1.
Chem Commun (Camb)
; 56(72): 10453-10456, 2020 Sep 10.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32748902
RESUMO
A mechanically interlocked [2]rotaxane is reported incorporating a ditopic ligand moiety as one of the stoppers. Upon complexation with palladium(ii) ions a metallo-[5]rotaxane was formed with a porous Pd2L4 metal-organic cage at the core of the structure. This proof-of-principle system precedes work towards the construction of metal organic polyhedra with switchable mechano-chemical properties.