A facile synthesis of a copper(I) thiourea sulphate complex and its application for highly efficient chalcopyrite solar cells.

The precursor compound plays a crucial role in the development of low-cost chalcogenide thin-film solar cells via a solution approach. In this work, we report on the synthesis of a new complex [Cu((NH2)2CS)3]2SO4·H2O through a simple redox reaction between inexpensive Cu(CH3COO)2·H2O and thiourea (TU) in water. Using this complex as a copper source, a stable dimethylformamide solution was made and copper indium sulfoselenide CuIn(S,Se)2 thin film solar cells with a high efficiency of 12.2% have been demonstrated.

Multifunctional sodium alginate/chitosan-modified graphene oxide reinforced membrane for simultaneous removal of nanoplastics, emulsified oil, and dyes in water.

Membrane technology is widely recognized as an efficient and advanced approach for wastewater treatment. However, the development of environmentally friendly and versatile membranes capable of effectively removing multiple contaminants remains a significant challenge. Inspired by natural magnets, we developed a heterostructured membrane using biomass materials to achieve the efficient removal of multiple contaminants from wastewater. Specifically, a bionic three-layer SA/GO/CS composite membrane was prepared by using sodium alginate (SA) and chitosan (CS) to modify graphene oxide (GO), respectively, and then assembled to both sides of the glass fiber (GF) membrane. The composite membranes achieved 99.87 % and 97.10 % removal of NPs with particle sizes of 500 nm and 50 nm. Moreover, the membrane demonstrated superior separation performance for mixed wastewater, enabling effective treatment of a broad spectrum of contaminants. Additionally, the membrane exhibited excellent stability when exposed to strong acid and alkali environments and demonstrated good recyclability throughout the multiple contaminants removal process. The bionic membrane, prepared using a straightforward method proposed in this study, provides an effective approach for enhanced removal of multiple contaminants in water. These findings contribute to the advancement of eco-friendly and versatile wastewater treatment membranes, opening new possibilities for sustainable water purification technologies.

In situ doping lignin-derived carbon quantum dots on magnetic hydrotalcite for enhanced degradation of Congo Red over a wide pH range and simultaneous removal of heavy metal ions.

A new N, S-CQDs@Fe3O4@HTC composite was prepared by loading N, S carbon quantum dots (N, S-CQDs) derived from lignin on magnetic hydrotalcite (HTC) via an in-situ growth method. The characterization results showed that the catalyst had a mesoporous structure. These pores facilitate the diffusion and mass transfer of pollutant molecules inside the catalyst, allowing them to approach the active site smoothly. The catalyst performed well in the UV degradation of Congo red (CR) over a wide pH range (3-11), with efficiencies over 95.43 % in all cases. Even at a high NaCl content (100 g/L), the catalyst showed extraordinary CR degradation (99.30 %). ESR analysis and free radical quenching experiments demonstrated that OH and O2- were the main active species governing CR degradation. Besides, the composite had outstanding removal efficiency for Cu2+ (99.90 %) and Cd2+ (85.08 %) simultaneously due to the electrostatic attraction between the HTC and metal ions. Moreover, the N, S-CQDs@Fe3O4@HTC had excellent stability and recyclability during five cycles, making it free of secondary contamination. This work provides a new environment-friendly catalyst for the simultaneous removal of multiple pollutants and a waste-to-waste strategy for the value-added utilization of lignin.

Lignin microparticles-reinforced cellulose filter paper for simultaneous removal of emulsified oils and dyes.

The presence of multiple pollutants in wastewater, often with complex interactions, poses a significant challenge for conventional membranes to effectively remove multiple pollutants simultaneously. Herein, a lignin microparticles-reinforced cellulose filter paper (FP@AL-LS-DA) was fabricated via an aldol condensation between lignin and cellulose filter paper and cross-linking with dopamine hydrochloride (DA), which showed desired rejection of oil-in-water emulsions and dyes. Characterizations revealed that the addition of lignin and DA effectively narrowed the pore size (from 4.45 µm to 2.01 µm) and enhanced the rigidity and stability of the cellulose filter paper, thus making it not easily damaged in the water environment and showing excellent tolerance to strong acid and high-salt environments. The oil-in-water emulsions removal efficiency was higher than 99 % even after ten times usage, and the oil flux was kept stable at 52.54 L·m-2·h-1, indicating that FP@AL-LS-DA had outstanding reusability and stability. Remarkably, FP@AL-LS-DA showed excellent removal efficiency (>99 %) for complex pollutants containing dyes and oil-in-water emulsions. In this work, we demonstrate a lignin microparticles-reinforced cellulose filter paper that is simple to prepare and can efficiently separate oil-in-water emulsions and remove dyes.

