RESUMO
Coal pyrolysis is a important method for classifying and utilizing coal resources and contributes to enhanced comprehensive resource utilization. However, In high-temperature areas such as coal pyrolysis, there is an abnormal phenomenon release of radioactive gas radon, understanding the relationship between temperature and radon exhalation characteristics, as well as the underlying mechanisms, holds great importance for assessing radon pollution in mining areas. After coal undergoes pyrolysis under high temperature conditions, its material composition, pore structure, water content, and other properties have changed. The pyrolysis products in different atmosphere environments have differences, and the characteristics of radon emission are also different. To address this, the present study conducted coal pyrolysis experiments in both aerobic and anaerobic environments, using long flame coal sourced from Yulin, China. The radon release concentration of the pyrolysis products was measured. The research findings indicate that during pyrolysis at elevated temperatures, the ratio of coal mass loss is constantly increasing. High temperatures promote the development of pores and fissures, and significant changes in coal properties at temperature thresholds (300 °C and 500 °C). The specific surface area, pore volume, and fracture ratio all display substantial increases, and the amplitude of change is greater under aerobic conditions. The fractal dimension of total pores and macropores shows continuous growth, while the specific surface area, pore volume, and fracture ratio exhibit a strong negative correlation with the radon emission rate of pyrolysis products. The expansion and penetration of pores and cracks, along with the release of a substantial amount of pyrolysis gas, accelerate the transformation, migration, and exhalation of radon, resulting in a negative correlation between the heat treatment temperature and the radon release rate of pyrolysis products. Under aerobic conditions, the radon release rate of pyrolysis products decreases more significantly.
RESUMO
Identifying the release characteristics of radon (Rn-222) in coal mines is critical preventing cancer risks for coal miners and coal fires. The present investigates the pore structure characteristics of coal samples from eleven coal mines in northern China, using low-temperature nitrogen adsorption (LTNA) test, combined with the radon exhalation rate in coal. The findings of the study reveal that the N2 adsorption isotherms of all the coal samples fall under the inverse S type, with micropores dominating in low-rank coals and mesopores dominating in the medium and high-rank coals, due to the separation of organic matter and quartz by shrinkage of micro-components and the orderly arrangement of aromatic rings as a result of ring condensation and thermal cleavage. The pore diameters of coal samples show similar distribution characteristics for sizes >2 nm, represented by a single peak near the pore diameter of 3 nm. Ash yield controls the mesopore and micropore volumes of medium and high-rank coal samples. The radon emission rate displays positive linear correlation (r2 = 0.87) with micropore volumes of analyzed coal samples due to the infillings of free radon in micropores. The radon element is derived by uranium decay, which causes a greater radon exhalation rate of coal mines in areas near the uranium mines. The results of the present study could be helpful to understand the influence mechanism of radon emission processes in coal, which provides an important basis for reducing cancer risks for coal miners and predicting coal fires.
