Interactions of pristine and aged nanoplastics with heavy metals: Enhanced adsorption and transport in saturated porous media.

Interactions of nanoplastics (NPs) with other contaminants are attracting attention, and it is essential to investigate the interaction of aged plastics with heavy metals. We obtained aged nanopolystyrene by UV radiation and investigated the effects of aged NPs on the adsorption and cotransport of Pb-(II) and Cd-(II). The results showed that the UV-aged NPs led to the enhanced adsorption capacity of heavy metals due to the increase in oxygen-containing functional groups, and the promotion of transport by the aged NPs to heavy metals was stronger than that of the pristine NPs. Furthermore, the heavy metals retained in the columns could be freed by the NPs, and the aged NPs were more capable of freed of heavy metals as carriers. In conclusion, the radiation of NPs is correlated with their ability to promote heavy metal transport, and the oxygen content on the surface of NPs plays an essential role in this process to promote the transport of heavy metals in porous media. The ADR equation and DLVO theory simulates the transport behaviour of NPs well. This study is expected to provide a new perspective for assessing the potential risk of aged NPs in soil-groundwater systems.

A review on the remediation of microplastics using constructed wetlands: Bibliometric, co-occurrence, current trends, and future directions.

Massive prevalence of microplastics (MPs) in the environment has become one of the world's most serious environmental concerns. Human dependence on plastics has created a constant flow of MPs from different sources into natural environment, which has raised public concern regarding consequences of MPs coming into contact with the natural environment. Deploying constructed wetlands (CWs) to reduce MPs pollution is considered a promising method, however there are still barriers for breakthroughs in this technology, particularly knowledge gaps in the mechanisms affect removal process. Recognising this, we provide a comprehensive summary of current advances and theories regarding the mechanisms of occurrence in this research area. In this work, the bibliometric methods were first used to identify annual publication trends and topical topics of research interest. The selected documents were then statistically analyzed using VOSviewer and the 'bibliometrix' package in R to derive the annual productivity of countries or organizations, the most relevant affiliations, the most relevant authors, the most relevant sources, textual analysis, co-occurrence analysis, and cluster analysis of keywords. Finally, detailed information concerning the removal of MPs by CWs was summarised, covering the most common operational and design parameters (i.e., structure types, wetland plants, substrate materials, and microbial communities), to reveal how these parameters can be adjusted for more efficient MPs removal rate. Challenges and future directions were additionally proposed. It is hoped that the review will help identify current research trends, provide insight into the mechanisms of the removal process, and contribute further to the development of this important area.

Effects of physicochemical factors on the transport of aged polystyrene nanoparticles in saturated porous media.

Plastic debris, particularly nanoplastics, have attracted substantial attention as an emerging pollutant of global concern. The aging process caused by UV could dramatically alter the physicochemical properties of polystyrene plastics and affect their fate and transport in the subsurface environment. We researched the effects of diverse factors, including flow rate, ionic strength (IS), and cation valence on the transport of aged polystyrene nanoparticles (PSNPs) in saturated porous media and found that their mobility was greatly enhanced by the aging process at all other experimental conditions except coexistence with Al3+. Interestingly, we found that the aged PSNPs were polymerized due to the coexistence with Al3+, which led the aged PSNPs to exhibit weaker mobility than the pristine. Zeta potential and particle size measurements, FTIR spectroscopy, and XPS were employed to characterize the PSNPs, and the results suggest that UV radiation provides O-containing functional groups for the PSNPs. The experimental results correspond well with the ADR model and the values of Smax and k closely reflect the deposition of the PSNPs in sand columns. Moreover, the Derjaguin-Landau-Verwey-Overbeek (DLVO) theoretical calculation accurately reflects the interaction of the pristine and aged PSNPs and quartz sand. Overall, due to the processes that PSNPs possibly undergo in the environment, their mobility may fluctuate dramatically. These findings help remedy knowledge deficiency regarding nanoplastic mobility being affected by aging processes, further underscore the critical influence of the aging process on the potential risks and environmental fates of nanoplastics.

Effect of surfactants on the transport of polyethylene and polypropylene microplastics in porous media.

The transport of microplastics in porous media is attracting increasing attention. However, to date, research is limited to polystyrene microplastics. Meanwhile, surfactants can promote solid dispersion to form a stable suspension, possibly allowing microplastics to migrate when attached to a surfactant, which would increase the scope and degree of microplastic pollution, further endangering human health and the stability of the ecological environment. Therefore, in this study, the transport behavior of microplastics in porous media was explored in the presence of surfactants. Herein, polyethylene (PE) and polypropylene (PP) were evaluated while dispersed by two ionic surfactants: cationic surfactant-cetyltrimethylammonium bromide (CTAB) and anionic surfactant-sodium dodecylbenzenesulfonate (SDBS). The influence of different factors (surfactant concentration, ionic strength, pH, flow rate, and multivalent cations) on the transport of microplastics in porous media was explored via quartz sand packed-column experiments. Our experimental results show that the transport abilities of PE and PP increased with increasing surfactant concentration when the surfactant concentration was less than the critical micelle concentration (CMC). In the presence of CTAB and SDBS, physicochemical factors had different effects on the transport of microplastics mainly by controlling Zeta potential, advection diffusion and CMC. The mobility of PE and PP decreased with increasing ionic strength, cation valence and pH, and decreasing flow rate. However, the mobility of PE and PP under CTAB is much greater than that of PE and PP under SDBS, because quartz sand can absorb more CTAB molecules through electrostatic attraction to weaken the collision between microplastics and quartz sand. Further, the transport ability of PP was greater than that of PE under all conditions considered. Notably, the Extended-Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory formed by adding osmotic, elastic, and hydrophobic force could well described the migration behavior of microplastics in CTAB and SDBS well. This research highlights that surfactant has a significant impact on the transport ability of microplastics, and provides a comprehensive understanding of the migration and fate behaviors of microplastics affected by surfactants, which is necessary to prevent and reduce the environmental hazards of microplastics.