RESUMO
A supramolecule photosensitizer (supra-photosensitizer) based on the host-guest complexation of cyclodextrins and a bis-chalcone dye (BDEA) was prepared. Methyl-ß-cyclodextrin (Me-ß-CD), with the highest inclusion rate, was confirmed as the best host among the four cyclodextrins. The host-guest properties of Me-ß-CD and BDEA were characterized by FTIR, XRD, 1H NMR, PLQY, SEM, Job's plot, Benesi-Hildebrand plot, and others. Compared to the conventional photosensitizers, the supra-photosensitizers showed higher fluorescence emission and longer fluorescence lifetime whether as a powder or distributed in a film. The improvement in fluorescence coincided with improvement in photoinitiation efficiency and was proven to enhance the generation of volume grating. It is expected that the supra-photosensitizer may open a new avenue for the design of high-performance photoinitiation systems.
RESUMO
Optimizing the electronic configuration of Mo2C by activating heteroatom(s)-neighboring carbon atoms to enhance the activity of hydrogen evolution reaction (HER) has been demonstrated. However, the development of heteroatom-doped Mo2C to fabricate a water electrolyzer is still a challenge because of the limitation of a well-defined electronic structure of hybridization of Mo with heteroatom(s). Here, nitrogen (N) and phosphor (P) codoped Mo2C embedded carbon nanotubes (NCNT@P,N-Mo2C) with the priority occupation of C-sites by N, which well confines the P-implantation at the pyrrodic N-sites and brings out N-O bonding on the surface, which favorably modifies the electronic configuration of adjacent Mo, resulting in highly efficient pH-tolerant HER activity. This study not only presents a potential HER electrocatalyst candidate but also provides a strategy for the construction of a well-defined electronic structure of heteroatom(s)-neighboring carbon-based materials.
