1.
Inter-ligand delocalisations in transition metal complexes containing multiple non-innocent ligands.
Dalton Trans
; 48(39): 14801-14807, 2019 Oct 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31552968
RESUMO
Systematic bonding analysis has been carried out for transition metal complexes containing more than one redox-active/non-innocent ligand. These complexes include tetralithio spiroaromatic palladole, dicupra[10]annulene, highly reduced nickel cyclooctadiene complex and tris(dithiolene)vanadium(iv). Our detailed bonding analysis reveals a common inter-ligand delocalisation pattern in these cases.