1.
RSC Adv
; 11(10): 5451-5455, 2021 Jan 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35423092
RESUMO
We report a method for addition of α-bromophenylacetic acids to vinyl C[double bond, length as m-dash]C bonds in styrenes to afford γ-lactones. Reactions employed a simple cobalt catalyst Co(NO3)2·6H2O in the presence of dipivaloylmethane (dpm) ligand. Many functionalities including halogen, ester, and nitro groups were compatible with reaction conditions. If α-bromoesters were used, vinylacetates were the major products.