Using Smooth Metamers to Estimate Color Appearance Metrics for Diverse Color-Normal Observers.

Color-normal subjects sometimes disagree about metameric matches involving highly structured SPDs, because their cone fundamentals differ slightly, but non-negligibly. This has significant implications for the design of light sources and displays, so it should be estimated. We propose a broadly applicable estimation method based on a simple adaptive "front-end" interface that can be used with any selected standard color appearance model. The interface accepts, as input, any set of color matching functions for the individual subject (for example, these could be that person's cone response functions) and also the associated tristimulus values for the test stimulus and also for the reference stimulus (i.e. reference white). The interface converts this data into tristimulus values of the form used by the selected color appearance model (which could, for example, be X, Y, Z), while also carrying out the needed transform, which is based on an estimate of the subject's likely previous long-term adaptations to their unique cone fundamentals. The selected standard color appearance model then provides color appearance data that is an estimate of the color appearance of the test stimulus, for that individual subject. This information has the advantage of being interpretable within that model's well-known color space. The adaptive front end is based on the fact that, for any selected input SPD and the subject's unique color matching functions, there can be many different SPDs that are metameric for that individual. Since observer-to-observer color perception differences are minimized for spectrally smooth SPDs, smooth metamers predict color appearances reasonably accurately.

Color appearance model incorporating contrast adaptation - implications for individual differences in color vision.

Color appearance models use standard color matching functions to derive colorimetric information from spectral radiometric measurements of a visual environment, and they process that information to predict color perceptual attributes such as hue, chroma and lightness. That processing is usually done by equations with fixed numerical coefficients that were predetermined to yield optimal agreement for a given standard observer. Here we address the well-known fact that, among color-normal observers, there are significant differences of color matching functions. These cause disagreements between individuals as to whether certain colors match, an important effect that is often called observer metamerism. Yet how these individual sensitivity differences translate into differences in perceptual metrics is not fully addressed by many appearance models. It might seem that appearance could be predicted by substituting an individual's color matching functions into an otherwise-unchanged color appearance model, but this is problematic because the model's coefficients were not optimized for the new observer. Here we explore a solution guided by the idea that processes of adaptation in the visual system tend to compensate color perception for differences in cone responses and consequent color matching functions. For this purpose, we developed a simple color appearance model that uses only a few numerical coefficients, yet accurately predicts the perceptual attributes of Munsell samples under a selected standard lighting condition. We then added a feedback loop to automatically adjust the model coefficients, in response to switching between cone fundamentals simulating different observers and color matching functions. This adjustment is intended to model long term contrast adaptation in the vision system by maintaining average overall color contrast levels. Incorporating this adaptation principle into color appearance models could allow better assessments of displays and illumination systems, to help improve color appearances for most observers.

Graphene-based bidirectional radiative thermal transfer method for heat engines.

We present a method for substantially enhancing the rate of heat transfer into and out of the working fluid of a heat engine, using bidirectional thermal radiation exchange between the external environment and many individual graphene layers that are dispersed and suspended within an inert gas. This hybrid working fluid has the unique composite property of high optical absorption/emission yet low specific heat. Consequently, it can heat and cool rapidly, enabling a much greater cycle frequency and a commensurate increase in specific power, in comparison to conventional closed-cycle heat engines for which the cycle frequency is limited by the use of slower, non-radiative, thermal transfer.

A simple principled approach for modeling and understanding uniform color metrics.

An important goal in characterizing human color vision is to order color percepts in a way that captures their similarities and differences. This has resulted in the continuing evolution of "uniform color spaces," in which the distances within the space represent the perceptual differences between the stimuli. While these metrics are now very successful in predicting how color percepts are scaled, they do so in largely empirical, ad hoc ways, with limited reference to actual mechanisms of color vision. In this article our aim is to instead begin with general and plausible assumptions about color coding, and then develop a model of color appearance that explicitly incorporates them. We show that many of the features of empirically defined color order systems (those of Munsell, Pantone, NCS, and others) as well as many of the basic phenomena of color perception, emerge naturally from fairly simple principles of color information encoding in the visual system and how it can be optimized for the spectral characteristics of the environment.

Electrically controlled diffraction employing electrophoresis, supercapacitance, and total internal reflection.

