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1.
Phys Chem Chem Phys ; 2024 Jul 04.
Artigo em Inglês | MEDLINE | ID: mdl-38962897

RESUMO

Nacre plays an important role in bionic design due to its light weight, high strength, and structure-function integration. The key to elucidate its reinforcing and toughening mechanisms is to truly characterize its multi-layer structure and properties. In this work, the dynamic impact responses of graphene reinforced polymer nanocomposites with a unique brick-and-mortar structure are investigated using coarse-grained molecular dynamics simulations, in which the interfacial coarse-grained force field between graphene and the polymer matrix is derived by the energy matching approach. The influences of various geometrical parameters on dynamic impact responses of the nanocomposites are studied, including the interlayer distance, lateral distance, and number of graphene layers. The results demonstrate that the impact resistance of the nacre-like structure can be significantly improved by tuning the geometrical parameters of graphene layers. It is also found that the chain scission and interchain disentanglement of polymer chains are the main failure mechanisms during the perforation failure process as compared to the stretching and breaking of bonds. In addition, the microstructure analysis is performed to deeply interpret the deformation and damage mechanisms of the nanocomposites during impact. This study could be helpful for the rational design and preparation of graphene reinforced nacre-like nanocomposites with high impact resistance.

2.
Polymers (Basel) ; 16(5)2024 Mar 04.
Artigo em Inglês | MEDLINE | ID: mdl-38475384

RESUMO

Elastomeric polymers have gained significant attention in the field of flexible electronics. The investigation of the electro-mechanical response relationship between polymer structure and flexible electronics is in increasing demand. This study investigated the factors that affect the performance of flexible capacitive pressure sensors using the finite element method (FEM). The sensor employed a porous elastomeric polymer as the dielectric layer. The results indicate that the sensor's performance was influenced by both the structural and material characteristics of the porous elastomeric polymer. In terms of structural characteristics, porosity was the primary factor influencing the performance of sensors. At a porosity of 76%, the sensitivity was 42 times higher than at a porosity of 1%. In terms of material properties, Young's modulus played a crucial role in influencing the performance of the sensors. In particular, the influence on the sensor became more pronounced when Young's modulus was less than 1 MPa. Furthermore, porous polydimethylsiloxane (PDMS) with porosities of 34%, 47%, 67%, and 72% was fabricated as the dielectric layer for the sensor using the thermal expansion microsphere method, followed by sensing capability testing. The results indicate that the sensor's sensitivity was noticeably influenced within the high porosity range, aligning with the trend observed in the simulation.

3.
Polymers (Basel) ; 16(1)2023 Dec 26.
Artigo em Inglês | MEDLINE | ID: mdl-38201746

RESUMO

High temperature and humidity affect the tribological performance of nitrile butadiene rubber (NBR) seals, which affects the precise positioning of cylinder systems. Therefore, it is crucial to study the effect of hydrothermal aging on the tribological performance of the NBR seals. In this study, the changes in the tribological performance of the NBR seals under hydrothermal aging conditions were investigated. The results show that the volatilization of additives and the increase in crosslink density of the NBR seals occurs in the hydrothermal aging environment, leading to the deterioration of their surface quality, elastic deformability, and tribological performance. The formation of surface micropores due to additive volatilization is the main factor in the degradation of tribological performance.

4.
Nanomaterials (Basel) ; 12(19)2022 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-36234394

RESUMO

Flexible pressure sensors have garnered much attention recently owing to their prospective applications in fields such as structural health monitoring. Capacitive pressure sensors have been extensively researched due to their exceptional features, such as a simple structure, strong repeatability, minimal loss and temperature independence. Inspired by the skin epidermis, we report a high-sensitivity flexible capacitive pressure sensor with a broad detection range comprising a bioinspired spinosum dielectric layer. Using an abrasive paper template, the bioinspired spinosum was fabricated using carbon nanotube/polydimethylsiloxane (CNT/PDMS) composites. It was observed that nanocomposites comprising 1 wt% CNTs had excellent sensing properties. These capacitive pressure sensors allowed them to function at a wider pressure range (~500 kPa) while maintaining sensitivity (0.25 kPa-1) in the range of 0-50 kPa, a quick response time of approximately 20 ms and a high stability even after 10,000 loading-unloading cycles. Finally, a capacitive pressure sensor array was created to detect the deformation of tires, which provides a fresh approach to achieving intelligent tires.

