The Practical Application of Bio-Inspired PMA for the Detection of Partial Discharges in High Voltage Equipment.

In this paper, the practical application of a bio-inspired antenna for partial discharge (PD) detection in high voltage equipment was evaluated in order to validate the efficiency of using this technology for PD monitoring purposes. For this, PD measurements using the bio-inspired antenna were performed on operational 69 kV potential transformers (PT) in a real substation. After the field experiment, laboratory measurements using the IEC 60270 standard method and a bio-inspired antenna were performed, simultaneously, over the evaluated PT. The results obtained at the substation indicated suspicious frequencies of partial discharge activity in two out of three evaluated potential transformers, mainly for the frequencies of 461 MHz, 1366 MHz, 1550 MHz and 1960 MHz. During the laboratory tests, the presence of partial discharge activity over the suspicious potential transformers was confirmed with the detection of PD apparent charge levels above 20 pC. Finally, the frequency spectrum obtained from the PD signals detected by the bio-inspired antenna in the laboratory presented similar frequency values to those obtained during the practical application at the substation, making it a promising indicator for future defect classification studies using artificial intelligence.

Primary renal ewing sarcoma in a 15-year-old female: Case report

@#Extraskeletal Ewing sarcoma (EES) is a rare tumor that primarily affects children and lacks specific clinical signs. Diagnosis is confirmed through imaging techniques, histology, and molecular diagnostics. Treatment typically involves surgical intervention and chemotherapy. We present the case of a 15-year-old female with a history of abnormal mass enlargement in the right flank area. An initial diagnosis of Wilms tumor was made, and the patient underwent a right open radical nephrectomy. However, the tumor recurred eight months after nephrectomy, necessitating a metastasectomy. Chemotherapy was started to immediately target the tumor recurrence. Next-generation sequencing done on the open radical nephrectomy and metastasectomy samples revealed the presence of the EWSR1-FLI1 fusion gene in both specimens, confirming the final diagnosis to be primary renal Ewing sarcoma. Despite undergoing a right open radical nephrectomy for the primary tumor site, a metastasectomy during tumor recurrence, and chemotherapy, the patient’s prognosis remained poor.

Design and Application of a Metamaterial Superstrate on a Bio-Inspired Antenna for Partial Discharge Detection through Dielectric Windows.

The adaptation of dielectric windows as metamaterial superstrate over a bio-inspired Printed Monopole Antenna (PMA) was evaluated in order to improve the detection sensitivity of Ultra High Frequency (UHF) sensors designed for Partial Discharge (PD) measurement. For this purpose, rectangular and circular Split Ring Resonators (SRR) structures were designed and evaluated aiming to achieve a metamaterial superstrate that improves the characteristics of the bio-inspired PMA as the gain, bandwidth, and radiation pattern. Measurements of the PMA with metamaterial superstrate were carried out in an anechoic chamber and compared to the simulations performed. The results show that the metamaterial superstrate insertion did not impact the original operating bandwidth, covering most of the characteristic frequency range of PD activity. Moreover, this insertion resulted in a mean gain enhancement of 0.7 dBi regarding the reference PMA, resulting in an antenna with better sensitivity for PD detection (mean gain of 3.61 dBi). The PMA-metamaterial set PD detection sensitivity was evaluated through laboratory tests with a point-to-plane PD generator setup and in field with measurements from a 230 kV current transformer. The developed PMA-metamaterial set was able to detect, successfully, the activity of PD for both tests, being classified as an optimized sensor for PD detection through dielectric windows.

UHF Partial Discharge Location in PowerTransformers via Solution of the MaxwellEquations in a Computational Environment.

This paper presents an algorithm for the localisation of partial discharge (PD) sourcesin power transformers based on the electromagnetic waves radiated by a PD pulse. The proposedalgorithm is more accurate than existing methods, since it considers the effects of the reflection,refractions and diffractions undergone by the ultra-high frequency (UHF) signal within the equipmenttank. The proposed method uses computational simulations of the electromagnetic waves generatedby PD, and obtains the time delay of the signal between each point in the 3D space and the UHFsensors. The calculated signals can be compared with the signals measured in the field, so thatthe position of the PD source can be located based on the best correlation between the simulatedpropagation delay and the measured data. The equations used in the proposed method are definedas a 3D optimisation problem, so that the binary particle swarm optimisation algorithm can be used.To test and demonstrate the proposed algorithm, computational simulations were performed. Thesolutions were sufficient to identify not only the occurrence of defects, but also the winding and theregion (top, centre or base) in which the defect occurred. In all cases, an accuracy of greater than15 cm was obtained for the location, in a 180 MVA three-phase transformer.

Design and Development of a Bio-Inspired UHF Sensor for Partial Discharge Detection in Power Transformers.

