Time-resolved polarimetry over water waves: relating glints and surface statistics.

The phenomenon of sunglint, well known in satellite remote sensing, lacks a fundamental characterization under controlled laboratory conditions. Exploiting an apparatus specifically assembled for the purpose, we examine the signal collected by a photopolarimeter, pointed at a wavy water surface with measurable statistics and illuminated by a laser source. We also analyze the wave slope distributions, retrieved with an imaging system, and correlate them with the time series of glints. More particularly, we investigate the link between the occurrence of glints and that of the slopes from which they originate. In this context, the results obtained by applying the Hilbert-Huang transform technique to the slope time series are compared with those obtained through a traditional Fourier transform. This novel study first identifies the individual atomic glints as Fresnel reflection originating from a single wave facet. It then discusses the periodic character of a sequence of glints generated by a gravity wave state, as opposed to the erratic behavior of glints typical of capillary wave states. In mixed gravity-capillary conditions, it is shown that the glint properties are governed mainly by the capillary regime.

Asymptotic solutions for optical properties of large particles with strong absorption.

The transverse wave condition is not applicable to the refracted electromagnetic wave within the context of geometrical optics when absorption is involved. Either the TM or the TE wave condition can be assumed for the wave to locally satisfy the electromagnetic boundary condition in a ray-tracing calculation. The assumed wave mode affects both the reflection and the refraction coefficients. As a result, nonunique solutions for these coefficients are inevitable. In this study the appropriate solutions for the Fresnel reflection-refraction coefficients are identified in light-scattering calculations based on the ray-tracing technique. In particular, a 3 x 2 refraction or transmission matrix is derived to account for the inhomogeneity of the refracted wave in an absorbing medium. An asymptotic solution that completely includes the effect of medium absorption on Fresnel coefficients is obtained for the scattering properties of a general polyhedral particle. Numerical results are presented for hexagonal plates and columns with both preferred and random orientations.

Scattering from nonspherical Chebyshev particles. 3: Variability in angular scattering patterns.

We study shape-induced variability in the scattered intensity from randomly oriented nonspherical particles. Up to 21 different Chebyshev shapes contribute to defining a shape-induced standard deviation about each of the mean nonspherical intensity vs angle curves shown in part 2 of this series. Bands of shape-induced variability (defined as plus and minus one standard deviation) for six size intervals within the size parameter range 1

Scattering from nonspherical Chebyshev particles. 2: Means of angular scattering patterns.

The calculated angular scattering properties of over 250 randomly oriented nonspherical Chebyshev particles are examined for the effect of three factors: size; concavity vs convexity; and amount of deformation from a sphere. Both shape and size averaging are performed to reveal general features of the angular scattering not discernible for particular shapes and sizes. Comparisons with a comparably extensive experimental study published by Zerull in 1976 reveal remarkable qualitative similarities, even though Zerull used greatly different shapes from ours. This augurs well for the eventual development of a general theory of nonspherical scattering, although such a theory must account for concavity in addition to the amount of deviation from a sphere; and it cannot be entirely deterministic, as the third paper in this series will argue.

Numerically stable algorithm for discrete-ordinate-method radiative transfer in multiple scattering and emitting layered media.

We summarize an advanced, thoroughly documented, and quite general purpose discrete ordinate algorithm for time-independent transfer calculations in vertically inhomogeneous, nonisothermal, plane-parallel media. Atmospheric applications ranging from the UV to the radar region of the electromagnetic spectrum are possible. The physical processes included are thermal emission, scattering, absorption, and bidirectional reflection and emission at the lower boundary. The medium may be forced at the top boundary by parallel or diffuse radiation and by internal and boundary thermal sources as well. We provide a brief account of the theoretical basis as well as a discussion of the numerical implementation of the theory. The recent advances made by ourselves and our collaborators-advances in both formulation and numerical solution-are all incorporated in the algorithm. Prominent among these advances are the complete conquest of two illconditioning problems which afflicted all previous discrete ordinate implementations: (1) the computation of eigenvalues and eigenvectors and (2) the inversion of the matrix determining the constants of integration. Copies of the FORTRAN program on microcomputer diskettes are available for interested users.

Forward optical glory.

Forward optical glory effects in Mie scattering are displayed here for the first time to our knowledge. These effects include regular oscillations in Mie efficiency factors and characteristic deviations from zero polarization in near-forward scattering, which are observable for real refractive indices near radical2 and 2. Complex angular momentum theory predicts the period of oscillation correctly and shows the important role played by surface waves with shortcuts through the sphere. Three possible types of experiment for detecting the forward glory are proposed, involving measurements of extinction, radiation pressure, and polarization in near-forward scattering.

Improved Mie scattering algorithms.

Scattering of electromagnetic radiation from a sphere, so-called Mie scattering, requires calculations that can become lengthy and even impossible for those with limited resources. At the same time, such calculations are required for the widest variety of optical applications, extending from the shortest UV to the longest microwave and radar wavelengths. This paper briefly describes new and thoroughly documented Mie scattering algorithms that result in considerable improvements in speed by employing more efficient formulations and vector structure. The algorithms are particularly fast on the Cray-1 and similar vector-processing computers.