1.
Org Biomol Chem
; 20(44): 8638-8642, 2022 11 16.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36102896
RESUMO
We describe herein a catalyst-free, traditional reductant-free strategy for the direct photoinduced hydrogenation or deuteration of aromatic olefins, ketones, and aldehydes with simple bases as the only additives. A broad range of substrates were demonstrated with high yields and deuterium incorporations. Mechanistic experiments indicate a radical mechanism.