Contribution to Knowledge on Bioapatites: Does Mg Level Reflect the Organic Matter and Water Contents of Enamel?

The matter constituting the enamels of four types of organisms was studied. The variability of the ions was presented in molar units. It was proven that the changes in water contents of the enamel are significantly positively related to changes in Mg; inversely, there is also a strong connection with changes in Ca and P, the main components of bioapatite. The variability in the organic matter has the same strong and positive characteristics and is also coupled with changes in Mg contents. Amelogenins in organic matter, which synthesize enamel rods, likely have a role in adjusting the amount of Mg, thus establishing the amount of organic matter and water in the whole enamel; this adjustment occurs through an unknown mechanism. Ca, P, Mg, and Cl ions, as well as organic matter and water, participate in the main circulation cycle of bioapatites. The selection of variations in the composition of bioapatite occurs only along particular trajectories, where the energy of transformation linearly depends on the following factors: changes in the crystallographic d parameter; the increase in the volume, V, of the crystallographic cell; the momentum transfer, which is indirectly expressed by ΔsinΘ value. To our knowledge, these findings are novel in the literature. The obtained results indicate the different chemical and crystallographic affinities of the enamels of selected animals to the human ones. This is essential when animal bioapatites are transformed into dentistic or medical substitutes for the hard tissues. Moreover, the role of Mg is shown to control the amount of water in the apatite and in detecting organic matter in the enamels.

Characterization of Biodegradable Food Contact Materials under Gamma-Radiation Treatment.

Radiation is an example of one of the techniques used for pasteurization and sterilization in various packaging systems. There is a high demand for the evaluation of the possible degradation of new composites, especially based on natural raw materials. The results of experimental research that evaluated the impact of radiation technology on biodegradable and compostable packaging materials up to 40 kGy have been presented. Two commercially available flexible composite films based on aliphatic-aromatic copolyesters (AA) were selected for the study, including one film with chitosan and starch (AA-CH-S) and the other with thermoplastic starch (AA-S). The materials were subjected to the influence of ionizing radiation from 10 to 40 kGy and then tests were carried out to check their usability as packaging material for the food industry. The results showed that the mechanical properties of AA-S films improved due to the radiation-induced cross-linking processes, while in the case of AA-CH-S films, a considerable decrease in the elongation at break was observed. The results also showed a decrease in the WVTR in the case of AA-S and no changes in barrier properties in the case of AA-CH-S. Both materials revealed no changes in the odor analyzed by sensory analysis. In the case of the AA-S films, the higher the radiation dose, the faster the biodegradation rate. In the case of the AA-CH-S film, the radiation did not affect biodegradation. The performed research enables the evaluation of the materials intended for direct contact with food. AA-CH-S was associated with unsatisfactory parameters (exceeding the overall migration limit and revealing color change during storage) while AA-S showed compliance at the level of tests carried out. The study showed that the AA-CH-S composite did not show a synergistic effect due to the presence of chitosan.

Polysaccharide-Based Nanocomposites for Food Packaging Applications.

The article presents a review of the literature on the use of polysaccharide bionanocomposites in the context of their potential use as food packaging materials. Composites of this type consist of at least two phases, of which the outer phase is a polysaccharide, and the inner phase (dispersed phase) is an enhancing agent with a particle size of 1-100 nm in at least one dimension. The literature review was carried out using data from the Web of Science database using VosViewer, free software for scientometric analysis. Source analysis concluded that polysaccharides such as chitosan, cellulose, and starch are widely used in food packaging applications, as are reinforcing agents such as silver nanoparticles and cellulose nanostructures (e.g., cellulose nanocrystals and nanocellulose). The addition of reinforcing agents improves the thermal and mechanical stability of the polysaccharide films and nanocomposites. Here we highlighted the nanocomposites containing silver nanoparticles, which exhibited antimicrobial properties. Finally, it can be concluded that polysaccharide-based nanocomposites have sufficient properties to be tested as food packaging materials in a wide spectrum of applications.