Polydentate hydrazones as multitasking catalysts in visible-light-induced coupling reactions of amines.

A Cu/hydrazone catalyst has been applied in the coupling reactions of anilines for the synthesis of diarylamines and azobenzenes. The copper complex that is formed in situ plays a double duty by harnessing photon energy as a photocatalyst and then by catalysing organometallic elementary steps as a transition metal catalyst. By the selection of hydrazones and bases, the reaction selectivity of aniline can be tuned between homo-coupling and its cross-coupling with arylboronic acid, exhibiting the great potential of such hydrazones in organic synthesis.

Heterogeneous copper-catalyzed synthesis of diaryl sulfones.

A carbon-supported copper nanoparticle (Cu-NP) with high catalytic activity for the synthesis of diaryl sulfones is reported. For the first time, this Cu-NP is proved to be able to effectively promote the reaction of arylboronic acids and arylsulfonyl hydrazides to generate diaryl sulfones at room temperature. The reaction shows excellent substrate universality, and substrates with different substituents can undergo the reaction smoothly, leading to the desired products in good yields. The Cu-NP is found to be made of low valence Cu based on XRD. Hence, the reaction catalyzed by the Cu-NP is believed to involve a Cu-mediated organometallic cycle.

Construction of α-Amino Azines via Thianthrenation-Enabled Photocatalyzed Hydroarylation of Azine-Substituted Enamides with Arenes.

α-Amino azines are widely found in pharmaceuticals and ligands. Herein, we report a practical method for accessing this class of compounds via photocatalyzed hydroarylation of azine-substituted enamides with the in situ-generated aryl thianthrenium salts as the radical precursor. This reaction features a broad substrate scope, good functional group tolerance, and mild conditions and is suitable for the late-stage installation of α-amino azines in complex structures.

An urchin-like MgCo2O4@PPy core-shell composite grown on Ni foam for a high-performance all-solid-state asymmetric supercapacitor.

In recent years, the electrochemical properties of supercapacitors have been greatly improved due to continuous improvement in their composite materials. In this study, an urchin-like MgCo2O4@PPy/NF (MgCo2O4@polypyrrole/Ni foam) core-shell structure composite material was successfully developed as an electrode for supercapacitors. The MCP-2 composite material, obtained by a hydrothermal method and in situ chemical oxidative polymerization, shows a high specific capacitance of 1079.6 F g-1 at a current density of 1 A g-1, which is much higher than that of MC (783.6 F g-1) under the same conditions. Simultaneously, it has low resistance and an excellent cycling stability of 97.4% after 1000 cycles. Furthermore, an all-solid-state asymmetric supercapacitor (ASC) was assembled using MCP-2 as the positive electrode and activated carbon (AC) as the negative electrode. The MCP-2//AC ASC exhibits high specific capacitance (94 F g-1 at a current density of 0.4 A g-1), high energy density (33.4 W h kg-1 at a power density of 320 W kg-1), high volumetric energy density (17.18 mW h cm-3 at a volumetric power density of 0.16 W cm-3) and excellent cycling stability (retaining 91% of the initial value after 10 000 cycles). Simultaneously, the device has low leakage current and excellent self-discharge characteristics. All these results indicate that the MCP-2//AC ASC is a good energy storage device; it can support the function of two LEDs for 20 minutes. These results indicate that the MCP-2//AC ASC will play an important role in energy structures in the future.