Wavelength extension beyond 3†µm in a Ho3+/Pr3+ co-doped AlF3-based fiber laser.

In this Letter, we report continuous-wave (CW) lasers with wavelengths beyond 3 µm in homemade Ho3+/Pr3+ co-doped AlF3-based glass fibers. The laser cavity was established through the integration of a dichroic mirror (DM, HR@3-3.1 µm) positioned at the pump end and a partial reflectivity (PR) fiber Bragg grating (FBG) situated at the laser emission end. The FBGs in AlF3-based glass fibers were fabricated by a fs laser direct-writing method, and the resonant wavelengths were 3.009, 3.036, and 3.064 µm, respectively. Under the pump of 1.15 µm laser, a maximum unsaturated output power of 1.014 W was obtained at 3.009 µm with an overall laser efficiency of 11.8% and FWHM bandwidth of 0.88 nm. Furthermore, in order to enhance the optical-thermal stability, the FBG was heat-treated at 200°C for 30 min, and a higher output power of 1081 mW (348 mW without heat treatment) at 3.036 µm was achieved. To the best of our knowledge, this is the first demonstration of 3-3.1 µm lasers by using FBGs in Ho3+/Pr3+ co-doped AlF3-based fibers.

Laser operation at 1.2†µm in Ho3+-doped ZBYA glass fibers.

Powerful 1.2-µm laser operation was produced in Ho3+-doped single-cladding, in-house fabricated ZrF4-BaF2-YF3-AlF3 (ZBYA) glass fibers. The fibers were fabricated based on ZBYA glass with a composition of ZrF4-BaF2-YF3-AlF3. Pumped by an 1150-nm Raman fiber laser, the maximum combined laser output power emitted from both sides of a 0.5-mol% Ho3+-doped ZBYA fiber was 6.7 W, with a slope efficiency of 40.5%. We also observed lasing at 2.9 µm with an output power of 350 mW, which was ascribed to the transition of Ho3+:5I6 → 5I7. The effect of rare earth (RE) doping concentration and the length of the gain fiber were also investigated to determine their effect on laser performance at 1.2 µm and 2.9 µm.

Efficient 2075-nm laser emission from Ho3+-doped fluorotellurite glass in a compact all-fiber structure.

In this Letter, we report an Ho3+-doped fluorotellurite glass all-fiber laser at 2075 nm. The gain fiber is pumped in-band with a 1976-nm fiber laser and connected by fusion splicing. A high-quality fusion splicing point with a loss of < 0.1 dB was obtained by finely adjusting the splicing power and offset. In addition, by optimizing the writing parameters, a third-order fiber Bragg grating (FBG) with a reflectivity of 98% was achieved at 2075 nm using the femtosecond laser direct-writing method. Using the FBG as the laser cavity mirror and a relatively short 28-cm-long home-made Ho3+-doped fluorotellurite fiber as the laser medium, a laser with a maximum unsaturated output power of 7.33 W was obtained, and the corresponding slope efficiency was as high as 93.4%. The first, to the best of our knowledge, demonstration of the fluorotellurite glass all-fiber ∼2.1-µm laser presented in this work may pave the way for a high-power 2.1-µm fiber laser with a compact structure.

Two-watt mid-infrared laser emission in robust fluorozirconate fibers.

To the best of our knowledge, we report here the first demonstration of 2.9 µm laser emission from in-house fabricated Ho3+/Pr3+ co-doped ZBYA glass fiber. The fiber was fabricated based on the ZBYA glass with compositions of ZrF4-BaF2-YF3-AlF3-PbF2-HoF3-PrF3. Under the pump of a 1150 nm Raman fiber laser, the maximum unsaturated output power of 2.16 W was obtained in a 15 cm long gain fiber with a slope efficiency of 24%. The influence of rare-earth doping concentration on laser performance was also investigated. The result indicates that ZBYA glass fibers have potential for using as a fluorozirconate glass gain fiber for mid-infrared fiber lasers.

Direct femtosecond laser inscription of Bragg gratings in Ho3+/Pr3+ co-doped AlF3-based glass fibers for a 2.86†µm laser.

