Large scale and oxygen vacancy VO2 porous thin sheets to enable high-performance zinc ion storage.

Herein, we report the first result of large scale and oxygen vacancy VO2 porous thin sheets assembled by a 3D interconnected nanoflake array framework, which is recorded as VOd. The as-prepared VOd was characterized by various methods and Zn2+ intercalation/deintercalation and structural decomposition mechanisms were proposed based on ex situ X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS).

Oxygen vacancy enriched Na1.19V8O20·4.42H2O nanosheets for fast and stable Zn-ion batteries.

Here, a facile hydrothermal method is employed to prepare an oxygen vacancy enriched sodium-ion intercalation Na1.19V8O20·4.42H2O nanosheet cathode with large interlayer spacing, fast reaction kinetics, and stable structure for superior zinc-ion batteries (ZIBs). The assembled ZIB exhibits a high specific capacity and excellent structural stability without capacity decay over 2000 cycles. Moreover, the multiple ion co-intercalation mechanism and partial phase transition mechanism are elucidated based on ex situ characterization techniques.