Synergistic effect of nitrogen-doping and graphene quantum dot coupling for high-efficiency hydrogen production based on titanate nanotubes.

Highly efficient H2 production from water splitting has been achieved by N-doped titanate nanotubes (N-TNTs) decorated with graphene quantum dots (GQDs) in this work. In order to promote charge carrier transmission at the interface, a facile and environmentally friendly in situ growth method was employed to construct a strongly coupled N-TNT/GQD composite photocatalyst. The results revealed that N atoms were effectively doped into the crystal lattice of the TNTs in the form of both interstitial N and substitutional N, and the GQDs were decorated onto both the inner and outer surfaces of the N-TNTs through the formation of Ti-O-C chemical bonds. Photoelectrochemical measurements proved that, in N-TNT/GQD composite, N-doping can extend light response to the visible-light range, and the coupling with GQDs not only enhanced visible-light absorption, but also promoted interfacial charge carrier transfer. Due to the synergistic effect between N-doping and GQD coupling, the closely integrated N-TNT/GQD composite exhibits a much superior photocatalytic H2 production performance under UV-vis irradiation, being 2.1 times higher than that of pure TNTs.

Lanthanide-doped mesoporous MCM-41 nanoparticles as a novel optical-magnetic multifunctional nanobioprobe.

To research and develop potential multifunctional nanoprobes for biological application, lanthanide-doped MCM-41 (Ln-MCM-41, Ln = Gd/Eu) silica nanoparticles with excellent pore structure and optical-magnetic properties were synthesized via a facile and economical sol-gel method. The microstructure and pore distribution of Ln-MCM-41 nanoparticles were obviously affected by the Ln-doping. As the Ln/Si mole ratio increased, the specific surface area and total pore volume of Ln-MCM-41 nanoparticles rapidly decreased. However, the Ln-MCM-41 nanoparticles still retained the typical well-ordered mesoporous structure, and exhibited excellent drug release behavior. Moreover, the drug release rate of Ln-MCM-41 was remarkably pH-dependent and increased gradually upon decreasing pH. Additionally, these nanoparticles also exhibit considerable photoluminescence properties, living cells photoluminescence imaging in vitro, and paramagnetism behavior at room temperature due to the Ln3+-ions doping. Our research shows the possibility of our Ln-MCM-41 nanoparticles as multifunctional nanoprobes for application in bioseparation, bioimaging, and drug delivery.