Sunlight-Driven Photochemical Removal of Polypropylene Microplastics from Surface Waters Follows Linear Kinetics and Does Not Result in Fragmentation.

Floating microplastics are susceptible to sunlight-driven photodegradation, which can convert plastic carbon to dissolved organic carbon (DOC) and can facilitate microplastic fragmentation by mechanical forces. To understand the photochemical fate of sub-millimeter buoyant plastics, ∼0.6 mm polypropylene microplastics were photodegraded while tracking plastic mass, carbon, and particle size distributions. Plastic mass loss and carbon loss followed linear kinetics. At most time points DOC accumulation accounted for under 50% of the total plastic carbon lost. DOC accumulation followed sigmoidal kinetics, not the exponential kinetics previously reported for shorter irradiations. Thus, we suggest that estimates of plastic lifespan based on exponential DOC accumulation are inaccurate. Instead, linear plastic-C mass and plastic mass loss kinetics should be used, and these methods result in longer estimates of photochemical lifetimes for plastics in surface waters. Scanning electron microscopy revealed that photoirradiation produced two distinct patterns of cracking on the particles. However, size distribution analyses indicated that fragmentation was minimal. Instead, the initial population of microplastics shrank in size during irradiations, indicating photoirradiation in tranquil waters (i.e., without mechanical forcing) dissolved sub-millimeter plastics without fragmentation.

Climatic control of Mississippi River flood hazard amplified by river engineering.

Over the past century, many of the world's major rivers have been modified for the purposes of flood mitigation, power generation and commercial navigation. Engineering modifications to the Mississippi River system have altered the river's sediment levels and channel morphology, but the influence of these modifications on flood hazard is debated. Detecting and attributing changes in river discharge is challenging because instrumental streamflow records are often too short to evaluate the range of natural hydrological variability before the establishment of flood mitigation infrastructure. Here we show that multi-decadal trends of flood hazard on the lower Mississippi River are strongly modulated by dynamical modes of climate variability, particularly the El Niño-Southern Oscillation and the Atlantic Multidecadal Oscillation, but that the artificial channelization (confinement to a straightened channel) has greatly amplified flood magnitudes over the past century. Our results, based on a multi-proxy reconstruction of flood frequency and magnitude spanning the past 500 years, reveal that the magnitude of the 100-year flood (a flood with a 1 per cent chance of being exceeded in any year) has increased by 20 per cent over those five centuries, with about 75 per cent of this increase attributed to river engineering. We conclude that the interaction of human alterations to the Mississippi River system with dynamical modes of climate variability has elevated the current flood hazard to levels that are unprecedented within the past five centuries.