In this Letter, we report the fabrication of fiber Bragg gratings (FBGs) in home-made Ho3+/Pr3+ co-doped single-cladding fluoroaluminate (AlF3) glass fibers and its application in watt-level lasing at the mid-infrared (MIR) wavelength of 2.86 µm. The FBGs were inscribed using an 800 nm femtosecond (fs) laser direct-writing technique. The FBG properties were investigated for different pulse energies, inscription speeds, grating orders, and transversal lengths. A second-order FBG with a high reflectivity of 99% was obtained at one end of a 16.5-cm-long gain fiber. Under 1150 nm laser pumping, this fiber yielded a power exceeding 1 W at 2863.9 nm with an overall laser efficiency of 17.7%. The fiber laser showed a FWHM bandwidth of 0.46 nm and long-term spectral stability.

Praseodymium mid-infrared emission in AlF3-based glass sensitized by ytterbium.

Broadband emission was obtained over 2.6 to 4.1 µm (Pr3+: 1G4→3F4, 3F3) in AlF3-based glass samples doped with different concentrations of praseodymium and 1 mol% ytterbium using a 976 nm laser pump. An efficient energy transfer process from Yb3+: 2F5/2 to Pr3+: 1G4 was analyzed through emission spectra and fluorescence lifetime values. The absorption and emission cross-sections were calculated by Füchtbauer-Ladenburg and McCumber theories and a positive gain can be obtained when P>0.3. To the best of the authors' knowledge, this work represents the first report of broadband mid-infrared emission of Pr3+ in an AlF3-based glass. The results show that praseodymium doped AlF3-based glass sensitized by ytterbium could be a promising candidate for fiber lasers operating in mid-infrared region.

2 µm lasing from Tm3+-doped PbO-PbF2-Bi2O3-Ga2O3 glass microspheres.

Whispering gallery mode (WGM) lasers at ∼2µm are demonstrated in PbO-PbF2-Bi2O3-Ga2O3 (PBG) heavy metal oxyfluoride glass microspheres. A 793 nm diode laser is used to pump the PBG microsphere and achieve single-mode and multimode WGM lasing. The fluorescence spectra of Tm3+-doped PBG glasses are measured under 793 nm diode laser pumping. The maximum absorption and emission cross sections of Tm3+:3F4→3H6 are calculated to be 8.23×10-21 and 4.42×10-20cm2, respectively. The experimental results indicate that these PBG glass microspheres could become an important photonic component for infrared laser applications.

Room-temperature watt-level and tunable ∼3 µm lasers in Ho3+/Pr3+ co-doped AlF3-based glass fiber.

A room-temperature watt-level continuous-wave-output power mid-infrared fiber laser operating at $\lambda\sim 3\; \unicode{x00B5}{\rm m}$ is demonstrated using a ${{\rm Ho}^{3 +}}/{{\rm Pr}^{3 +}}$ co-doped ${{\rm AlF} _3}$ based glass fiber as a gain fiber. This fixed-wavelength laser had maximum output power of 1.13 W with a slope efficiency of 10.3% and a long-term operating stability of ${\gt}{40}\;{\min }$ without any additional packaging or active thermal management. A fiber laser with tunability from 2.842 to 2.938 µm showed a maximum output power of 110 mW.

Circulating sFasL Levels Predict the Severity and Outcome of Burn Injury: A Prospective Observational Study.

BACKGROUND: Severe burn injury activates shock, inflammation, and blood cell system, but inappropriate reactions may lead to adverse outcomes. Soluble Fas ligand (sFasL) participates in apoptosis and inflammatory response. The circulating sFasL levels we investigated in association with the burn severity, shock, inflammation, blood cells, and mortality in patients with severe burns. METHODS: A total of 56 patients with severe burns were recruited. The levels of sFasL and the biomarkers reflecting shock, organ damage, inflammation, and blood cells at 48 h postburn were analyzed. We compared the practical situation of patients that stratified by median sFasL levels and investigated the predictive value of sFasL for mortality. RESULTS: High circulating sFasL levels were associated with the higher degrees of burn index, shock index, lactate, N-terminal probrain natriuretic peptide, total bilirubin, blood urea nitrogen, creatinine, tumor necrosis factor-α, interleukin-1ß, interleukin-8, intercellular adhesion molecule 1, and complement 3, and the lower degrees of oxygenation index, lymphocytes, and platelets. Multiple linear regression analysis showed that the higher tumor necrosis factor-α (P < 0.001) and the lower oxygenation index (P = 0.031) and lymphocytes (P = 0.043) were associated with the higher sFasL. High sFasL (a unit is 50 ng/L) (odds ratio [OR] 5.50 [95% CI 1.04-29.20], P = 0.045) was an independent predictor of increased mortality by multivariate logistic regression analysis. CONCLUSIONS: High circulating sFasL at 48 h postburn in patients with severe burns reflect shock, proinflammatory response, organ damage, and lymphocyte reductions and predict 30-day mortality.

