Highly Stretchable, Ultra-Sensitive, and Self-Healable Multifunctional Flexible Conductive Hydrogel Sensor for Motion Detection and Information Transmission.

Self-healable flexible sensing materials are extensively investigated for their potential use in human motion detection, healthcare monitoring, and other fields. However, the existing self-healable flexible sensing materials have limited their application in real life due to the weak stability of the conductive network and the difficulty in balancing stretchability and self-healing performances. In this paper, a flexible sensor with skin-like properties was prepared by composing a polymer composite hydrogel with a multiple network structure consisting of polyaniline, polyvinyl alcohol, chitosan, and phytic acid. The composite hydrogel was tested and proved to own high mechanical properties (stretchability ≈ 565%, strength ≈ 1.4 MPa), good electrical conductivity (0.214 S cm-1), excellent self-healing properties (>99% healing efficiency in a 4 h healing period), and antibacterial properties. It had high sensitivity and a wide sensing range for strain and pressure, making it possible to manufacture multifunctional flexible sensors with comprehensive performance exceeding that of most flexible sensing materials. Notably, this polymer composite hydrogel can be manufactured in a large area and at a low cost, which is beneficial for its further application in many fields.

Carbon Nanotubes/Polydopamine/ZSM-5 Composite Soil Conditioner with Good Controlled Release and Adsorption Properties.

Currently, the excessive application of fertilizers and the random discharge of waste water, waste gas, and residues have led to more and more serious soil pollution problems. Zeolite is the most promising material for preparing a green and environmentally friendly soil conditioner. Herein, the carbon nanotubes/polydopamine/ZSM-5 composite soil conditioner was prepared by a facile two-step method, and it was used to release fulvic acid and adsorb methylene blue to improve the environment. The cumulative release rate of the composite soil conditioner was 52% within 430 h for fulvic acid, which had a good sustained release effect and could be sustained-released in different acid-based surroundings. In addition, it showed a good adsorption capacity of methylene blue, and it is about 80.02 mg/g which was about six times higher than that of ZSM-5. It was beneficial for the adsorption of methylene blue in a neutral environment. Finally, it could promote the growth of brassica chinensis and maize, and the promotion effect was 60 and 35%, respectively. Therefore, the carbon nanotubes/polydopamine/ZSM-5 composite soil conditioner is a green and efficient material, which provides a new strategy to solve the problem of soil pollution.

Aminated Multiwalled Carbon Nanotube-Doped Magnetic Flower-like WSe2 Nanosheets for Efficient Adsorption in Acidic Wastewater.

The water body environment is related to ecological and human health. Adsorption is an effective means to remove pollutants from water bodies. Currently, the common adsorbents suffer from disadvantages such as structural instability and poor adsorption performance under acidic conditions, which not only affect the adsorption efficiency but also cause secondary pollution of water bodies. In this study, a novel aminated multiwalled carbon nanotube-doped flower-like nanocomposite was designed, where the anionic or neutral groups were protonated under acidic conditions, and it displayed a higher adsorption capacity for dyes by ion exchange, represented by methylene blue (MB) and rhodamine B (RB). WSe2 in the composite increases its adsorption sites. The adsorption efficiency of pollutants in acidic wastewater was enhanced while avoiding secondary contamination. The synthesized composites showed maximum adsorptions of 27.55 and 27.47 mg/g for MB and RB, respectively. The current work offers a novel approach to treating acidic wastewater.

A Multifunctional Microspheric Soil Conditioner Based on Chitosan-Grafted Poly(acrylamide-co-acrylic acid)/Biochar.

A multifunctional microspheric soil conditioner based on chitosan-grafted poly(acrylamide-co-acrylic acid)/biochar [CS-g-P(AM-co-AA)/BC] was prepared. First, the P(AM-co-AA) was synthesized and successfully grafted onto CS, and the three-dimensional network structure of microspheres was formed with N,N-methylenebis(acrylamide) as the cross-linking agent according to the inverse suspension polymerization method. Meanwhile, BC and urea were encapsulated into the body of microspheres during the polymerization. The structure of the microspheres was analyzed by Fourier transform infrared spectroscopy, polarized optical microscopy, and scanning electron microscopy, and the mechanism of adsorption of Cu2+ on the microspheres was investigated by X-ray photoelectron spectroscopy. Furthermore, the experimental results demonstrated the excellent water absorption and retention capabilities of microspheres, and the release rate of urea was dramatically reduced. Importantly, the introduction of BC significantly enhanced the adsorption performance of the microspheres with respect to heavy metal ions. Consequently, the multifunctional soil conditioner held promise for use in soil improvement and agricultural production.