Recycling waste iron-rich algal flocs as cost-effective biochar activator for heterogeneous Fenton-like reaction towards tetracycline degradation: Important role of iron species and moderately defective structures.

Harvesting aquatic harmful algal blooms (HABs) and reusing them is a promising way for antibiotic degradation. Herein, a novel iron-rich biochar (Fe-ABC), derived from algal biomass harvested by magnetic coagulation, was successfully designed and fabricated as activator for heterogeneous Fenton-like reaction. The modification methods and pyrolysis temperatures (400-800 °C) were optimized to enhance the formation of rich iron species and moderately defective structure, yielding Fe-ABC-600 with enhanced electron transfer and H2O2 activation capability. Thus, Fe-ABC-600 exhibited superior removal efficiency (95.33%) on tetracycline (TC), where the presence of multiple iron species (Fe3+, Fe2+ and Fe4+) and moderately defective structure accelerating the Fenton-like oxidation. The concentration of leaching Fe after each reaction was all below 0.74 mg/L in five cycles, ensuring the sustained degradation. And •OH was proved to be the major radical contributing to the degradation of TC, as well as the direct electron transfer mechanism together, in which the CO acted as electron regulator and electron donor. Fe-ABC as a cost-effective catalyst has notable application potentials in TC removal from wastewater owing to its remarkable advantages of high resource utilization, enhanced catalytic property, high ecological safe, notable TC degradation efficiency, low cost and environmental-friendliness.

Removal of emulsified oil from water by using recyclable chitosan based covalently bonded composite magnetic flocculant: Performance and mechanism.

In this work, a novel recyclable covalently bonded magnetic flocculant (FS-MC) was successfully prepared by combining chitosan-based modified polymers (MCS) with Fe3O4@SiO2 through a silane coupling agent. The covalent bond Fe-O-Si-O-C and the core-shell structure of FS-MC were confirmed through several characterization methods. The emulsified oily wastewater flocculation performance and mechanism by using FS-MC were evaluated and studied. Results showed that 94.47%, 93.95%, and 92.98% of emulsified oil could be removed by using FS-MC1, FS-MC2 and FS-MC3 at dosages of 2.0, 2.5, and 2.0 mg/L, respectively. Furthermore, FS-MC exhibited an excellent behavior on the removal of organic compounds with molecular weight > 10 kDa, including long chain alkanes, cycloalkanes, and aromatic hydrocarbon compounds. In addition, triple-phase separation of oil, water and flocculants was achieved by using magnetic FS-MC. Due to the introduction of cationic and hydrophobic groups in FS-MC, charge neutralization, compression double electric-layer action, hydrophobic interaction, interfacial adsorption bridging and sweep-flocculation synergistically contributed and enhanced the removal of emulsified oil. Recycling experiments also showed that no obvious decrease of oil removal rate was observed by using magnetic FS-MC flocculants in five cycles.