The pH paradox.

This paper highlights the critical role of pH or proton activity measurements in environmental studies and emphasises the importance of applying proper statistical approaches when handling pH data. This allows for more informed decisions to effectively manage environmental data such as from mining influenced water. Both the pH and {H+} of the same system display different distributions, with pH mostly displaying a normal or bimodal distribution and {H+} showing a lognormal distribution. It is therefore a challenge of whether to use pH or {H+} to compute the mean or measures of central tendency for further environmental statistical analyses. In this study, different statistical techniques were applied to understand the distribution of pH and {H+} from four different mine sites, Metsämonttu in Finland, Felsendome Rabenstein in Germany, Eastrand and Westrand mine water treatment plants in South Africa. Based on the statistical results, the geometric mean can be used to calculate the average of pH if the distribution is unimodal. For a multimodal pH data distribution, peak identifying methods can be applied to extract the mean for each data population and use them for further statistical analyses.

Paleoenvironmental changes in river channel systems in alpine rockslide deposits exemplified by the Fernpass rockslide in the Tyrolian Außerfern District, Austria.

This paper describes the instability of river channel systems in alpine rockslide deposits using the Fernpass Rockslide and the river Loisach in the Tyrolian Außerfern District (Austria) as an example of paleoenvironmental developments. This is the first investigation of this kind of the Fernpass, one of the most important Alpine north-south transport connections since the bronze age. It uses geomorphological, sedimentological, onomastic and hydrogeological investigations to reconstruct the course of a late Holocene river in this area and a probabilistic simulation for dating. Tracer tests assisted in investigating the potential groundwater connections of the river systems. The findings show that the Palaeoloisach runs on the orographically right side in a marginal valley of the Fernpass furrow and changes to the orographically left side of the furrow within the Rauth suburb in the village of Biberwier. A probabilistic simulation of the Narrenbichl slip event, which changed the course of the Palaeoloisach, dates the event to an age of 664 ± 116 BC. This investigation is an important contribution to understanding Quaternary postrockslide developments, how groundwater contributes to forming postrockslide channel systems and archaeological findings occurring in populated areas.

Toxicity of polychlorinated biphenyls in aquatic environments - A review.

The assessment of polychlorinated biphenyls (PCBs) and their congeners resulting from the pollution of all environmental media is inherently related to its persistence and ubiquitous nature. In principle, determination of this class of contaminants are limited to the determination of their concentrations in the various environmental matrices. For solving many problems in this context, knowledge of the emission sources of PCBs, transport pathways, and sites of contamination and biomagnification is of great benefit to scientists and researchers, as well as many regulatory organizations. By far the largest amounts of PCBs, regardless of their discharged points, end up in the soil, sediment and finally in different aquatic environments. By reviewing relevant published materials, the source of origin of PCBs in the environment particularly from different pollution point sources, it is possible to obtain useful information on the nature of different materials that are sources of PCBs, or their concentrations and their toxicity or health effects and how they can be removed from contaminated media. This review focuses on the sources of PCBs in aquatic environments and critically reviews the toxicity of PCBs in aquatic animals and plants. The review also assesses the toxicity equivalency factors (TEFs) of PCBs providing valuable knowledge to other scientists and researchers that enables regulatory laws to be formulated based on selective determination of concentrations regarding their maximum permissible limits (MPLs) allowed. This review also supplies a pool of valuable information useful for designing decontamination technologies for PCBs in media like soil, sediment, and wastewaters.

Density stratification and double-diffusive convection in mine pools of flooded underground mines - A review.

Layering of water bodies with different physico-chemical properties is called stratification. This physical effect is known from lakes or oceans but also occurs in flooded underground mines and has been studied in the past. This review gives a summary of their investigation methods, flow dynamics, stratification development and breakdown. Furthermore, the barrier effect of stratification is discussed, meaning that less mineralized water bodies (CF water bodies) on the top are separated from higher mineralized water bodies (WM water bodies) in the lower parts of the mine. This separation causes less mineralized water to discharge from the flooded mine and mine water treatment can be reduced or omitted. Various options to study mine water stratification will be discussed, thereunder tracer tests, camera-aided depth profile measurements and depth dependant mine water sampling. Studies about free convection and natural stratification as well as those about using artificial stratification to encapsulate the lower quality water in the deeper mine parts will be presented. No forecasting tool for the existence or development of stratification in flooded mines was found in the literature. References and a discussion about the long-term stability of the stratification and its potential implementation will be given. The conclusions show that precise predictions of mine water stratification are currently not possible in all detail, but wherever stratification occurs, it is mostly stable over a longer period of time as the density difference between the CF and WM layers prevents their mixing.

The Whitehill Formation as a natural geochemical analogue to the Witwatersrand Basin's mine water issues, South Africa.

