A Novel Polyfunctional Polyurethane Acrylate Derived from Castor Oil-Based Polyols for Waterborne UV-Curable Coating Application.

Because of its unique molecular structure and renewable properties, vegetable oil has gradually become the focus of researchers. In this work, castor oil was first transformed into a castor oil-based triacrylate structure (MACOG) using two steps of chemical modification, then it was prepared into castor oil-based waterborne polyurethane acrylate emulsion, and finally, a series of coating materials were prepared under UV curing. The results showed that with the increase in MACOG content, the glass transition temperature of the sample was increased from 20.3 °C to 46.6 °C, and the water contact angle of its surface was increased from 73.85 °C to 90.57 °C. In addition, the thermal decomposition temperature, mechanical strength, and water resistance of the samples were also greatly improved. This study not only provides a new idea for the preparation of waterborne polyurethane coatings with excellent comprehensive properties but also expands the application of biomass material castor oil in the field of coating.

Effect of modified bamboo lignin replacing part of C5 petroleum resin on properties of polyurethane/polysiloxane pressure-sensitive adhesive and its application on the wood substrate.

This paper reports a fresh and robust strategy to develop polyurethane/polysiloxane pressure-sensitive adhesives (PSAs) with excellent properties by replacing part of C5 petroleum resin with modified lignin. A unique aspect of this work is the use of renewable lignin to obtain modified monomers. The phenolic hydroxyl group of lignin is increased by 21.4% after demethylation, which will help to introduce 6-bromo-1-hexene into the lignin structure through Williamson method. The L3 lignin and C5 petroleum resin are mixed with polyurethane/polysiloxane prepolymer, and furthermore a series of PSAs are obtained under ultraviolet light. It turns out that L3 lignin can not only replace part of C5 petroleum resin, but also obtain attractive and controllable features. Especially when the mass ratio of C5 petroleum resin to L3 lignin is 6:4, compared with pure C5 petroleum resin, the 180° peel strength and the shear strength of PU46 are increased by 24.1% and 91.5% respectively. Additionally, the shear strength on the wood substrate is increased by 320.6%. This study provides an effective method for the preparation of high value-added lignin PSA, and expands the application fields of PSA.

Evolution properties of the radially polarized Laguerre-Gaussian-correlated Schell-model beams propagating in uniaxial crystals.

In this paper, we discuss, both analytically and numerically, the paraxial propagation of the radially polarized Laguerre-Gaussian-correlated Schell-model (LGCSM) beams orthogonal to the optical axis in uniaxial crystals. The analytical expression for the cross-spectral density function and the second-order moments of the radially polarized LGCSM beams are derived, and the evolution properties of the normalized intensity distribution, the spectral degree of the coherence (SDOC), and the spectral degree of the polarization (SDOP) in uniaxial crystals are elucidated by numerical examples. It is found that the intensity distribution of the radially polarized LGCSM beams evolves from a doughnut shape into a solid shape and finally converts into an elliptical symmetric hollow-ring profile in uniaxial crystals due to the combined effect of special correlation functions and the anisotropy effect of the uniaxial crystals. The evolution of the SDOC and SDOP for the radially polarized LGCSM beams is quite different from that of the radially polarized Gaussian-Schell-model beams. In addition, the propagation properties of the radially polarized LGCSM beams are closely related to the spatial coherence length, the mode order, and the ratio of extraordinary and ordinary reflective indices. The results show that the uniaxial crystals could modulate the evolution properties of the radially polarized LGCSM beams.

Seawater-enhanced tough agar/poly(N-isopropylacrylamide)/clay hydrogel for anti-adhesion and oil/water separation.

