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1.
J Chem Phys ; 148(19): 194307, 2018 May 21.
Artigo em Inglês | MEDLINE | ID: mdl-30307200

RESUMO

The microwave spectra of 10 teflic acid isotopologues were recorded in the frequency range of 3-25 GHz using supersonic jet-expansion Fourier transform microwave spectroscopy. Despite being asymmetric in its equilibrium structure, the delocalization of the hydrogen atom leads to a symmetric top vibrational ground state structure. In this work, we present the zero point structure obtained from the experimental rotational constants and an approach to determine the semi-experimental equilibrium structure aided by ab initio data. The Te-O bond length determined in the equilibrium structure is accurate to the picometer and can be used as a benchmark for computational methods treating relativistic effects.

2.
Artigo em Alemão | MEDLINE | ID: mdl-6781860

RESUMO

Polygraphic records (EEG, EOG, heart rate) were obtained of 5 subjects during and after transcendental meditation (TM) as well as during night sleep. The records were analyzed twice. During TM the amplitude of the alpha-waves was higher as before TM and appeared continuously. Bilateral theta-bursts were also observed. The same EEG changes were seen during relaxation with closed eyes. The discriminance-analysis of 5 frequency-bands of the EEG recorded from C3 showed either no differences in dominant frequency, power and variancy. No differences were observed between the flat EEGs recorded during TM or sleep. The heart rate was significantly slower during meditation or light sleep - when a flat EEG (stage 1) was recorded - as when the recording showed an alpha-rhythm. The vigilosomnograms of all our subjects were normal. The subjects reported that they experienced an increased relaxation, alertness and floating consciousness. They were able to maintain themselves for unusually long time in a state of decreased alertness (stages W1;10).


Assuntos
Computadores , Eletroencefalografia/métodos , Terapia de Relaxamento , Fases do Sono , Adulto , Potenciais Evocados , Frequência Cardíaca , Humanos , Masculino , Sono REM
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