Mining activities within the Witwatersrand Basin, South Africa, have led to many studies, particularly focusing on the generation of acid mine drainage (AMD) in the basin and the associated environmental effects. This study assesses whether gypsum in the Whitehill Formation is connected to acid rock drainage (ARD) resulting from reactions between the pyrite-bearing shale and carbonaceous rocks. To investigate this, the geochemical, geological and palaeoclimatic settings were investigated and a laboratory experiment with Whitehill Formation rock samples was conducted. XRF data of the rocks and modal analysis were used to determine the mineral composition of the Whitehill Formation. In addition, pH-redox equilibrium (PHREEQC) modelling was used for simulations. The results of this study show that metals precipitated from the water-rock solution form various mineral phases like those of the Witwatersrand Basin. Large-scale dolomite dissolution might not be expected.

Synthesis and application of alginate immobilised banana peels nanocomposite in rare earth and radioactive minerals removal from mine water.

This study describes the preparation, characterisation and application of pelletised immobilised alginate/montmorillonite/banana peels nanocomposite (BPNC) in a fixed-bed column for continuous adsorption of rare earth elements and radioactive minerals from water. The materials was characterised by Fourier transform infrared, X-ray diffraction and scanning electron microscopy analyses. Analyses indicated that the pellets are porous and spherical in shape. FT-IR analysis showed that the functional groups responsible for the coordination of metal ions were the carboxylic (-COO-) and siloxane (Si-O-Si and Si-O-Al) groups. XRD analysis showed two additional peaks which were attributed to alginate and montmorillonite. The influence of the initial concentration, bed depth and flow rate were investigated using synthetic and real mine water in order to determine the breakthrough behaviour of both minerals. The processed bed volume, adsorbent exhaustion rate and service time, were also explored as performance indices for the adsorbent material. Furthermore, the breakthrough data were fitted to both the Thomas and Bohart-Adams models. The BPNC exhibited high affinity for U, Th, Gd and La in the real mine water sample. However, studies may still be required using waters from different environments in order to determine the robustness of BPNC.

Sulfate removal from acid mine water from the deepest active European mine by precipitation and various electrocoagulation configurations.

Sulfate removal from mine or process water is a key issue in the mining industry. In this paper, precipitation with lime (calcium oxide) was integrated with electrocoagulation for sulfate removal from Pyhäsalmi/Finland mine water. Sulfate precipitation with calcium oxide decreased the sulfate concentration from 13,000 mg/L to 1600 mg/L. Various current densities were applied to the pre-treated mine water with various electrodes and aluminium and iron anodes. It was found that 25 mA/cm2 was the best tested current density for both anode types. At the second stage, this current density was used for different iron and aluminium anodes in various monopolar and bipolar configurations. It was found that this hybridisation is effective for sulfate removal, and that a bipolar configuration showed better results than the monopolar configuration. The best result was gained from 25 mA/cm2 with a two aluminium and two stainless steel anode-cathode configuration and calcium oxide pre-treatment to reach pH 12. The removal efficiency reached 84.4% and 63.8% with aluminium anodes in bipolar and monopolar configurations, respectively. This setup was able to decrease sulfate concentrations from 13,000 mg/L to 250 mg/L, which meets mine water discharge limits. Kinetic studies showed that iron and aluminium anodes obey pseudo-second order kinetic. Finally, the energy consumption was calculated.

Application of banana peels nanosorbent for the removal of radioactive minerals from real mine water.

Transformation of agricultural waste such as banana peels into a valuable sorbent material has been proven effective and efficient in wastewater treatment. Further, transformation into nanosorbent to enhance the removal capacity of actinides (uranium and thorium) from synthetic and real mine water is extensively investigated in this study. The nanosorbent samples before and after adsorption were characterised by X-ray diffraction (XRD), Fourier transform infra-red (FTIR), zetasizer nanoseries and scanning electron microscopy (SEM) while the amount of radioactive substances adsorbed was determined by inductively coupled plasma optical emission spectroscopy. Results revealed that there was a crystallite size and particle size reduction from 108 to 12 nm and <65,000 nm to <25 nm respectively as a function of milling time. Furthermore, appearance and disappearance of nanofibers via milling was noticed during structural analysis. The functional groups responsible for the banana peels capability to coordinate and remove metal ions were identified at absorption bands of 1730 cm-1 (carboxylic groups) and 889 cm-1 (amine groups) via FTIR analysis. Equilibrium isotherm results demonstrated that the adsorption process was endothermic for both uranium and thorium. The Langmuir maximum adsorption capacity was 27.1 mg g-1, 34.13 mg g-1 for uranium and 45.5 mg g-1, 10.10 mg g-1 for thorium in synthetic and real mine water, respectively. The results obtained indicate that nanostructured banana peels is a potential adsorbent for the removal of radioactive substances from aqueous solution and also from real mine water. However, the choice of this sorbent material for any application depends on the composition of the effluent to be treated.