Modification Strategies of High-Energy Li-Rich Mn-Based Cathodes for Li-Ion Batteries: A Review.

Li-rich manganese-based oxide (LRMO) cathode materials are considered to be one of the most promising candidates for next-generation lithium-ion batteries (LIBs) because of their high specific capacity (250 mAh g-1) and low cost. However, the inevitable irreversible structural transformation during cycling leads to large irreversible capacity loss, poor rate performance, energy decay, voltage decay, etc. Based on the recent research into LRMO for LIBs, this review highlights the research progress of LRMO in terms of crystal structure, charging/discharging mechanism investigations, and the prospects of the solution of current key problems. Meanwhile, this review summarizes the specific modification strategies and their merits and demerits, i.e., surface coating, elemental doping, micro/nano structural design, introduction of high entropy, etc. Further, the future development trend and business prospect of LRMO are presented and discussed, which may inspire researchers to create more opportunities and new ideas for the future development of LRMO for LIBs with high energy density and an extended lifespan.

Ecotoxicological evaluation of functional carbon nanodots using zebrafish (Danio rerio) model at different developmental stages.

Considering functional carbon nanodots (FCNs) are potential to be applied in many areas, their risk and toxicity to organisms are imperative to be evaluated. Thus, this study conducted acute toxicity test of zebrafish (Danio rerio) at embryonic and adult stage to estimate the toxicity of FCNs. Results show that the toxic effects of FCNs and nitrogen doped FCNs (N-FCNs) at their 10% lethal concentration (LC10) values on zebrafish are expressed in developmental retardation, cardiovascular toxicity, renal damage and hepatotoxicity. There are interactive relationships between these effects, but the main reason should be ascribed to the undesirable oxidative damage induced by high doses of materials, as well as the biodistribution of FCNs and N-FCNs in vivo. Even so, FCNs and N-FCNs can promote the antioxidant activity in zebrafish tissues to cope with the oxidative stress. FCNs and N-FCNs are not easy to cross the physical barriers in zebrafish embryos or larvae, and can be excreted from intestine by adult fish, which proves their biosecurity to zebrafish. In addition, because of the differences in physicochemical properties, especially nano-size and surface chemical property, FCNs show higher biosecurity to zebrafish than N-FCNs. The effects of FCNs and N-FCNs on hatching rates, mortality rates and developmental malformations are dose-dependent and time-dependent. The LC50 values of FCNs and N-FCNs on zebrafish embryo at 96 hpf are 1610 mg/L and 649 mg/L, respectively. According to the Acute Toxicity Rating Scale of the Fish and Wildlife Service, the toxicity grades of FCNs and N-FCNs are both defined as "practically nontoxic", and FCNs are "Relatively Harmless" to embryos because their LC50 values are above 1000 mg/L. Our results prove the biosecurity of FCNs-based materials for future practical application.