In this paper, the design and development of a bio-inspired UHF sensor for partial discharge detection in power transformers is presented. The UHF sensor was developed for external use in dielectric windows of power transformers. For this purpose, a microstrip antenna was designed with a radiating element shape based on the leaf of the Jatropha mollissima (Pohl) Baill plant. Then, an epoxy coating and an aluminium enclosure were developed to protect the antenna against corrosion and to provide mechanical support, external noise immunity, and a lifetime compatibility with power transformers. In order to verify the electrical parameters of the developed sensor, measurements of the gain and the reflection coefficient were performed in an anechoic chamber. Lastly, the antenna sensitivity for denominated partial discharge (PD) detection was compared with the IEC 60270 standard method. For this purpose, simultaneous tests were carried out in a partial discharge generator setup, composed of an oil cell with needle-plane electrodes. The experimental tests demonstrated the effectiveness of the sensor for detecting PD signals with apparent charge values higher than 35 pC.

Bio-inspired Printed Monopole Antenna Applied to Partial Discharge Detection.

A new, bio-inspired printed monopole antenna (PMA) model is applied to monitor partial discharge (PD) activity in high voltage insulating systems. An optimized sensor was obtained by designing a PMA in accordance with the characteristics of the electromagnetic signal produced by PD. An ultra-wideband (UWB) antenna was obtained by applying the truncated ground plane technique. The patch geometry was bio-inspired by that of the Inga Marginata leaf, resulting in a significant reduction in size. To verify the operating frequency and gain of the PMA, measurements were carried out in an anechoic chamber. The results show that the antenna operating bandwidth covers most of the frequency range of PD occurrence. Moreover, the antenna presented a good sensitivity (mean gain of 3.63 dBi). The antenna performance was evaluated through comparative results with the standard IEC 60270 method. For this purpose, simultaneous tests were carried out in a PD generator arrangement, composed by an oil cell with point-to-plane electrode configurations. The developed PMA can be classified as an optimized sensor for PD detection and suitable for substation application, since it is able to measure PD radiated signals with half the voltage levels obtained from the IEC method and is immune to corona discharges.

Dissipation kinetics and effect of processing on imidacloprid and its metabolites in cardamom (Elettaria cardamomum Maton).

Dissipation behaviour of the chloronicotinyl insecticide, imidacloprid (Tatamida 17.8 % SL), in fresh and cured cardamom capsules was studied following application at doses 20 and 40 g a.i. ha(-1) in a cardamom plantation of Indian Cardamom Hills (ICH), Idukki, Kerala, India. A single-laboratory ultra performance liquid chromatography mass spectrometry (UPLC-MS/MS) method was developed and validated for the estimation of imidacloprid and its six metabolites (5-hydroxy, olefin, guanidine, urea, 6-chloronicotinic acid and nitrosimine) in fresh and cured cardamom. At the lower dose, the initial deposits of total imidacloprid residues were 1.91 and 7.23 µg g(-1), respectively, in fresh and cured cardamom. At the higher dose, the initial residues were 3.94 and 14.72 µg g(-1), respectively, in fresh and cured capsules. The residues dissipated below the quantitation level of 0.01 µg g(-1) after 21 and 28 days at lower dose and after 28 days for both at higher dose. The half-lives of imidacloprid in fresh and cured cardamom were 4.02 and 3.63 days, respectively, at lower dose and 3.61 days for both at higher dose. The waiting periods of imidacloprid on fresh and cured cardamom at lower and higher doses were 21.40, 27.10, 23.85 and 30.70 days, respectively. The mean processing factor of imidacloprid was 3.96 at 20 g a.i. ha(-1). Amongst metabolites of imidacloprid, urea had maximum residues in fresh and cured cardamom followed by 5-hydroxy and guanidine. Other metabolites such as 6-chloronicotinic acid, olefin and nitrosimine were not detected either in fresh or cured cardamom.

Persistence and effect of processing on reduction of chlorantraniliprole residues on brinjal and okra fruits.

Dissipation and decontamination of chlorantraniliprole (Coragen 18.5 SC) in brinjal and okra fruits were studied following field application at single and double doses of 30 and 60 g ai ha(-1), and the residues of the insecticide was estimated using LC-MS/MS. Initial residues of chlorantraniliprole at single and double doses on the fruits of brinjal were 0.72 and 1.48 mg kg(-1), while on okra fruits, the residues were 0.48 and 0.91 mg kg(-1), respectively. The residues reached below detectable level of 0.01 mg kg(-1) on the 10th day. Half-life of chlorantraniliprole at 30 and 60 g ai ha(-1) on brinjal was 1.58 and 1.80 days with the calculated waiting period of 0.69 and 2.38 days, whereas on okra, the values were 1.60 and 1.70 and 0 and 1.20 days, respectively. The extent of removal of chlorantraniliprole using simple decontaminating techniques at 2 h and 3 days after spraying was 40.99-91.37% and 29.85-89.12%, respectively, from brinjal fruits and 47.78-86.10% and 41.77-86.48%, respectively, from okra fruits.

Communication: Ab initio study of O4H+: a tracer molecule in the interstellar medium?