Enhanced 3.9 µm emission from diode pumped Ho3+/Eu3+ codoped fluoroindate glasses.

The use of Eu3+ codoping for enhancing the Ho3+:5I5→5I6 emission in fluoroindate glasses shows that Eu3+ could depopulate the lower laser state Ho3+:5I6 while having little effect on the upper state Ho3+:5I5, resulting in greater population inversion. The Ho3+/Eu3+ codoped glass has high spontaneous transition probability (6.31s-1) together with large emission cross section (7.68×10-21cm2). This study indicates that codoping of Ho3+ with Eu3+ is a feasible alternative to quench the lower energy level of the 3.9 µm emission and the Ho3+/Eu3+ codoped fluoroindate glass is a promising material for efficient 3.9 µm fiber lasers.

Broadband 2.7 µm mid-infrared emissions in Er3+-doped PbO-PbF2-Bi2O3-Ga2O3 glasses.

Broadband emission at 2.7 µm is observed in an Er3+-doped PbO-PbF2-Bi2O3-Ga2O3 glass. The measured emission band full-width-at-half-maximum (FWHM) is ∼184.4nm, approximately 36 nm wider than that of fluoride glasses. The 2.7 µm emission intensity is almost twice as strong as that of fluoride glasses. The peak values of emission and absorption cross-sections are calculated to be 1.54×10-20cm2 and 1.19×10-20cm2, respectively. This oxyfluoride heavy metal glass shows potential as broadband mid-infrared emission gain material.

Intense mid-infrared emission at 3.9 µm in Ho3+-doped ZBYA glasses for potential use as a fiber laser.

Intense mid-infrared emission at 3.9 µm in Ho3+-doped ZBYA glasses with direct upper laser level (Ho3+:5I5) pumping at a wavelength of 888 nm is reported for the first time, to the best of our knowledge. Spectroscopic parameters were determined using the Judd-Ofelt theory and the measured absorption spectrum. The maximum emission cross section of the Ho3+-doped ZBYA glass is estimated to be 2.7×10-21cm2 at 3906 nm. Additionally, fluorescence spectra and lifetimes of ZBYA glasses with different Ho3+ ion doping concentrations were measured. The results provide theoretical and experimental basis for better selection of rare-earth-doped matrix glasses to achieve a fluorescence output centered on a wavelength of 3.9 µm.

Tm3+-doped fluorotellurite glass microsphere resonator laser at 2.3 µm.

In this Letter, we report lasing at 2.3 µm in Tm3+-single-doped and Tm3+/Ho3+-codoped fluorotellurite glass microsphere resonators. By employing a 793 nm diode laser as a pump and exploiting whispering gallery mode microresonators (WGMRs), dual-wavelength lasing at 1.9 and 2.3 µm and triple-wavelength lasing at 1.9, 2.07, and 2.3 µm are achieved in Tm3+-doped and Tm3+/Ho3+-codoped microspheres, respectively. The introduction of Ho3+ ions significantly reduces the lasing threshold of Tm3+ at 2.3 µm because of energy transfer.

2.9 µm lasing from a Ho3+/Pr3+ co-doped AlF3-based glass fiber pumped by a 1150 nm laser: publisher's note.

This publisher's note contains corrections to Opt. Lett. 45, 1216 (2020).

2.9 µm lasing from a Ho3+/Pr3+ co-doped AlF3-based glass fiber pumped by a 1150 nm laser.

Ho3+/Pr3+ co-doped AlF3-based glass fibers were fabricated by using a rod-in-tube method based on the matrix glass composition of AlF3-BaF2-CaF2-YF3-SrF2-MgF2-LiF-ZrF4-PbF2. Under the pump of a 1150 mW Raman fiber laser, a 2.9 µm laser was observed in a 19 cm long Ho3+/Pr3+ co-doped AlF3-based glass fiber with an output power of 173 mW and a slope efficiency of 10.4%. Ho3+/Pr3+ co-doped AlF3-based glasses were fabricated to investigate the deactivation effects of Pr3+ ions on the Ho3+:5I7 level. Our results showed that the Ho3+/Pr3+ co-doped AlF3-based glass fibers are potential gain media for ∼2.9µm lasers.

