Demonstrating Aqueous-Phase Low-Molecular-Weight-Gel Wicking of Oil for the Remediation of Oil Spilled into Surface Water.

Oils spilled into surface water require effective and timely treatment. In this paper, we report on a low-molecular-weight gelator that can form gels in organic and aqueous phases. The aqueous gel was observed to absorb oils, which is proposed as a new class of materials for remediating oil spilled into surface water. The gels and the low-molecular-weight gelator have both fundamental and applied significance. Fundamentally, identifying the mechanisms that govern the formation of these gels and their resultant mechanical properties is of interest. Subsequently, these fundamental insights aid in the optimization of these gels for addressing spilled oil. First, we briefly compare the organic and aqueous gels qualitatively before focusing on the aqueous gel. Second, we demonstrate the ability of the aqueous gel to wick oils through experiments in a Hele-Shaw cell and compare our results to the Washburn equation for porous media. The Washburn equation is not entirely adequate in describing our results due to the change in volume of the porous media during the wicking process. Finally, we investigate mechanisms proposed to govern the formation of low-molecular-weight gels in the literature through rheological shear measurements during gel formation. Our experiments suggest that the proposed mechanisms are applicable to our aqueous gels, growing as anisotropic crystal networks with fractal dimensions between one and two dimensions from temporally sporadic nucleation sites.

Effect of Toluene and Hexane Sorption on the Rheology and Interfacial Properties of Lecithin-Based Emulsion Gels.

A novel sorbent material consisting of a gel made from canola oil and water, emulsified with lecithin, was used to remove two model solvents from water. Sorption capacity was quantified through small-scale batch experiments. The structure and the mechanical properties of the gel were compared with and without added solvent to assess their cohesiveness upon removing contaminants from water. Confocal microscopy showed that the initial gel consisted of water droplets clustered in a canola oil continuous phase. The G' of the gels increased with solvent absorption to a maximum at 33% (v/v) hexane or 24% (v/v) toluene. Larger absorbed volumes led to decreases in G' of the gel. G' for solvent mixtures of 50% toluene and 50% hexane was intermediate between G' measured for the same volumes of pure solvents. Confocal microscopy suggests that the decrease of G' upon addition of large solvent volumes was due to a simple dilution effect. It is hypothesized that the initial increase in storage modulus was caused by changes in the structure of the lecithin films formed at the oil-water interfaces. This hypothesis was evaluated through measurements of interfacial tension, visualization of the interface with optical microscopy, force measurements of a single droplet under compression using a cantilevered-capillary force apparatus, compressional isotherm measurements conducted using a Langmuir trough. The cantilevered-capillary force apparatus and Langmuir trough experiments demonstrated that lecithin films at the canola oil-water interface were rigidified by toluene and hexane addition.