Recent Advances in the Synthesis of Cyclic Sulfoximines via C-H Bond Activation.

Sulfoximines, a ubiquitous class of structural motifs, are widely present in bioactive molecules and functional materials that have received considerable attention from modern organic chemistry, pharmaceutical industries, and materials science. Sulfoximines have proved to be an effective directing group for C-H functionalization which was widely investigated for the synthesis of cyclic sulfoximines. Within the last decade, great progress has been achieved in the synthesis of cyclic sulfoximines. Thus, this review highlights the recent advances in the synthesis of cyclic sulfoximines via the C-H activation strategy and is classified based on the substrate types.

Advances of Sulfenate Anions in Catalytic Asymmetric Synthesis of Sulfoxides.

In recent years, sulfenate anions as key intermediates in enantioselective synthesis have attracted considerable attention. Typically, development of novel synthetic methods to generate sulfenate anions allows for the preparation of various enantiopure sulfoxides, which are prevalently used as auxiliaries, ligands, organocatalysts, and biologically active compounds. This review presents the in situ preparation methods and the recent applications of sulfenate anions in catalytic asymmetric synthesis of chiral sulfoxides.

Projection-based disparity control for toed-in multiview images.

The multiview images captured by toed-in camera array can reproduce the 3D scene vividly with appropriate positive, negative, and zero disparities. However, it is a challenging task to adjust the depth of the scene according to requirements of visual effects. In this paper, we propose a novel disparity control method based on projection to solve this problem. With the relationship between the world coordinate system and camera coordinate system, the zero disparity point in reference view is projected into other views. Thus, disparities of different views are obtained through matched corresponding points and views are shifted with calculated disparities. The proposed method is easy to implement, and the depth of toed-in multiview images can be adjusted as requirements. Experiment results show that the proposed method is effective in comparison to the conventional method, and the processed multiview images present desirable stereoscopic visual quality.