RESUMO
In this study, a Ti3C2 MXene@g-C3N4 composite powder (TM-CN) was prepared by the ultrasonic self-assembly method and then loaded onto a carbon nanofiber membrane by the self-assembly properties of MXene for the treatment of organic pollutants in wastewater. The characterization of the TM-CN and the C-TM-CN was conducted via X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared spectrometer (FTIR) to ascertain the successful modification. The organic dye degradation experiments demonstrated that introducing an appropriate amount of Ti3C2 MXene resulted in the complete degradation of RhB within 60 min, three times the photocatalytic efficiency of a pure g-C3N4. The C-TM-CN exhibited the stable and outstanding photocatalytic degradation of the RhB solution over a wide range of pH values, indicating the characteristics of the photodegradation of organic pollutants in a wide range of aqueous environments. Furthermore, the results of the cyclic degradation experiments demonstrated that the C-TM-CN composite film maintained a degradation efficiency of over 85% after five cycles, thereby confirming a notable improvement in its cyclic stability. Consequently, the C-TM-CN composite film exhibits excellent photocatalytic performance and is readily recyclable, making it an auspicious eco-friendly material in water environment remediation.
RESUMO
In this study, two natural clay minerals were combined with hydrogels to study the influence of natural adsorbents on the adsorption performance of hydrogels. Here, we separately doped bentonite and vermiculite and discussed their mechanical properties and adsorption properties. It was found that the compressive performance of the hydrogel added with clay increased by 21.6% and the swelling performance decreased or increased to varying degrees. Regarding the adsorption performance of hydrogels, it can be seen from the adsorption Langmuir isotherm model that the adsorption capacity of clay-hydrogels is improved to varying degrees (6.6%-15.8%) compared with non-clay-hydrogels, and clay-hydrogels have different degrees of improvement (6.6%-15.8%). The hydrogel has a removal efficiency of more than 95% for low concentrations of heavy-metal ions and dyes. In addition, the clay-hydrogel has low cost and is easy to prepare, and can be recycled many times. Therefore, the material is of great significance for the treatment of pollutants. PRACTITIONER POINTS: The effect of natural clay on the adsorption performance of hydrogels was studied. Clay can enhance the compression and adsorption properties of hydrogels. The adsorption mechanism and adsorption capacity of clay hydrogels were evaluated.