5.
Nanomaterials (Basel) ; 12(14)2022 Jul 20.
Artigo em Inglês | MEDLINE | ID: mdl-35889718

RESUMO

Flexible pressure sensors that can maintain their pressure sensing ability with arbitrary deformation play an essential role in a wide range of applications, such as aerospace, prosthetics, robotics, healthcare, human-machine interfaces, and electronic skin. Flexible pressure sensors with diverse conversion principles and structural designs have been extensively studied. At present, with the development of 5G and the Internet of Things, there is a huge demand for flexible pressure sensor arrays with high resolution and sensitivity. Herein, we present a brief description of the present flexible pressure sensor arrays with different transduction mechanisms from design to fabrication. Next, we discuss the latest progress of flexible pressure sensor arrays for applications in human-machine interfaces, healthcare, and aerospace. These arrays can monitor the spatial pressure and map the trajectory with high resolution and rapid response beyond human perception. Finally, the outlook of the future and the existing problems of pressure sensor arrays are presented.

6.
ACS Appl Mater Interfaces ; 14(4): 6274-6282, 2022 Feb 02.
Artigo em Inglês | MEDLINE | ID: mdl-35075896

RESUMO

Directional self-transportation of tiny droplets is significant in many fields. However, almost all existing studies focus on the phenomenon in air, and to realize similar performance in complex environments, such as oil, is still extremely rare. Here, we report a TiO2-coated conical spine (TCS) and demonstrate underoil directional self-transportation of water droplets on its surface. It is found that high surface hydrophilicity resulting from UV irradiation is necessary to achieve the self-transportation of water in oil. The critical water contact angle in oil is about 57°, and the maximal transport velocity can reach 1.4 mm/s. Mechanism analysis reveals that the excellent self-transportation property is ascribed to the combined effect between the Laplace force (FL) caused by the conical gradient structure and the hysteresis reduction resulting from the high hydrophilicity. Moreover, based on the special underoil self-transportation performance, a droplet-based microreaction and demulsification of water-in-oil emulsions were demonstrated using the TCS. This work reports the self-transportation of water in oil, which could provide some fresh ideas for designing new superwetting self-transportation materials.

7.
Polymers (Basel) ; 13(19)2021 Oct 07.
Artigo em Inglês | MEDLINE | ID: mdl-34641253

RESUMO

The tribological characteristics of the cylinder directly affect the operation accuracy of the pneumatic servo system. However, the geometric error has a significant effect on its tribological behavior and the related research is insufficient. Thus, the dynamic friction process of rubber seals has been investigated considering the influence of geometric errors. Firstly, based on the self-made friction test platform, the friction force of the rubber seals was studied and the influence law of geometric error on the contact area of the rubber seal ring was revealed. Secondly, the numerical model of the friction and contact of the rubber seals for the cylinder segment was developed by using the finite element simulation method and the influence laws of machining errors, such as roundness and straightness on the friction characteristics, were revealed. Finally, synergy effects of roundness and straightness in the friction behavior of rubber seals considering geometric errors was investigated, which lays a foundation for the accurate prediction of cylinder dynamic mechanical properties.

8.
Nanomaterials (Basel) ; 11(9)2021 Sep 21.
Artigo em Inglês | MEDLINE | ID: mdl-34578778

RESUMO

Tribological properties of tread rubber is a key problem for the safety and durability of large aircraft tires. So, new molecular models of carbon nanotube (CNT) reinforced vulcanized natural rubber (VNR) composites have been developed to study the enhanced tribological properties and reveal the reinforced mechanism. Firstly, the dynamic process of the CNT agglomeration is discussed from the perspectives of fractional free volume (FFV) and binding energy. Then, a combined explanation of mechanical and interfacial properties is given to reveal the CNT-reinforced mechanism of the coefficient of friction (COF). Results indicate that the bulk, shear and Young's modulus increase with the increasement of CNT, which are increasement of 19.13%, 21.11% and 26.89% in 15 wt.% CNT/VNR composite compared to VNR; the predicted results are consistent with the existing experimental conclusions, which can be used to reveal the CNT-reinforced mechanism of the rubber materials at atomic scale. It can also guide the design of rubber material prescription for aircraft tire. The molecular dynamics study provides a theoretical basis for the design and preparation of high wear resistance of tread rubber materials.