The reflectance of a surface can be altered by controlling the concentration of dye ions in a region adjacent to an optically transparent and electrically conductive thin film. We present a method for nonmechanical light deflection achieved by altering the reflectance of a diffraction grating, an approach that creates new diffraction peaks that lie between those associated with the original grating spacing. We have demonstrated this effect by applying an electrical potential difference between interdigitated indium-tin oxide (ITO) electrodes and measuring the intensity of one of the new diffraction peaks. The measured diffraction peak intensities were found to reversibly deflect approximately 7% of the reflected light to previously nonexistent peaks. The diffraction grating was formed by patterning a thin film of planar, untreated ITO on a glass substrate using standard photolithography techniques. The size scale for this method of electrically controlled diffraction is limited only by the lithographic process; thus there is potential for the grating to deflect light to angles greater than those achievable using other methods. This approach could be used in applications such as telecommunications, where large deflection angles are required, or other applications where alternate beam-steering methods are cost prohibitive.

Modified point spread function for efficient high dynamic range LED backlight capable of high uniformity, high contrast, and smooth gradients.

We investigate the effect of new point spread functions (PSFs) on the uniformity and contrast of high dynamic range displays that use local dimming of LEDs to yield a large dynamic range. A PSF shaped like a quadratic B-spline was hypothesized to create a uniform brightness backlight, as well as producing linear and quadratic gradients, while maintaining a very high contrast. We have found a practical optical structure to produce such a PSF, yielding a nonuniformity of only ±0.8%, while enabling a contrast ratio of 5∶1 and 33∶1 over distances of one and two unit cell spacings, respectively.

Electrochemical threshold conditions during electro-optical switching of ionic electrophoretic optical devices.

Electro-optical modulation by electrophoresis of dye ions is a promising technique for applications such as electronic paper displays and nonmechanical beam steering devices. To achieve a sufficient response rate in these devices, the transition time between two different optical states can be decreased by increasing the magnitude of the voltage applied across the electrodes, but this also leads to irreversible and undesirable electrochemical reactions. An electron tunneling model has been developed to describe the electrochemical reaction and to better understand the conditions determining its onset. The model gives rise to three predictions that were subsequently confirmed experimentally: the magnitude of the applied surface charge density should determine the rate of electrochemical activity, the bulk concentration of ions in the solution should shift the threshold voltage at which electrochemical reactions occur, and the reaction rate should be substantially enhanced around nanometer-sized bumps on the electrode surface. Applying this new understanding, the transition time of a device incorporating porous zinc antimonate (ZnSb2O6) electrodes and a solution of Methylene Blue dye in methanol was reduced by a factor of approximately 20.

A new model of protein adsorption kinetics derived from simultaneous measurement of mass loading and changes in surface energy.

We describe a novel technology based on changes in the resonant frequency of an acoustically actuated surface and use it to measure temporal changes in the surface energy gamma (N m(-1)) of an elastomeric polymer membrane due to the adsorption of macromolecules from aqueous solution. The resonant elastomeric surface-tension (REST) sensor permits simultaneous determination of mass loading kinetics and gamma(t) for a given adsorption process, thereby providing a multivariable data set from which to build and test models of the kinetics of adsorption at solid-liquid interfaces. The technique is used to measure gamma(t) during the adsorption of either sodium dodecyl sulfate (SDS) or hen egg-white lysozyme (HEWL) onto an acrylic polymer membrane. The adsorption of SDS is reversible and is characterized by a decrease in gamma over a time period that coincides with that required for the mass loading of the membrane. For the adsorption of HEWL labeled with Alexa Fluor 532 dye, gamma continues to change long after the surface concentration of labeled HEWL, measured by using the elastomeric polymer membrane as an optical waveguide, reaches steady state. Gradual but significant changes in gamma(t) are observed as long as the concentration of protein in the bulk solution, c(b), remains nonzero. HEWL remains adsorbed to the membrane when c(b) = 0, but changes in gamma(t) are not observed under this condition, indicating that the interaction of bound protein molecules with those free in solution contribute to the prolonged change in the surface energy. This observation has been used to define a new model for the kinetics of globular protein adsorption to a solid-liquid interface that includes a mechanism by which the molecules in the bulk can facilitate the desorption of a sorbate molecule or change the energetic states of adsorbed molecules and, thus, the overall surface energy. The model is shown to capture the unique features of protein adsorption kinetics, including the relatively fast mass loading, the much more gradual change in surface energy that does not cease until the protein is removed from the bulk, the rapid desorption of an incubation-time-dependent fraction of bound protein when the protein is removed from the bulk, and the fixing of the residual surface concentration and surface energy at constant values once the removal of reversibly bound protein and free protein is complete.

