Preparation of benzenesulfonyl hydrazone modified guar gum and its adsorption properties for dyes and phytotoxicity assays.

Herein, a novel environmentally friendly benzenesulfonyl hydrazone modified guar gum (DGH) that carries excellent adsorption performance towards dyes was facilely prepared through oxidation and condensation. The structure, morphology, and physics-chemical of DGH were fully characterized by multiple analysis techniques. The as-prepared adsorbent yielded highly efficient separating performance towards multiple anionic and cation dyes, including CR, MG, and ST with the maximum adsorption capacity of 1065.3839 ± 10.5695, 1256.4467 ± 2.9425, and 1043.8140 ± 0.9789 mg/g at 298.15 K, respectively. The adsorption process well fitted the Langmuir isotherm models and the pseudo-second-order kinetic models. The adsorption thermodynamics revealed that the adsorption of dyes onto DGH was spontaneous and endothermic. The adsorption mechanism indicated that the hydrogen bonding and electrostatic interaction participated in the fast and efficient removal of dyes. Furthermore, the removal efficiency of DGH still remained above 90 % after six adsorption-desorption cycles, and the presence of Na+, Ca2+, and Mg2+ have weakly impacted the removal efficiency of DGH. The phytotoxicity assay was conducted via the germination of mung bean seeds, which confirmed the adsorbent can effectivity decreased the toxicity of dyes. Overall, the modified gum-based multifunctional material has good promising applications for wastewater treatment.

Highly selective and sensitive fluorescent probe possessing AIEE and ICT properties for rapid detection of Pb2+ in aqueous medium and its applications in living cells.

In this paper, a novel rapid, highly selective and sensitive Pb2+ fluorescent probe (E)-N'-((2-(4'-(diphenylamino)-[1,1'-biphenyl]-4-yl)-2H-1,2,3-triazol-4-yl)methylene) (DBTBH) was synthesized. The probe DBTBH not only exhibited more excellent selectivity and sensitivity to Pb2+ detection compared with other analytes (include metal ions and anions) in H2 O:THF solution (v:v = 9:1, 10 mM Tris-HCl, 1 mM KI, pH 7.4), but also had excellent optical properties such as aggregation-induced emission enhancement (AIEE) and intramolecular charge transfer (ICT). Detection limit of the probe DBTBH towards Pb2+ was 4.49 × 10-8 M. The possible mechanism was verified by 1 H NMR titration and HR-MS. Furthermore, the successful detection of Pb2+ by DBTBH in real water samples and HeLa cells indicated that DBTBH has great potential for selective recognition of Pb2+ in the natural environment and biological systems. These findings will provide a promising new idea for designing better Pb2+ fluorescent probes in the future.

Functionalized polymethyl methacrylate-modified dialdehyde guar gum containing hydrazide groups for effective removal and enrichment of dyes, ion, and oil/water separation.

In the study, a novel polymethacryloyl hydrazone modified guar gum adsorption material (GSA) was prepared via condensation between polyhydrazide and dialdehyde guar gum. GSA exhibited an abundant porous structure, higher selectivity for cationic pollutants in high-concentration wastewater like methylene blue (MB), malachite green (MG) dyes, and Cu2+. Under optimized experimental conditions, the maximum equilibrium adsorption capacity of MB, MG, and Cu2+ were 1418.36 mg/g, 1375.58 mg/g, and 196 mg/g, respectively. Adsorption isotherms and kinetics were well fitted with the Langmuir isotherm model and pseudo-second-order kinetic model. The thermodynamic analysis demonstrated that the adsorption process was endothermic, feasible, and spontaneous. Correspondently, the adsorption mechanism was explored by FTIR, SEM-EDS and XPS. The adsorbent was employed in disposing of local sewage water. Additionally, GSA successfully achieves efficient water/oil separation in different salt concentrations with a separation efficiency exceeding 99%.