Seeding fiber amplifiers with piecewise parabolic phase modulation for high SBS thresholds and compact spectra.

We propose using piecewise parabolic phase modulation of the seed laser for suppressing stimulated Brillouin scattering (SBS) in a fiber amplifier. Simulations are run with a 9 m passive fiber. Compared with random phase modulation and 0-π pseudo-random phase modulation, the piecewise parabolic phase waveform yields a higher SBS threshold per unit bandwidth. If the bandwidth is defined as the range of frequencies containing 85% of the total power, the threshold for parabolic phase modulation is 1.4 times higher than the threshold for the five- or seven-bit pseudo-random modulation format. If the bandwidth is defined more tightly, e.g., the range of frequencies containing 95% of the total power, the threshold for parabolic phase modulation is three times higher. For both cases, achieving a bandwidth of 1.5 GHz requires a maximum phase shift of ~30 radians. All of the waveforms are compared on the basis of the bandwidth required of the phase moduator. The coherence functions are calculated in order to compare their suitability for coherent combining.

1.6 kW Yb fiber amplifier using chirped seed amplification for stimulated Brillouin scattering suppression.

In a high power fiber amplifier, a frequency-chirped seed interrupts the coherent interaction between the laser and Stokes waves, raising the threshold for stimulated Brillouin scattering (SBS). Moving the external mirror of a vertical cavity surface-emitting diode laser 0.2 µm in 10 µs can yield a frequency chirp of 5×1017 Hz/s at a nearly constant output power. Opto-electronic feedback loops can linearize the chirp, and stabilize the output power. The linear variation of phase with time allows multiple amplifiers to be coherently combined using a frequency shifter to compensate for static and dynamic path length differences. The seed bandwidth, as seen by the counter-propagating SBS, also increases linearly with fiber length, resulting in a nearly-length-independent SBS threshold. Experimental results at the 1.6 kW level with a 19 m delivery fiber are presented. A numerical simulation is also presented.

Phase-locking and coherent power combining of broadband linearly chirped optical waves.

We propose, analyze and demonstrate the optoelectronic phase-locking of optical waves whose frequencies are chirped continuously and rapidly with time. The optical waves are derived from a common optoelectronic swept-frequency laser based on a semiconductor laser in a negative feedback loop, with a precisely linear frequency chirp of 400 GHz in 2 ms. In contrast to monochromatic waves, a differential delay between two linearly chirped optical waves results in a mutual frequency difference, and an acoustooptic frequency shifter is therefore used to phase-lock the two waves. We demonstrate and characterize homodyne and heterodyne optical phase-locked loops with rapidly chirped waves, and show the ability to precisely control the phase of the chirped optical waveform using a digital electronic oscillator. A loop bandwidth of ~ 60 kHz, and a residual phase error variance of < 0.01 rad(2) between the chirped waves is obtained. Further, we demonstrate the simultaneous phase-locking of two optical paths to a common master waveform, and the ability to electronically control the resultant two-element optical phased array. The results of this work enable coherent power combining of high-power fiber amplifiers-where a rapidly chirping seed laser reduces stimulated Brillouin scattering-and electronic beam steering of chirped optical waves.

Using a volume Bragg grating instead of a Faraday isolator in lasers incorporating stimulated Brillouin scattering wavefront reversal or beam cleanup.

A master-oscillator power-amplifier with stimulated Brillouin scattering (SBS) beam cleanup or wavefront reversal typically incorporates a Faraday isolator to outcouple the Stokes light, limiting the power scalability. Volume Bragg gratings (VBGs) have the potential for scaling to higher powers. We report here the results of tests on a VBG designed to resolve wavelengths 0.060 nm apart, corresponding to the 16 GHz frequency shift for SBS backscattering at 1064 nm in fused silica. Such an element may also find use in between stages of fiber amplifiers, for blocking the Stokes wave.

Optically fabricated three dimensional nanofluidic mixers for microfluidic devices.

This paper describes a simple technique for fabricating complex, but well defined, three-dimensional (3D) networks of nanoscale flow paths in the channels of microfluidic systems. Near field scanning optical measurements reveal the optics associated with the fabrication process and the key features that enable its application to the area of microfluidics. Confocal studies of microfluidic devices that incorporate 3D nanostructures formed using this approach show that they function as efficient passive mixing elements, particularly at low Reynolds numbers. This application and others such as separation and extraction inmicrofluidic total analysis systems or lab on a chip devices represent promising areas for 3D nanostructures of this general type.