Hydrogels as typical hydrophilic materials are promising candidates for designing novel functional materials for anti-fouling, oil/water separation, wearable devices, tissue scaffolds, etc. However, it still remains a challenge to design stable and tough hydrogels for applications in complex environments of high stress, temperature, salt, and pH. Herein, we fabricate a novel seawater-enhanced Agar/Poly(N-isopropylacrylamide)/clay hydrogel (APNC gel) through a facile photo-initiated polymerization process. The APNC gel consists of fully interpenetrating double networks with negatively-charged clay serving as physical cross-linkers. The resulting gel exhibits tough mechanical strength (tensile strength of 0.85 MPa and compression strength of 1.68 MPa) and excellent stabilities for high temperature (100 °C) and high salt levels (20 wt% NaCl). Especially, the strength of the APNC gel is greatly enhanced (up to 5.04 MPa) by seawater, which contains numerous inorganic ions (Mg2+, Na+, K+, etc.). Meanwhile, the APNC gel presents excellent anti-adhesion performance due to the negatively-charged clay. Thus, a hydrogel-coated mesh with underwater superoleophobicity has been designed for oil/seawater separation. The resulting mesh can selectively remove oil from seawater with high separation efficiency (up to 99%). These characteristics demonstrate that the tough APNC gel will be an ideal material candidate for developing functional materials applied in a complex environment.

Propagation properties of partially coherent crescent-like beams under maritime environment.

Based on the extended Huygens-Fresnel principle, the analytical expressions for the intensity distribution, effective radius of curvature, beam wander, Strehl ratio, and the power in the bucket of a partially coherent crescent-like (PCCL) beam under the maritime environment are derived. The propagation properties of the PCCL beams through the maritime environment are investigated in detail. Numerical results indicate that, for the maritime environment, the propagation properties and beam quality of a PCCL beam are closely related to its initial beam parameters and the turbulence parameters. Comparative analyses are performed for the new models under the marine turbulence and the terrestrial turbulence. It turns out that the marine turbulence influences the beam width and the beam wander more than the terrestrial turbulence does. Also, the beam quality of the PCCL beams in marine turbulence can be improved by choosing a large beam width, high coherence length, or short wavelength. The PCCL beams have a range-dependent tilt, which can be useful for some practical applications, such as traveling around an obstacle. The results are of significance for over-the-sea communication systems.

Biosynthetic bifunctional enzyme complex with high-efficiency luciferin-recycling to enhance the bioluminescence imaging.

Firefly luciferase is a prominent reporter on molecular imaging with the advantage of longer wavelength on light emission and the ATP linear correlation, which makes it useful in most of current bioluminescence imaging model. However, the utility of this biomaterial was limited by the signal intensity and stability which are respectively affected by enzyme activity and substrate consumption. This study demonstrated a series of novel synthetic bifunctional enzyme complex of Firefly luciferase (Fluc) and Luciferin-regenerating enzyme (LRE). A peptide linker library was constructed for the fusion strategy on biosynthesis. The findings of both experimental data and structural simulation demonstrated that the intervention of fused LRE remarkably improve the stability of in vitro bioluminescence signal through luciferin recycling; and revealed the competitive relationship of Fluc and LRE on luciferin binding: Fluc performed higher activity with one copy number of rigid linker (EAAAK) at the C terminal while LRE acted more efficiently with two copy numbers of flexible linker (GGGGS) at the N terminal. With the advantage of signal intensity and stability, this fused bifunctional enzyme complex may expand the application of firefly luciferase to in vitro bioluminescence imaging.

Fusion expression of bifunctional enzyme complex for luciferin-recycling to enhance the luminescence imaging.

Firefly luciferase (Fluc) has been widely used as a bioluminescent monitor. The ATP linear correlation and exogenous luciferin requirement make it useful in most of current imaging systems. However, the utility of this reporter was still limited by the intensity and decay of the luminescent signal, and the active site and structure of enzyme including the relevant substrate channeling region. This study demonstrated a novel construction of bifunctional enzyme system to improve the luminescence generation of firefly luciferase, by bringing in a luciferin-regenerating enzyme (LRE) fusion expressed to the C terminal of luciferase, between which were connected with peptide linker. The fusion protein constructed with typical type of linker, rigid linker (EAAAK) and flexible linker (GGGGS), were analyzed comparing with the unlinked free enzyme. In vivo and in vitro assessment of the bioluminescence intensity and decaying rate to the series of Fluc-LRE enzyme complex were assayed. The fInding demonstrated that the presence of LRE remarkably enhance the generation of luminescence and remained significant stronger signal than that of the control, and the peptide-linked dual enzyme present more stability and continuation on the signal generation and lower decaying rate on signal recession, especially at low dose of Fluc injection. With the advantage of luminescence intensity and reaction period, the peptide mediated fusion expressed LRE may expand the application of Firefly luciferase on bioluminescence imaging.