Experimental Diagnosis on Combustion Characteristic of Shock Wave Focusing Initiation Engine.

A shock wave focusing initiation engine was assembled and tested in an experimental program. The effective pyrolysis rate of the pre-combustor was evaluated over a range of supplementary fuel ratio in this paper. Results highlight two operational modes of the resonant cavity: (1) pulsating combustion mode, (2) stable combustion mode. The appearance of the two combustion modes is jointly affected by the flow and the structural characteristic value of the combustion chamber. This paper uses images, time-frequency analysis, and nonlinear time series analysis methods to identify and distinguish these two combustion modes. It is believed that the interaction between the combustion chamber and the supply plenum is the probable reason for different combustion modes. The experiment has found that structural parameters and import flow parameters have an impact on the initiation of the combustion chamber. Increasing the injection pressure can appropriately broaden the fuel-rich boundary of initiation. Low equivalence ratio and high injection pressure can also appropriately increase the combustion working frequency in a small range. From the perspective of pressure utilization, under the premise of ensuring successful initiation, injection pressure should not be too high.

Nitrogen-doped hollow carbon spheres with a wrinkled surface: their one-pot carbonization synthesis and supercapacitor properties.

Nitrogen-doped hollow carbon spheres with a wrinkled surface were rationally synthesized for the first time by using graphene oxide as a morphology controlling agent through direct pyrolysis of core-shell structured GO-resol@melamine formaldehyde composites, showing excellent rate performance towards supercapacitors, due to their unique structural and surface properties.

Graphene/Cu nanoparticle hybrids fabricated by chemical vapor deposition as surface-enhanced Raman scattering substrate for label-free detection of adenosine.

We present a graphene/Cu nanoparticle hybrids (G/CuNPs) system as a surface-enhanced Raman scattering (SERS) substrate for adenosine detection. The Cu nanoparticles wrapped by a monolayer graphene shell were directly synthesized on flat quartz by chemical vapor deposition in a mixture of methane and hydrogen. The G/CuNPs showed an excellent SERS enhancement activity for adenosine. The minimum detected concentration of the adenosine in serum was demonstrated as low as 5 nM, and the calibration curve showed a good linear response from 5 to 500 nM. The capability of SERS detection of adenosine in real normal human urine samples based on G/CuNPs was also investigated and the characteristic peaks of adenosine were still recognizable. The reproducible and the ultrasensitive enhanced Raman signals could be due to the presence of an ultrathin graphene layer. The graphene shell was able to enrich and fix the adenosine molecules, which could also efficiently maintain chemical and optical stability of G/CuNPs. Based on the G/CuNPs system, the ultrasensitive SERS detection of adenosine in varied matrices was expected for the practical applications in medicine and biotechnology.