Phase correction of interferograms using digital all-pass filters.

A method for the phase correction of interferograms in Fourier transform infrared spectroscopy is presented. It is shown that phase error can be canceled to within an arbitrary angular precision by a low-order digital all-pass filter. Such a filter only modifies the phase of the Fourier transform of the interferogram and keeps the magnitude unchanged, like the Mertz method, for example. However, our method minimizes the asymmetric apodization that results in photometric errors when using the Mertz method alone. A practical example is provided in which phase correction over a frequency range of 800 cm(-1) to 4000 cm(-1) using a 9-pole all-pass filter resulted in a photometric error of <0.01%, much less than the 0.3% error of the Mertz method. An alternative and faster (approximately 100 ms) approach is to use an all-pass filter with lower angular precision followed by the Mertz method. Removing most of the phase error with the filter brings the interferogram to an optimal state so that the residual phase error can be completely removed with the Mertz procedure without introducing photometric error. The method can be used in most experiments, including emission spectroscopy, where conventional techniques are inadequate. A simple all-pass filter design algorithm is given.

Diffraction-based solid immersion lens.

A solid immersion lens based on diffraction (dSIL) is proposed as an alternative to the conventional design based on refraction. A design analogous to a Fresnel zone plate is derived in accordance with the Huygens-Fresnel principle. Fabrication of a binary dSIL is achieved by electron-beam lithography and reactive-ion etching on LaSF35, with index n = 2.014. Measurement of the point-spread function is performed with near-field optical microscopy. The results are in accord with the expected resolution enhancement of a factor n with respect to the diffraction limit.

Thermal conductivity imaging at micrometre-scale resolution for combinatorial studies of materials.

Combinatorial methods offer an efficient approach for the development of new materials. Methods for generating combinatorial samples of materials, and methods for characterizing local composition and structure by electron microprobe analysis and electron-backscatter diffraction are relatively well developed. But a key component for combinatorial studies of materials is high-spatial-resolution measurements of the property of interest, for example, the magnetic, optical, electrical, mechanical or thermal properties of each phase, composition or processing condition. Advances in the experimental methods used for mapping these properties will have a significant impact on materials science and engineering. Here we show how time-domain thermoreflectance can be used to image the thermal conductivity of the cross-section of a Nb-Ti-Cr-Si diffusion multiple, and thereby demonstrate rapid and quantitative measurements of thermal transport properties for combinatorial studies of materials. The lateral spatial resolution of the technique is 3.4 microm, and the time required to measure a 100 x 100 pixel image is approximately 1 h. The thermal conductivity of TiCr(2) decreases by a factor of two in crossing from the near-stoichiometric side of the phase to the Ti-rich side; and the conductivity of (Ti,Nb)(3)Si shows a strong dependence on crystalline orientation.

Picosecond laser for performance of efficient nonlinear spectroscopy from 10 to 21 microm.

Laser tunability from 10 to 21 microm is obtained by use of an optical parametric oscillator based on a KTP crystal followed by a difference-frequency stage with a CdSe crystal. An all-solid-state picosecond Nd:YAG oscillator mode locked by a frequency-doubling nonlinear mirror is used for synchronous pumping.

Infrared-visible sum frequency generation investigation of Cu corrosion inhibition with benzotriazole.

Infrared-visible sum frequency generation spectroscopy is used to investigate the corrosion inhibitor benzotriazole (BTAH) adsorbed on Cu(100) and Cu(111) in acidic solution. Potential-dependent in situ spectra indicate that the adsorbed molecule is the benzotriazole anion (BTA-) at all potentials investigated. The Cu(100) surface is shown to form an ordered adlayer at all potentials probed, while the Cu(111) face is shown to be disordered at negative potentials, but to order with applied positive potential. The ordered adlayer is shown to consist of the BTA- in two configurations, one coordinated to the surface and Cu+ ions in solution and the other coordinated only to the surface. The BTA- coordinated to Cu+ is shown to be more stable with respect to Cl- addition than BTA- coordinated to only the surface. This study demonstrates the viability of using sum frequency generation to study corrosion inhibition in situ.