9.
Polymers (Basel) ; 13(7)2021 Apr 02.
Artigo em Inglês | MEDLINE | ID: mdl-33918415

RESUMO

The road surface and the tread pattern structures directly affect the wear performance of aircraft tire, especially for lateral sliding conditions. In this paper, wear tests of tread block with different draft angles and root radiuses, different interfaces, and different slip angles were carried out, and combined with the simulation, the effects of tread groove structure and slip angle on the wear mechanism were analyzed. Results indicated that the influences of draft angle were greater than the root radius; the wear geometry of the tread block decreased when the draft angle increased in the range of 0° to 15°, but for the root radius, the wear geometry of each sample was similar to a strip shape. A considerable material loss occurred at the front edge when the slip angle increased, and the slip angle was larger in the range of 0° to 45°. Combined with the simulation and wear test, fatigue wear and abrasive wear of the slide surface are dominant factors when considering the effects of tread groove structure and slip angle, and both front edges of the tread blocks roll up repeatedly; the coefficient decreases with the increase in load when the cement concrete pavement interface is dry, but for a wet interface, the coefficient decreases softly.

10.
Angew Chem Int Ed Engl ; 59(33): 14029-14033, 2020 Aug 10.
Artigo em Inglês | MEDLINE | ID: mdl-32374487

RESUMO

MXene (Ti3 C2 Tx ) is a new 2D material with both hydrophilicity and high electrical conductivity, and it has shown promise in smart electronic devices. Reported herein is a homogeneous MXene film actuator with high electrical conductivity triggered by moisture gradients. The actuator is highly sensitive to moisture and undergoes deformation, with the maximum bending angle as high as 155° at a relative humidity difference of 65 %. Several analysis methods show that the humidity drive and large deformation of the MXene film occur in situ by asymmetric expansion of the bilayer structure. The combination of deformation and electrical conductivity makes this film applicable to flexible excavators, electrical switches, and other fields, applications that are difficult to achieve directly by using other 2D materials. More importantly, this work further expands the new application range of MXene materials and provides new opportunities for building the next generation of high-conductivity smart actuators.

11.
Polymers (Basel) ; 12(1)2020 Jan 04.
Artigo em Inglês | MEDLINE | ID: mdl-31947977

RESUMO

Cylinder has become an indispensable and important pneumatic actuator in the development of green production technology. The sealing performance of the cylinder directly affects its safety and reliability. Under the service environment of the cylinder, hydrothermal aging of the rubber sealing ring directly affects the dynamic friction performance of the cylinder. So, the dynamic friction model of the cylinder has been developed based on the LuGre friction model, which considers the influence of hydrothermal aging. Here, the influences of the static friction coefficient and Coulomb friction coefficient on the friction model are analyzed. Then, the aging characteristic equation of rubber is embedded in the model for revealing the influence of aging on the friction coefficient of the model. Results show that the aging temperature, aging time, and compressive stress affects the friction coefficient; the variation of the static friction coefficient is larger than that of the Coulomb friction coefficient. The improved cylinder friction model can describe the influence of the aging process on the cylinder friction characteristics, which is of great significance in the design of the cylinder's dynamic performance.