Control of reflection at an optical interface in the absence of total internal reflection for a retroreflective display application.

Reflection at an interface between two materials can be modulated by means of varying the optical properties at the interface. We have studied this modulation of the reflected light with an aim to develop a flashing retroreflector for roadside conspicuity applications. Reflectance modulation has previously been studied under the conditions of total internal reflection (TIR), where a light-absorbing material placed in the associated evanescent wave region can be used to attenuate the intensity of the reflected light. If instead the light rays strike the interface at an angle that is slightly smaller than the critical angle required for TIR, they instead undergo a substantial, but partial, reflection. We have demonstrated that an analogous attenuation effect to the TIR situation is observed, even though there is no evanescent wave present under these circumstances. We have studied this behavior and have developed a model to describe the motion of the absorbing material and the related interference effects that occur.

Controlled frustration of total internal reflection by electrophoresis of pigment particles.

A model based on geometrical optics has been developed to describe the photometric observations associated with a novel method to control the reflectance of a surface. In this new reflectance modulation approach, electrophoresis of pigment particles is used to absorb light reflected by total internal reflection (TIR). The pigment particles are sufficiently small that they substantially do not scatter light, but rather they modify the effective refractive index at the reflection interface. An incident light ray interacting with this modified effective index is attenuated in a spectrally selective manner. Although frustrated TIR has been understood and used in various applications for some time, in this case it is used to substantially modify the color of the reflected light, which to our knowledge has not been previously reported. A numerical model of the pigment particle distribution has been developed to describe the observations.

Novel electrophoresis mechanism based on synchronous alternating drag perturbation.

We present a novel means of transporting molecules in solution by applying a zero-time-average alternating motive force to the molecules, and perturbing the molecular drag coefficient synchronously with the applied force, thus causing a net drift in a direction determined by the phase of the alternating drag perturbation relative to the alternating force. We apply an electrophoretic form of the method to transport and concentrate DNA in a gel, such that all molecules migrate on average away from the nearest electrode and toward a central region. Since an electrode does not occupy this central region, this method presents the possibility of transporting and focusing DNA and other charged molecules in regions free from electrodes and the associated electrochemistry.

Control of reflectance of liquid droplets by means of electrowetting.

It has recently been noted that hemispherical structures have useful reflection characteristics. We describe a new application that makes use of these characteristics by controlling the reflectance of a surface composed of an array of hemispherical liquid droplets. In this system the reflectance state is spatially controlled through the use of electrowetting to alter the shape of an array of droplets. This may have an application in the field of electronic image displays.

Modulation of retroreflection by controlled frustration of total internal reflection.

Retroreflective images are useful in outdoor application for which high legibility is required both during the day and in response to vehicular illumination. To date, all variable message retroreflective images have employed mechanical shutters as the switching mechanism. As an alternative, we propose a method for switching the total internal reflection effect used in retroreflectors by means of pneumatic actuation of surface treated polydimethylsiloxane gel. This approach is both effective and compatible with current large-scale manufacturing methods.

Electrical modulation of diffractive structures.

We present an experimental demonstration of two new methods for electronically modulating diffractive structures. The first involves the creation of periodic displacement of a liquid-air interface by application of a spatially modulated electric field produced by an array of electrodes. The second method also uses an electrode array but creates a diffraction grating by selectively attracting and repelling electrophoretic particles in a dielectric fluid. Potential areas of application of these techniques include controllable holography and wavelength division multiplexing.

Navigational range lights: effect of stimulus configuration on alignment accuracy.

The use of range lights in nautical navigation involves the visual determination of the vertical alignment of two points of light, in order to indicate the centre of the channel. In two experiments it is shown that this vernier alignment task is more accurate if illuminated linear stimuli are used as range lights. Experiment 1 involved a laboratory simulation and experiment 2 involved a field test with full sized range lights. The average reduction of error through the use of linear stimuli over the standard point stimuli, for navigational alignments at a distance of one-half nautical mile from the range lights, was 69-4%. This suggests that a marked safety advantage might accrue from the use of linear range lights for nautical navigation purposes.