The structure and energetics of the protonated molecular oxygen dimer calculated via ab initio methods is reported. We find structures that share analogies with the eigen and zundel forms for the protonated water dimer although the symmetrical sharing of the proton is more prevalent. Analysis of different fragmentation channels show charge transfer processes which indicate the presence of conical intersections for various states including the ground state. An accurate estimate for the proton affinity of O4 leads to a significantly larger value (5.6 eV) than for O2 (4.4 eV), implying that the reaction H3(+) + O4 → O4H(+) + H2 is exothermic by 28 Kcal/mol as opposed to the case of O2 which is nearly thermoneutral. This opens up the possibility of using O4H(+) as a tracer molecule for oxygen in the interstellar medium.

Persistence and effect of processing on reduction of fipronil and its metabolites in chilli pepper (Capsicum annum L.) fruits.

A single laboratory UPLC-MS/MS method was developed and validated for the estimation of fipronil and its metabolites in fresh and dry chilli pepper fruits. Dissipation of fipronil on chilli fruits was studied following the application of fipronil (Jump 80 WG) at 40 and 80 g active ingredient (a.i.) ha(-1) in the fruiting stage of the crop. The initial deposits of total fipronil on fresh chilli fruits at single and double dose application were 0.69 and 1.43 µg g(-1), respectively, and were dissipated to below quantitation level at 27 days after application. The half-life of fipronil at single and double dose in fresh chilli pepper was 4.22 and 4.32 days and the waiting period was 25.9 and 30.6 days, respectively. Processing factor due to sun drying was calculated by measuring fipronil residues in dry chilli fruits, and it ranged from 2.96 to 3.50 during 0 to 21st day after application. Among the metabolites of fipronil, fipronil desulfenyl and fipronil sulfone had maximum residues in fresh and dried chilli, respectively, followed by fipronil sulfide. Dipping in solutions of tamarind, turmeric, vinegar and slaked lime and wet scrubbing could remove more than 90% of fipronil residues in fruits.

Dissipation kinetics and effect of different decontamination techniques on the residues of emamectin benzoate and spinosad in cowpea pods.

Dissipation and decontamination of the semisynthetic macrolide emamectin benzoate and the natural insecticide spinosad on cowpea pods were studied following field application at single and double doses of 11.0 and 22 and 73 and 146 g ai ha(-1), respectively. Residues of these naturalytes were estimated using LC-MS/MS. The initial deposit of 0.073 and 0.153 mg kg(-1) of emamectin benzoate dissipated below quantitation level on the fifth and seventh day at single and double dosage, respectively. For spinosad, the initial deposits of 0.94 and 1.90 mg kg(-1) reached below quantitation level on the 7th day and 15th day at single and double dosage, respectively. The half-life of emamectin benzoate and spinosad was 1.13-1.49 and 1.05-1.39 days with the calculated safe waiting period of 2.99-6.12 and 1.09-3.25 days, respectively, for single and double dosage. Processing of the harvestable pods with different decontamination techniques resulted in 33.82 to 100 % removal 2 h after the application of emamectin benzoate and 100 % removal 3 days after spraying, while the removal was 42.05 to 87.46 % 2 h after the application of spinosad and 38.05 to 68.08 % 3 days after application.

Persistence and effects of processing on reduction of chlorantraniliprole residues on cowpea fruits.

A field trial was conducted to study the dissipation kinetics of chlorantraniliprole 18.5 % SC on cowpea fruits. The fruit samples drawn periodically were analyzed by liquid chromatography and tandem mass detection (LC-MS/MS). The initial residues of chlorantraniliprole in cowpea fruits were found to be 0.55 mg kg(-1) which dissipated rapidly, with a half-life of 1.31 days and a waiting period of 0.62 days following first order kinetics. Processing of the fruits with solutions commonly used in households reduced the insecticide residues on cowpea fruits harvested 2 h after spraying by 47.19 %-91.70 % and 44.56 %-91.25 % on fruits plucked on the third day.

Dissipation kinetics and assessment of processing factor for chlorpyrifos and lambda-cyhalothrin in cardamom.

The dissipation kinetics and method for estimation of residues of chlorpyrifos and lambda-cyhalothrin in cardamom were studied and developed. The limit of detection and limit of quantitation arrived for the compounds were 0.01 and 0.025 µg g(-1), respectively. Gas chromatographic response of chlorpyrifos and lambda-cyhalothrin residues was linear in the range of 0.01-0.50 µg g(-1) and the mean recovery obtained was 97.3 % for chlorpyrifos and 98.9 % for lambda-cyhalothrin with satisfactory relative standard deviation values. The mean initial residues of chlorpyrifos applied at a concentration of 0.05 % in cardamom was 2.5 µg g(-1) and the residue was 8.1 µg g(-1) after processing, with a processing factor of 3.24, while lambda-cyhalothrin when applied at 0.0025 % resulted in initial residues of 1.63 µg g(-1) that magnified to 4.86 µg g(-1) on curing, with a processing factor of 2.98. The half-life of chlorpyrifos was in the range of 5.1-5.24 days while that of lambda-cyhalothrin was in the range of 4.40-4.55 days. The processing factor arrived at in the above experiment lead to the conclusion that the residues of chlorpyrifos got magnified to 3.24-3.68 times and that of lambda-cyhalothrin got magnified to 2.98-3.46 times of initial residues, consequent to loss of weight due to dehydration during curing.