12.
Soft Matter ; 16(4): 1011-1020, 2020 Jan 28.
Artigo em Inglês | MEDLINE | ID: mdl-31854423

RESUMO

In this work, we study the peeling of a cylindrical shell attached to a smooth rigid substrate and subjected to a vertical force. A generalized peeling model based on the energy-variational approach is presented, and its numerical solutions characterize the cross-section profile and peeling force. The interfacial interactions are represented by the Lennard-Jones potential. Molecular dynamics simulations are performed for the peeling system with single-walled carbon nanotubes and gold substrates, and simulation results show good agreement with the theoretical predictions. We show that there are three stages (stable peeling stage, line-contact stage, and pull-off stage) in the entire peeling process. A spring-like behavior is observed in the stable peeling stage. With the peeling displacement increasing, the second stage has a marked feature of line contact and the peeling force arrives at a peak pull-off force. Furthermore, we show that the pull-off force strongly depends on the flexural stiffness of cylindrical shell and two Lennard-Jones parameters, but is independent of the initial radius of cylindrical shell. Our findings may help to reveal the interactions between thin-walled nanotubes and substrates.

13.
Plants (Basel) ; 9(1)2019 Dec 19.
Artigo em Inglês | MEDLINE | ID: mdl-31861523

RESUMO

Soil microorganisms play important roles in nutrient mobilization and uptake of mineral nutrition in plants. Agricultural management, such as soil sterilization, can have adverse effects on plant growth because of the elimination of indigenous microorganisms. Arbuscular mycorrhizal (AM) fungi are one of the most important beneficial soil microorganisms for plant growth. However, whether AM fungi can compensate for the loss of indigenous microbial communities to support plant growth and metabolism is largely unknown. In this study, a pot experiment was conducted to investigate the effects of AM fungi on plant growth and secondary metabolism in sterilized and unsterilized soil. We used liquorice (Glycyrrhiza uralensis Fisch.), an important medicinal plant as the host, which was inoculated with the AM fungus Rhizophagus irregularis or not and grown in unsterilized or sterilized soil. Plant photosynthesis traits, plant growth and nutrition level, concentrations of the secondary metabolites, and expression levels of biosynthesis genes were determined. The results showed that soil sterilization decreased plant growth, photosynthesis, and glycyrrhizin and liquiritin accumulation, and moreover, downregulated the expression of related biosynthesis genes. Inoculation with R. irregularis in sterilized soil offset the loss of indigenous microbial communities, resulting in plant growth and glycyrrhizin and liquiritin concentrations similar to those of plants grown in unsterilized soil. Thus, AM fungi could compensate for the loss of indigenous microbial communities by soil sterilization to support plant growth and secondary metabolism.

14.
Int J Phytoremediation ; 21(9): 849-856, 2019.
Artigo em Inglês | MEDLINE | ID: mdl-30994000

RESUMO

A pot experiment was conducted to investigate the potential influence of arbuscular mycorrhizal fungi (AMF), Funneliformis mosseae and Diversispora spurcum, on the growth and nutrient (P and S) and heavy metal (HMs) (Pb, Zn, and Cd) content of bermudagrass [Cynodon dactylon (L.) Pers.] in a lead-zinc mine wasteland. The D. spurcum inoculation significantly increased the bermudagrass growth, whereas the F. mosseae inoculation did not. The AMF inoculation significantly increased the soil pH and uptake of P, S, and HMs by bermudagrass, decreased the contents of available Pb and Zn in soils and Pb in shoots, reduced the translocation factor (TF) and translocation capacity factor (TF') of Pb and Cd in bermudagrass and increased the TF and TF' of Zn in bermudagrass. A significant negative correlation was found between pH and available HMs in soil, whereas a significant positive correlation was noted between the HMs content and nutrient content in bermudagrass shoots. Experiment results provide evidence of the potential role of AMF in improving bermudagrass performance for the vegetation restoration of metalliferous mine wastelands.


Assuntos
Metais Pesados , Micorrizas , Poluentes do Solo/análise , Biodegradação Ambiental , Cynodon , Chumbo , Zinco
15.
Adv Sci (Weinh) ; 5(10): 1800750, 2018 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-30356956

