A review on efficient removal of phthalic acid esters via biochars and transition metals-activated persulfate systems.

As emerging contaminants, PAEs (Phthalic Acid Esters or Phthalate Esters) have been extensively utilized in industrial production to soften the rigid plastics (plasticizers), and their related products are widely distributed in our daily life. The PAEs can readily transfer from the products to the surrounding environment due to not being chemically bound to the products. In this study, we analyzed the PAEs' properties, usage, and consumption in the world, as well as toxicity to human beings. As endocrine-disrupting chemicals (EDCs), PAEs can disturb the normal hormones reactions, resulting in developmental and reproductive problems. Thus, we have to concern the removal strategies of PAEs. We summarized two novel approaches, including biochars and persulfate (PS) oxidation for effectively removing PAEs in the literature. Their characteristics, removal mechanisms, and the main impact factors on the removal of PAEs were highlighted. Moreover, transition metal-activated PS showed good performance on PAEs degradation. Furthermore, the synergy of biochars and transition metals-PS can overcome the disadvantages of a single approach, and show better performance on the removal of PAEs. Finally, we put forward vital strategies to update two approaches (including the combined) for enhancing the removal of PAEs. It is expected that the researchers or scientists can get a hint on effectively remediating PAEs-contaminated sites via the biochars' sorption/transition metals-PS or the combined two from this review paper.

Impact of water quality on the microbial diversity in the surface water along the Three Gorge Reservoir (TGR), China.

The Three Gorges Reservoir (TGR), one of the world's largest reservoirs, has crucial roles in flood control, power generation, and navigation. The TGR is contaminated because of the human activities, and how the contaminated water influences the distribution of the microbial community have not been well studied. In this study, we collected 41 freshwater samples from 13 main dwelling districts along the TGR to investigate the water quality, the distribution of the microbial community, and how water quality affects the microbial community structure. The sampling sites cover the whole TGR along the stream, with 670 km distance. Our results show that both water quality and the compositions of bacterial community vary along the TGR. The distribution of bacterial community is closely related to the local water quality. There is the highest concentration of chemical oxygen demand (COD), the highest relative abundance of Firmicutes, and the highest relative abundance of Bacillus in the upstream, compared to the middle and down streams. Redundancy analysis (RDA) showed that PO43- and COD were the main environmental factors influencing on the structure of bacterial community. The relative abundance of nitrification and denitrification functional genes also altered along the streams. These findings provide the basic data for water quality, the distribution of bacterial community, the link of environmental factors, and the bacterial community structure along the TGR, which guides the local environmental protection agency to launch protection strategy for maintaining the ecosystem health of the TGR.