Synthesis of cationic biomass lignosulfonate hydrogel for the efficient adsorption of Cr(VI) in wastewater with low pH.

In the present study, we synthesized a cationic lignosulfonate hydrogel (LS-g-P (AM-co-DAC)) by grafting acrylamide (AM) and acryloxyethyl trimethyl ammonium chloride (DAC) onto sodium lignosulfonate (LS) via free radical copolymerization. The solution pH, contact time, initial concentration, and temperature were comprehensively investigated through the static adsorption method for the adsorption behaviours of Cr(VI) by the hydrogel. The experimental results show that the best conditions were a temperature of 30°C, a dosage of 0.1 g, pH = 3, a concentration of 50 mg / L, and contact time = 2 h with removal efficiencies of above 70% and adsorption capacity of 18.14 mg·g-1. The adsorption process followed the Langmuir isothermal model, indicating monolayer adsorption, and the maximum adsorption capacity was 58.86 mg·g-1. Adsorption kinetics results show that the pseudo-second-order kinetic model dominated the adsorption process, and the adsorption activation energy was 5.489 kJ·mol-1. In addition, the adsorption involved spontaneous exothermic and entropy reduction. The combination of FT-IR, SEM, and XRD was used to characterize the structure and properties of the prepared hydrogel, and the adsorption mechanism was the result of electrostatic attraction, physical and chemical adsorption, and hydrogen bond. The hydrogel has good regenerative properties after desorption. Overall, this work synthesized an environmentally friendly biomass lignin-based hydrogel, which can be used as an adsorbent for the treatment of anionic pollutants, and explored a new method for the high-value utilization of industrial lignin.HighlightsNovel cationic lignosulfonate hydrogel (LS-g-P (AM-co-DAC)) was synthesized by a free radical method.SEM and XRD results confirmed the surface of the obtained hydrogel shows a 3D network structure and does not have a crystal structure.LS-g-P (AM-co-DAC) hydrogel adsorbent can selectively adsorb Cr6+ at pH 3.0.The adsorption conditions and the adsorption mechanism were studied in detail.Electrostatic interaction plays a key role in the adsorption of Cr6+.

Clinical characteristics of second primary malignancies among first primary malignancy survivors: A single-center study, 2005-2020.

The cancer survivor population is growing due to advances in detection and treatment. For improved long-term patient management, it is critical to examine the clinical characteristics and outcomes of second primary malignancies (SPMs). An SPM is defined as a second distinct pathological diagnosis, with the same or different origin as the first primary malignancy (FPM). In the present retrospective study, categorical clinical variables were compared between subgroups and the impact on overall survival was evaluated. A total of 1,188 patients with an FPM were included, of which 102 experienced an SPM (8.59%). When compared with the patients who did not develop an SPM, patients with an SPM were significantly older at first diagnosis, had a higher pathological stage and higher rates of biliary tract disease and thyroid disease. In addition, patients with an SPM were more likely to have received postoperative chemotherapy (28.43 vs. 12.16%, P<0.0001) and to be long-term consumers of cigarettes and alcohol (25.00 vs. 8.95%, P<0.05). In addition, an increase in the number of regimens received but not in the number of courses of chemotherapy was associated with a reduction in the time interval to SPM development. Non-small cell lung cancer (NSCLC) was the most common type of FPM (18.27%). In patients with NSCLC the occurrence of SPMs was relatively low (5.07%) and the SPM-associated mortality rate was 2.30%. Breast cancer was the second common type of FPM (12.09%). Patients with breast cancer had a relatively high likelihood of developing an SPM (9.30%), for which family history of malignancy and postoperative chemotherapy were identified as potential risk factors. Patients with stomach cancer were the most vulnerable to SPM (17.95%) and patients with digestive tract cancer had the longest time interval between the FPM and SPM development. In addition, thyroid adenoma was identified as a potential risk factor for SCLC. The findings of the present study may provide valuable guidance for the short- and long-term monitoring of FPM survivors.

Biomass-based materials for solar-powered seawater evaporation.

Clean and safe water is crucial to maintaining human life on earth. Solar-powered seawater desalination (SSD) is a promising and feasible way to use solar energy resources to overcome water scarcity. Among all the candidate materials for solar seawater evaporators, biomass-based materials stand out thanks to their excellent inherent natural structure, ease of preparation, low cost, and abundant resources. In this article, we review biomass-based materials, from angiosperms, algae, and fungi to animal materials and other atypical biomass materials, proposed for solar-powered seawater evaporation in the shape of the nanofluid, membrane, gels, composite sponge structures, composites Janus structures and other composites. The approaches for improving biomass-based solar seawater evaporators (BSSE) performance are emphasized, including optical absorption regulation, system thermal management optimization, adequate water supply, salt resistance, and effective steam condensate recovery. In the end, the opportunities and challenges of biomass-based materials for SSD are illustrated.