RESUMO

MXene films are attractive for advanced supercapacitor electrodes requiring high volumetric energy density due to their high redox capacitance combined with extremely high packing density. However, the self-restacking of MXene flakes unavoidably decreases the volumetric performance, mass loading, and rate capability. Herein, a simple strategy is developed to prepare a flexible and free-standing modified MXene/holey graphene film by filtration of the alkalized MXene and holey graphene oxide dispersions, followed by a mild annealing treatment. After terminal groups (-F/-OH) are removed, the increased proportion of Ti atoms enables more pseudocapacitive reaction. Meanwhile, the embedded holey graphene effectively prevents the self-restacking of MXene and forms a high nanopore connectivity network, which is able to immensely accelerate the ion transport and shorten transport pathways for both ion and electron. When applied as electrode materials for supercapacitors, it can deliver an ultrahigh volumetric capacitance (1445 F cm-3) at 2 mV s-1, excellent rate capability, and high mass loading. In addition, the assembled symmetric supercapacitor demonstrates a fantastic volumetric energy density (38.6 Wh L-1), which is the highest value reported for MXene-based electrodes in aqueous electrolytes. This work opens a new avenue for the further exploration of MXene materials in energy storage devices.

16.
Environ Sci Pollut Res Int ; 25(24): 24338-24347, 2018 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-29948717

RESUMO

In this study, we investigated the effects of the arbuscular mycorrhizal fungi (AMF) Funneliformis mosseae and Diversispora spurcum on the growth, antioxidant physiology, and uptake of phosphorus (P), sulfur (S), lead (Pb), zinc (Zn), cadmium (Cd), and arsenic (As) by maize (Zea mays L.) grown in heavy metal-polluted soils though a potted plant experiment. F. mosseae significantly increased the plant chlorophyll a content, height, and biomass; decreased the H2O2 and malondialdehyde (MDA) contents; and enhanced the superoxide dismutase (SOD) and catalase (CAT) activities and the total antioxidant capacity (T-AOC) in maize leaves; this effect was not observed with D. spurcum. Both F. mosseae and D. spurcum promoted the retention of heavy metals in roots and increased the uptake of Pb, Zn, Cd, and As, and both fungi restricted heavy metal transfer, resulting in decreased Pb, Zn, and Cd contents in shoots. Therefore, the fungi reduced the translocation factors for heavy metal content (TF) and uptake (TF') in maize. Additionally, F. mosseae promoted P and S uptake by shoots, and D. spurcum increased P and S uptake by roots. Moreover, highly significant negative correlations were found between antioxidant capacity and the H2O2, MDA, and heavy metal contents, and there was a positive correlation with the biomass of maize leaves. These results suggested that AMF alleviated plant toxicity and that this effect was closely related to antioxidant activation in the maize leaves and increased retention of heavy metals in the roots.


Assuntos
Metais Pesados/farmacocinética , Micorrizas/fisiologia , Folhas de Planta/metabolismo , Raízes de Plantas/metabolismo , Zea mays/microbiologia , Antioxidantes/metabolismo , Biomassa , Glomeromycota/fisiologia , Peróxido de Hidrogênio/metabolismo , Fósforo/farmacocinética , Folhas de Planta/efeitos dos fármacos , Raízes de Plantas/efeitos dos fármacos , Raízes de Plantas/microbiologia , Poluentes do Solo/farmacocinética , Enxofre/farmacocinética , Zea mays/crescimento & desenvolvimento , Zea mays/metabolismo
17.
Nanoscale ; 10(20): 9642-9652, 2018 May 24.
Artigo em Inglês | MEDLINE | ID: mdl-29756628

RESUMO

MXene films are attractive for use in advanced supercapacitor electrodes on account of their ultrahigh density and pseudocapacitive charge storage mechanism in sulfuric acid. However, the self-restacking of MXene nanosheets severely affects their rate capability and mass loading. Herein, a free-standing and flexible modified nanoporous MXene film is fabricated by incorporating Fe(OH)3 nanoparticles with diameters of 3-5 nm into MXene films and then dissolving the Fe(OH)3 nanoparticles, followed by low calcination at 200 °C, resulting in highly interconnected nanopore channels that promote efficient ion transport without compromising ultrahigh density. As a result, the modified nanoporous MXene film presents an attractive volumetric capacitance (1142 F cm-3 at 0.5 A g-1) and good rate capability (828 F cm-3 at 20 A g-1). Furthermore, it still displays a high volumetric capacitance of 749 F cm-3 and good flexibility even at a high mass loading of 11.2 mg cm-2. Therefore, this flexible and free-standing nanoporous MXene film is a promising electrode material for flexible, portable and compact storage devices. This study provides an efficient material design for flexible energy storage devices possessing high volumetric capacitance and good rate capability even at a high mass loading.

