1.
Chem Commun (Camb)
; 54(58): 8060-8063, 2018 Jul 17.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29967915
RESUMO
A gradual change of BrN bond lengths and strengths from the values typical for intermolecular associates to that characteristic of a covalent bond was observed in a series of halogen-bonded complexes. This continuum reveals a fundamental relationship between the limiting types of bonding and implies the onset of covalency in the intermolecular interactions.