Novel decorated aluminium(iii) phthalocyanine complex with the application of MWCNTs on electrodes: electrochemical non-enzymatic oxidation and reduction of glucose and hydrogen peroxide.

In this study, we performed the physicochemical and electrochemical characterization of a decorated macrocyclic aluminium(iii) phthalocyanine complex (AlTMQNCAPc). Subsequently, the AlTMQNCAPc@MWCNT/GC electrode was used for the electrochemical detection of glucose and hydrogen peroxide (H2O2) by cyclic voltammetry (CV), differential pulse voltammetry (DPV), and chronoamperometry (CA). Moreover, the limit of detection, linear range, and sensitivity for glucose and H2O2 were investigated (CV: 2.5 nM L-1 and 25 nM L-1, 50-500 µM, 0.052 and 0.072 µA µmol cm-2; DPV: 3.1 nM L-1 and 18 nM L-1, 50-500 µM, 0.062 and 0.066 µA µmol cm-2 and CA: 10 nM L-1 and 20 nM L-1, 50-500 µM, 0.098 and 0.07 µA µmol cm-2, respectively). In addition, the AlTMQNCAPc@MWCNT/GC electrode showed good selectivity for the detection of glucose and H2O2 in the presence of common interfering substances, such as AA, DA, UA, glycine, l-cysteine, nitrite, Pb(ii), Cd(ii), Cu(ii), Co(ii), Hg(ii), Zn(ii), and glucose. For the detection of glucose and H2O2, the kinetic parameters, including the electron transfer coefficient and catalytic reaction rate constant, were also established. Finally, for usage in practical applications, the modified electrode was employed to achieve the quantitative detection of glucose and H2O2 in human urine and commercial samples of 3% H2O2, respectively.

Fabricate, advancement, molecular docking and DNA reactivity of preferred divalent metal(II) complexes attributing (E)-N'-((6-hydroxybenzo[d]oxazol-5-yl) methylene)isonicotinohydrazide.

A series of metal(II) complexes (M=Co (II), Ni(II) and Cu(II)) supported by Schiff base ligand (L=(E)-N'-((6-hydroxybenzo[d]oxazol-5-yl)methylene)isonicotinohydrazide) has been designed and developed from condensation of 6-hydroxybenzo[d]oxazole-5-carbaldehyde and isoniazid. The ligand (H2L) and its metal(II) complexes were structurally characterized utilizing a variety of physicochemical and spectroscopic approaches. The study shows that Schiff bases (H2L) act as monobasic tridentate ONO ligand and conform to octahedral geometry according to the general formula [M(HL)2]. Furthermore, the interaction of these complexes with CT-DNA was investigated at pH = 7.2, utilizing UV-visible absorption, and viscosity measurement. In order to determine the mechanism of binding of the metal(II) complexes to the B-DNA dodecamer, docking studies were conducted using an AutoDock Vina 1.2.0 tool. The photo induced cleavage reveals that the ligand (H2L) and its complexes have UV-visible photo nuclease properties against pUC19 DNA by agarose gel electrophoresis technique. Studies showed that the complexes evaluated firmly bind to CT-DNA via intercalative mode and provides a distinctive pattern of DNA binding.

Novel Schiff base cobalt(ii) phthalocyanine with appliance of MWCNTs on GCE: enhanced electrocatalytic activity behaviour of α-amino acids.

A novel tetra-4-{(E)-[(8-aminonaphthalen-1-yl)imino]methyl}-2-methoxyphenol Co(ii) phthalocyanine (CoTANImMMPPc) was synthesized using a precursor protocol and characterized via electroanalytical and spectroscopic techniques. The FT-IR spectra of the synthesized compounds showed significant peaks corresponding to the functional groups of the precursors and phthalocyanine (Pc) compound. The mass and NMR spectra confirmed the formation of the target precursor compounds. A film of CoTANImMMPPc was deposited on the surface of an electrode and applied for the detection and monitoring of l-alanine and l-arginine. The cyclic voltammetric studies of l-alanine and l-arginine using the (CoTANImMMPPc/MWCNTs/GC) electrode showed a linear response in the range of 50-500 nM and the limit of detection was found to be 1.5 and 1.2 nM, respectively. Differential pulse voltammetry and chronoamperometry showed that the catalytic response for l-alanine and l-arginine is in the range of 50-500 nM with an LoD of 1.8 and 2.3 nM, respectively. The oxidation-active CoTANImMMPPc film significantly enhanced the current response in the chronoamperometric method and displayed a selective and sensitive response towards l-alanine and l-arginine in the presence of various other bio-molecules. The developed electrode showed good working stability and was applied for the analysis of real samples, which yielded satisfactory results. Therefore, CoTANImMMPPc-MWCNTs/GCE shows good analytical performance, is economical and produced via a simple synthetic method and can be applied as a sensor for the detection of l-alanine and l-arginine.

Recent Advances in Synthesis and Properties of Hybrid Halide Perovskites for Photovoltaics.

The progress made by the scientific community in emerging photovoltaic technologies over the past two decades has been outstanding. Numerous methods have been developed for the preparation of hybrid organic-inorganic perovskite solar cells. The power conversion efficiency has been up to 14% by a one-step vacuum deposition technique. A serious concern is the toxicity of the materials. In this review, several methods aimed at resolving these problems to some extent have been compiled, including eco-friendly synthesis. Further efficiency enhancements are expected following optimization, and a better fundamental understanding of the internal electron charge transfer, electron-hole diffusion to the corresponding layers, flexibility, and stability-dependent bandgaps is reported. This paper explores the green synthesis of organic-inorganic perovskites for industrialization. Concerning the above facts, a simple low-cost model called "dispersed photovoltaic cells" is presented.