Characterization of the key aroma compounds in aged Chinese Xiaoqu Baijiu by means of the sensomics approach.

The aromatic characteristics of Xiaoqu Baijiu differ noticeably and were investigated using the sensomics approach. Aroma extract dilution analysis revealed more aroma-active compounds in aged Xiaoqu Baijiu than fresh Xiaoqu Baijiu, with 55 compounds identified with flavor dilution (FD) factors of ≥8. Using sensomics, 51 odorants were identified as important aroma compounds in aged Xiaoqu Baijiu. Omission models suggested that 3-hydroxy-4,5-dimethyl-2(5H)-furanone (sotolon), vanillin, and 3-(methylthio)propionaldehyde (methional) played critical roles in the overall aroma characteristics of aged Xiaoqu Baijiu. Furthermore, 1,1-dimethoxyethane, 3-methylbutanal, dimethyl trisulfide, ethyl acetate, and ethyl isovalerate also exhibited significant roles in the aroma characteristics of aged Xiaoqu Baijiu. This work may provide a better understanding on Chinese Xiaoqu Baijiu and the changes of aroma compounds during the aging process of liquor.

Synthesis of a functional biomass lignin-based hydrogel with high swelling and adsorption capability towards Acid Red 73.

In this study, sodium lignosulfonate (LS) was used as raw material. Acrylamide (AM) and acryloxyethyltrimethylammonium chloride (DAC) were grafted onto LS through the free radical graft copolymerisation to synthesise a functional biomass terpolymer lignin-based hydrogel adsorbent (LAD). The effects of different factors on the LAD adsorption of Acid Red (AR 73) were investigated through the static adsorption method. LAD adsorbed AR 73 (C0=100mg·L-1) for 2 h to reach equilibrium, and the equilibrium adsorption capacity and removal rate were 47.59 mg·g-1 and 95.18%, respectively. The prepared LAD hydrogel swelling ratio for 2 h was 25 g·g-1, and the water loss rate in ethanol solvent in 120 min was 93.51%. The adsorption of AR 73 by LAD was consistent with the Langmuir isotherm adsorption model. This adsorption was a single-molecule adsorption with a maximum adsorption capacity of 409.84 mg·g-1. The adsorption was a process of spontaneous heat release and entropy reduction. The adsorption kinetic was in accordance with the pseudo-second-order model, and the adsorption activation energy was 2.501 kJ·moL-1. Moreover, the mechanism of adsorption was electrostatic attraction, and comprehensive effects of physical, and chemical adsorption and hydrogen bond. The LAD hydrogel adsorbent has a remarkable adsorption effect on AR 73, and can be used as an efficient and recyclable biomass adsorbent for the treatment of anionic dye wastewater.

Expression and Significance of TRIM 28 in Squamous Carcinoma of Esophagus.

Tripartite motif-containing protein 28 (TRIM28) has been proved to accelerate cell proliferation and metastasis in a variety of human cancers. However, the role of TRIM28 in esophageal squamous cell carcinoma (ESCC) remains unclear. In this study, to compare the biological effect and significance of TRIM28 expression in ESCC, immunohistochemistry (streptavidin-perosidase, S-P) method was used firstly to examine the expression of TRIM28 in 136 cases of ESCC, 35 cases of high grade intraepithelial neoplasia (HGIN), 29 cases of low grade intraepithelial neoplasia (LGIN) and 37 cases of normal esophageal epithelium (NEE). Then the associations of TRIM28 expression with clinicopathological data and overall survival (OS) were also analyzed. Western blot was performed to evaluate TRIM28 protein in a total of 20 matched human ESCC and NEE tissues. Moreover, the localization of TRIM28 protein in ESCC and NEE tissues was also detected by immunofluorescence. TRIM28 protein was mainly distributed in the nucleus of ESCC. The expression of TRIM28 increased progressively from NEE to LGIN, to HGIN, and to ESCC, and it was also related to invasive depth, pTNM stage and lymph node metastasis in ESCC (P < 0.05). The results of western blot and immunofluorescence all showed that the relative expression of TRIM28 protein was markedly upregulated in ESCC compared with the NEE tissues (P < 0.01). However, prognostic analysis showed that TRIM28 may not be a prognostic factor of patients with ESCC. In conclusion, the overexpression of TRIM28 may play an important role for development and metastasis in ESCC.