Correction: Borinelli et al. VOC Emission Analysis of Bitumen Using Proton-Transfer Reaction Time-Of-Flight Mass Spectrometry. Materials 2020, 13, 3659.

The authors wish to make the following corrections to this paper [...].

Physicochemical and Rheological Properties of a Transparent Asphalt Binder Modified with Nano-TiO2.

Transparent binder is used to substitute conventional black asphalt binder and to provide light-colored pavements, whereas nano-TiO2 has the potential to promote photocatalytic and self-cleaning properties. Together, these materials provide multifunction effects and benefits when the pavement is submitted to high solar irradiation. This paper analyzes the physicochemical and rheological properties of a transparent binder modified with 0.5%, 3.0%, 6.0%, and 10.0% nano-TiO2 and compares it to the transparent base binder and conventional and polymer modified binders (PMB) without nano-TiO2. Their penetration, softening point, dynamic viscosity, master curve, black diagram, Linear Amplitude Sweep (LAS), Multiple Stress Creep Recovery (MSCR), and Fourier Transform Infrared Spectroscopy (FTIR) were obtained. The transparent binders (base and modified) seem to be workable considering their viscosity, and exhibited values between the conventional binder and PMB with respect to rutting resistance, penetration, and softening point. They showed similar behavior to the PMB, demonstrating signs of polymer modification. The addition of TiO2 seemed to reduce fatigue life, except for the 0.5% content. Nevertheless, its addition in high contents increased the rutting resistance. The TiO2 modification seems to have little effect on the chemical functional indices. The best percentage of TiO2 was 0.5%, with respect to fatigue, and 10.0% with respect to permanent deformation.

VOC Emission Analysis of Bitumen Using Proton-Transfer Reaction Time-Of-Flight Mass Spectrometry.

Bitumen is one of the most important materials used in roads. During asphalt pavement construction, workers can be affected by emissions, such as volatile organic compounds (VOCs), when bitumen is heated. Therefore, it is crucial to correctly identify and measure VOCs. This paper presents a novel, promising method to determine VOC emissions. The proposed method offers a way to standardize routine measurements on a lab scale, enabling reliable comparison across bitumen types and their modifications or additives. A proton-transfer reaction time-of-flight mass spectrometer (PTR-TOF-MS) was used to monitor VOC emissions from commercial unmodified bitumen and crumb rubber modified bitumen (CRMB) with heating of up to 180 °C. Results confirmed that the temperature range of 160-180 °C is a highly influential factor for VOC emissions from heated commercial bitumen and particularly CRMB. A significant increase in alkane and aromatic emission was detected when the binders were heated to 180 °C. Sulfur-containing VOCs were almost nonexistent for the base bitumen fumes, while a significant increase was detected in the fumes when two different types of CR were added to the bitumen, even at 120 °C. The additional CR in the bituminous binder contributed to the potentially harmful VOC emission of benzothiazole, which belongs to the class of sulfur-containing compounds. The concentration of benzothiazole was 65%, 38%, and 35% higher for CR1 in comparison to CR2 at 140, 160, and 180 °C, respectively. It is clear from the results that this method allows different bitumen sources or modifications to be quickly analyzed and their VOC emissions cross-compared. If adopted and confirmed further, the method could offer the asphalt industry a viable solution to monitor VOC emissions by analyzing samples in real time at different steps of the production process.

Characterizing the Complex Modulus of Asphalt Concrete Using a Scanning Laser Doppler Vibrometer.

Asphalt mixtures are the most common types of pavement material used in the world. Characterizing the mechanical behavior of these complex materials is essential in durable, cost-effective, and sustainable pavement design. One of the important properties of asphalt mixtures is the complex modulus of elasticity. This parameter can be determined using different standardized methods, which are often expensive, complex to perform, and sensitive to the experimental setup. Therefore, recently, there has been considerable interest in developing new, easier, and more comprehensive techniques to investigate the mechanical properties of asphalt. The main objective of this research is to develop an alternative method based on an optical measurement technique (laser Doppler vibrometry). To do this, a frequency domain system identification technique based on analytical formulas (Timoshenko's beam theory) is used to determine the complex modulus of asphalt concrete at its natural frequencies and to form their master curve. The master curve plotted by this method is compared with the master curve obtained from the standard four-point bending test, and it is concluded that the proposed method is able to produce a master curve similar to the master curve of the standard method. Therefore, the proposed method has the potential to replace the standard stiffness tests. Furthermore, the standard stiffness methods usually conduct experiments up to the maximum frequency of 30 Hz. However, the proposed method can provide accurate complex modulus at high frequencies. This makes an accurate comparison between the properties of the asphalt mixtures in high frequencies and the development of more accurate theoretical models for simulation of specimens possible.

Lime Treatment of Coal Bottom Ash for Use in Road Pavements: Application to El Jadida Zone in Morocco.

Industrial waste causes environmental, economic, and social problems. In Morocco, the Jorf Lasfar Thermal Power Station produces two types of coal ash with enormous quantities: fly ash (FA) and Bottom ash (BA). FA is recovered in cement while BA is stored in landfills. To reduce the effects of BA disposal in landfills, several experimental studies have tested the possibility of their recovery in the road construction, especially as a subbase. In the first phase of this study, the BA underwent a physicochemical and geotechnical characterization. The results obtained show that the BA should be treated to improve its mechanical properties. The most commonly used materials are lime and cement. In the selected low-cost treatment, which is the subject of the second phase of the study, lime is used to improve the low pozzolanicity of BA while calcarenite sand is used to increase the compactness. Several mixtures containing BA, lime, and calcarenite sand were prepared. Each of these mixtures was compacted in modified Proctor molds and then subjected to a series of tests to study the following characteristics: compressive strength, dry and wet California Bearing Ratio (CBR), dry density and swelling. The composition of each mixture was based on an experimental design approach. The results show that the values of the compressive strength, the dry density, and the CBR index have increased after treatment, potentially leading to a valorization of the treated BA for use in a subbase.