1.
Org Lett
; 5(6): 905-8, 2003 Mar 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-12633102
RESUMO
[reaction: see text] Acetonides derived from different terpenes undergo Grob fragmentation by treatment with a catalytic amount of acid, triflic acid, or boron trifluoride, giving aldehydes containing a cyclopropane or cyclobutane ring with good yields and complete diastereoselectivity. The structure and the stereochemistry of the starting acetonide have a crucial influence on the reaction course.