In-fiber temperature sensor based on green up-conversion luminescence in an Er3+-Yb3+co-doped tellurite glass microsphere.

A novel, to the best of our knowledge, in-fiber temperature sensor based on green up-conversion (UC) luminescence in an Er3+-Yb3+ co-doped tellurite glass microsphere is described. The tellurite glass microsphere is located firmly inside a suspended tri-core hollow-fiber (STCHF) structure. The pump light launched via a single-mode fiber (SMF) is passed through a section of multimode fiber, which is fusion spliced between the SMF and the STCHF into the cores suspended inside the hollow fiber and coupled into the microsphere. Green and red UC emissions of the Er3+ ions are observed using 980 nm pump excitation. The temperature-sensing capability of the tellurite glass microsphere is based on the thermally coupled effect between the upper energy levels responsible for green emissions at 528 nm and 549 nm. The resulting fluorescence intensity ratio, depending on the surrounding temperature range from 303 K to 383 K, is experimentally determined, and a maximum sensitivity of 5.47×10-3 K-1 is demonstrated. This novel in-fiber microsphere-resonator-based device is highly integrated and has the additional advantages of ease of fabrication, compact structure, and low fabrication cost and therefore has great application potential in integrated optical sources including lasers.

Tm3+-Ho3+ codoped tellurite glass microsphere laser in the 1.47 µm wavelength region.

In this Letter, a Tm3+-Ho3+ codoped tellurite glass microsphere laser in the 1.47 µm wavelength region is described. Using a traditional tapered microfiber-microsphere coupling method, multimode and single-mode lasing around the wavelength of 1.47 µm is observed using an 802 nm laser diode as a pump source. This Tm3+-Ho3+ codoped tellurite glass microsphere laser can be used in near-infrared telecommunications, biomedical, and astrophysical applications.

Investigation of a novel SMS fiber based planar multimode waveguide and its sensing performance.

A novel, MMI-based all-fiber structure, which consists of two single-mode fibers and a multimode fiber polished on both sides, is described. The light propagation characteristics of this fiber structure, as well as its superior sensing performance, are analyzed theoretically by using the beam propagation method (BPM). This fiber structure demonstrates a significant spectral response to changes of the surrounding refractive index (RI), and the measured results exhibit good agreement with the predicted data. The measured average RI sensitivity is as high as 151.29 nm/RIU over an RI range from 1.3450 to 1.4050, when the polished depth is 30 µm on both sides of the multimode fiber. This fiber structure can be an advantageous platform for various applications, especially for a lab-on-fiber type sensing application.

Broadband multicolor upconversion from Yb3+-Mn2+ codoped fluorosilicate glasses and transparent glass ceramics.

In contrast to well-known upconversion (UC) emission from Yb3+-Mn2+-codoped crystal, a room-temperature intense broadband UC phenomenon was first observed in both Yb3+-Mn2+-codoped fluorosilicate glasses and transparent glass ceramics under 980 nm pumping. The obtained photoluminescence ranged from yellow to white to blue. We attributed this effect to the cooperative UC of Yb3+ and to the formation of Yb3+-Mn2+ pairs. After heat treatment, KZnF3 nanocrystals appeared in the glass matrix, as identified by x-ray diffraction and transmission electron microscopy, and emission intensity increased 45 times. We believe that Yb3+-Mn2+-codoped glasses and glass ceramics show great potential as materials for multicolor displays.

Effect of Tm3+ concentration on the emission wavelength shift in Tm3+-doped silica microsphere lasers.

In this work, a Tm3+-doped solgel silica microsphere lasing at 2.0 µm is reported. Microspheres with different Tm3+ concentrations are fabricated by overlaying different Tm3+ concentration solgel solutions on the surface of a pure silica microsphere resonator and then annealing the sample with a CO2 laser. Based on a traditional fiber taper-microsphere coupling method, single and multimode microsphere lasing in the wavelength range 1.8-2.0 µm is observed if an 808 nm laser diode is used as a pump source. A relatively low threshold pumping power of 1.2 mW is achieved using this arrangement. This solgel method allows for an easy varying of the Tm3+ doping concentration. The observed laser output shifts to longer wavelengths when the Tm3+ doping concentration increases. This has been explained by the larger Tm absorption at shorter wavelengths. The ability to fabricate solgel co-doped silica glass microlasers represents a new generation of low threshold and compact infrared laser sources for use as miniaturized photonic components for a wide range of applications, including gas sensing and medical surgery.