Cu/Co Bimetallic Carbon Catalyst as a Highly Efficient Promoter for Reactive Dyes Degradation with PMS.

The synergistic effect between bimetallic catalysts has been confirmed as an effective method for activating persulfate (PMS). Therefore, we immobilized copper-cobalt on chitosan to prepare bimetallic carbon catalysts for PMS activation and degradation of reactive dyes. Experimental results demonstrate that the CuCo-CTs/PMS catalytic degradation system exhibits excellent degradation performance toward various types of reactive dyes (e.g., Ethyl violet, Chlortalidone, and Di chlorotriazine), with degradation rates reaching 90% within 30 min. CuCo-CTs exhibit high catalytic activity over a wide pH range of 3-11 at room temperature and under static conditions, degrading over 92% of RV5 within 60 min. ultraviolet-visible (UV-vis) spectroscopy and color changes in the dye solution confirm the effective degradation of RV5, with a degradation rate of 97.2% within 10 min. Additionally, CuCo-CTs demonstrate good stability and reusability, maintaining a degradation rate of 92.8% after eight cycles. Kinetic studies indicate that the degradation follows pseudo-first-order kinetics. Furthermore, based on the results of radical scavenging experiments, the catalytic degradation mechanism of the dye involves both radical and nonradical pathways, with 1O2 identified as the primary active species. This study provides insights and experimental evidence for the application of persulfate oxidation in the treatment of dyeing wastewater.

Preparation of multifunctional cellulose macromolecule blended fabrics through internal and external synergy by N1, N6-bis (ethylene oxide-2-ylmethyl) hexane-1,6-diamine.

With the diversification of people's demand for textile functions, the preparation of multifunctional fabrics is still a current research hotspot. In this study, the water-soluble epoxy compound N1, N6-bis(oxiran-2-ylmethyl) hexane-1,6-diamine (EH) was introduced into cellulose macromolecule blended fabrics (cotton/modal) by two-phase vaporization technique, resulting in excellent wrinkle, hydrophobicity, and certain UV protection effects. It could be observed by electron microscopy that EH formed a polymer film on the fiber surface. In addition, the results of EDS scans and fiber swelling rate tests showed that EH was uniformly distributed and formed a cross-linked structure in the amorphous zones inside the fibers. Compared with the control fabrics, the wrinkle recovery angle of the EH-treated fabric was increased by 39.7 %. The fabrics could reach a contact angle of 136.9°, providing excellent hydrophobic effect. In addition, the fabrics achieved certain UV protection effects (UPF of 50+). The EH-treated fabrics were less stabilized in strong acid and alkali conditions, but exhibited greater durability in other environments. In summary, the internal and external synergistic effects of EH in forming polymer films on the fibers surface and internal cross-linking structures provided a cleaner, simple, and feasible method for the preparation of multifunctional cellulose macromolecule fibers textiles.