Potassium-based emulsifying salts in processed cheese: A rheological, textural, tribological and thermal approach.

The aim of the study was to investigate the impact of potassium-based emulsifying salts (ES; 2% wt/wt concentration) with different phosphate chain lengths [dipotassium hydrogenphosphate (K2HPO4; DKP), tetrapotassium diphosphate (K4P2O7; KTPP), pentapotassium triphosphate (K5P3O10; TKPP)] on the physicochemical, viscoelastic, textural, tribological, thermal, and sensory properties of processed cheese (PC; 40% wt/wt dry matter, 50% wt/wt fat in dry matter) during a 60d storage period (6 ± 2°C). On the whole, the hardness of all PC samples increased with the increasing chain length of ES (DKP < TKPP < KTPP) and the prolonging storage period. Moreover, the hardness results were in accordance with those of the rheological analysis. All PC samples exhibited a more elastic character (G' > G"; tan δ < 1). The type of potassium-based ES affected the binding of water into the structure of the PC. Furthermore, the study confirmed that the manufactured PCs received optimal sensory scores, without any excessive bitterness. It could be concluded that the type of applied ES and storage length affected the functional properties of PC. Finally, the information provided in this study could serve as a tool for the dairy industry to help appropriately select potassium-based ES for PC manufacture with desired properties.

Microencapsulation of zinc plating waste using silicone polymers.

This paper deals with the treatment of hazardous zinc-bearing waste using hydraulic binders and silicone polymers, with the aim to allow its safe disposal into landfill. The waste was solidified using hydraulic binders in the first step and then encapsulated using silicone polymers. Samples were characterised using x-ray fluorescence, x-ray diffraction, and scanning electron microscopy. The effectiveness of the process was evaluated by leaching tests in distilled water and in an acidic environment according to Toxicity Characteristic Leaching Procedure. The effect of porosity and pH on the release of pollutants was also studied. Zinc and chloride were identified as the most significant pollutants in the waste. Portland cement did not stabilize them efficiently. The two-step treatment with Portland cement and silicone binders decreased, in the best case, the concentration of zinc and chloride in acidic extracts from 12,400 mg/L and 38,300 mg/L to 21.9 mg/L and 74 mg/L, respectively, and the treated waste complied with regulatory requirements for hazardous waste disposal into landfills. The two-step treatment was also found as a more effective method than microencapsulation using a silicone binder alone. The factor that most affects leachability appears to be the porosity of the encapsulated waste.

Stabilization/solidification of hot dip galvanizing ash using different binders.

This study focuses on solidification of hot dip-galvanizing ash with a high content of zinc and soluble substances. The main purpose of this paper is to immobilize these pollutants into a matrix and allow a safer way for landfill disposal of that waste. Three different binders (Portland cement, fly ash and coal fluidized-bed combustion ash) were used for the waste solidification. Effectiveness of the process was evaluated using leaching test according to EN 12457-4 and by using the variance analysis and the categorical multifactorial test. In the leaching test, four parameters were observed: pH, zinc concentration in leachate, and concentration of chlorides and dissolved substances in leachate. The acquired data was then processed using statistical software to find an optimal solidifying ratio of the addition of binder, water, and waste to the mixture, with the aim to fulfil the requirement for landfill disposal set by the Council Decision 2003/33/EC. The influence on the main observed parameters (relative amount of water and a binder) on the effectiveness of the used method and their influence of measured parameters was also studied.