an experimental chaotic circuit.

A high-resolution codimension-two parameter space showing the abundance of complex periodic structures of an experimental chaotic circuit is reported. Such resolution was propitiated by the use of a 0.5 mV step dc voltage source as one of the control parameters. Those complex periodic structures organize themselves in a period-adding bifurcation cascade that accumulates in a chaotic region. Numerical investigations on the dynamical model were also carried out to corroborate several new features observed in the experimental high-resolution parameter space.