18.
Nanotechnology ; 29(7): 075705, 2018 Feb 16.
Artigo em Inglês | MEDLINE | ID: mdl-29256867

RESUMO

Carbon nanotubes (CNTs) can undergo collapse from the ordinary cylindrical configurations to bilayer ribbons when adhered on substrates. In this study, the collapsed adhesion of CNTs on the silicon substrates is investigated using both classical molecular dynamics (MD) simulations and continuum analysis. The governing equations and transversality conditions are derived based on the minimum potential energy principle and the energy-variational method, considering both the van der Waals interactions between CNTs and substrates and those inside CNTs. Closed-form solutions for the collapsed configuration are obtained which show good agreement with the results of MD simulations. The stability of adhesive configurations is investigated by analyzing the energy states. It is found that the adhesive states of single-walled CNTs (SWCNTs) (n, n) on the silicon substrates can be categorized by two critical radii, 0.716 and 0.892 nm. For SWCNTs with radius larger than 0.892 nm, they would fully collapse on the silicon substrates. For SWCNTs with radius less than 0.716 nm, the initial cylindrical configuration is energetically favorable. For SWCNTs with radius between two critical radii, the radially deformed state is metastable. The non-contact ends of all collapsed SWCNTs are identical with the same arc length of 2.38 nm. Finally, the role of number of walls on the adhesive configuration is investigated quantitatively. For multi-walled CNTs with the number of walls exceeding a certain value, the cylindrical configuration is stable due to the increasing bending stiffness. The present study can be useful for the design of CNT-based nanodevices.

19.
ACS Appl Mater Interfaces ; 9(26): 21763-21772, 2017 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-28605894

RESUMO

The volumetric performance is a vitally important metric for portable electronic and wearable devices with limited space. However, it is contradictory for the most supercapacitors in the connection between the volumetric and gravimetric capacitances. Herein, we report a simple strategy to prepare a free-standing and binder-free holey graphene/PPy film that possesses a dense microstructure but still high gravimetric capacitances. The holey graphene/PPy film own high-efficiency ion transport channels and big ion-accessible surface area to achieve high-powered supercapacitor electrodes, which have a superior volumetric capacitance (416 F cm-3) and high gravimetric capacitance (438 F g-1) at 1.0 A g-1 in 6 M KOH electrolyte. Meanwhile, it possesses high rate capability and good cycling performance (82.4% capacitance retention even after 2000 cycles). Furthermore, the volumetric energy density of assembled holey graphene/PPy film symmetric supercapacitor can show high as 22.3 Wh L-1. Such densely packed free-standing holey graphene/PPy film is a very significant electrode material for compact and miniaturized energy storage equipment in the further.

20.
J Phys Chem B ; 120(45): 11834-11844, 2016 11 17.
Artigo em Inglês | MEDLINE | ID: mdl-27766876

RESUMO

Effective potentials are of great importance for coarse-grained (CG) simulations, which can be obtained by the structure-based iterative Boltzmann inversion (IBI) method. However, the standard IBI method is incapable of maintaining the mechanical and thermodynamic properties of the CG model in agreement with those of the all-atom model. Unlike the existing techniques, such as introducing friction force as the dissipative force to reduce the superatom motion while keeping the conservative force arising from the CG potential intact, we directly modified the standard IBI nonbonded potential by adding an empirical function. According to an analysis of the dissipative particle dynamics, the additional function did compensate for the friction reduction of the standard IBI CG model. In this work, the thermal fluctuation information from the nonbonded radial distribution function was incorporated into the additional empirical function. As an illustration of the new CG force fields, we presented simulations of the stress-strain relation and thermodynamic properties in terms of cis-polyisoprene and compared the statistical structure information of the superatoms with those of the IBI CG model and the all-atom model. It should be emphasized that the additional empirical function contributed to compensating for the friction reduction, irrespective of the functional form it took. In this sense, the proposed method was easily operable.

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