Assessment of uranium migration and pollution sources in river sediments of the Ili River Basin using multiply statistical techniques.

Uranium (U) is a highly toxic radioactive element and limited to < 30 µg/L in drinking water by the World Health Organization. In this study, the concentration, distribution, possible source, and correlation with other elements of U were investigated in river sediments of the Ili River Basin. Metal contamination factors (CFs) and geoaccumulation index (Igeo) were calculated, and both of them indicated that U in the survey region was unpolluted, slightly polluted, or moderately polluted (its concentration was ranged from 1.37 to 5.99 mg/kg). Notably, U pollution in the tributaries near the Wusun Mountain was evidently higher than those in the main streams of the Ili River and the Tekes River. Principal component analysis (PCA), cluster analysis (CA), and correlation analysis revealed that U was significantly positively correlated with Pb, and both of them might have originated from the dense coal mines in the areas of the Wusun Mountain. Sediment U in the main streams of the rivers was unpolluted or slightly polluted, which might be strongly influenced by the U contamination in their upstream tributaries. The results from this work showed that the source control of the coal-derived U pollution near the Wusun Mountain was critical to protect the aquatic environment in the Ili River Basin.

The kinetics, thermodynamics and mineral crystallography of CaCO3 precipitation by dissolved organic matter and salinity.

Calcium carbonate (CaCO3) precipitation is an important geochemical process. In the estuary zone and some arid shallow lakes, DOM (dissolved organic matter) and salinity are two frequent changing factors that may affect CaCO3 precipitation. The joint effect of DOM and salinity on CaCO3 precipitation kinetics and thermodynamics are still unclear. In this study, effects of DOM on CaCO3 precipitation process at 0.5‰ and 70‰ salinity were investigated by QCM (Quartz Crystal Microbalance) technique, real-time pH measurement and single-injection nanoliter ITC (isothermal titration calorimetry). The mineral crystallography was analyzed by SEM-EDS. Both DOM and salinity had inhibitory effect on CaCO3 precipitation. DOM had more pronounced inhibitory effect on CaCO3 precipitation at lower salinity. Regardless of DOM, 70‰ salinity inhibited CaCO3 precipitation >0.5‰ salinity. The CaCO3 precipitation kinetics followed the first-order kinetic model and the adhesion kinetics of the instantaneous nucleation and crystal growth stage could be well described by the exponential function. CaCO3 precipitation was an endothermic process and high salinity strongly hindered CaCO3 precipitation. The effect of DOM on the absorbed heat was significant at 0.5‰ salinity. At 70‰ salinity, regardless of the effect of DOM, CaCO3 precipitation rate was greatly slowed down because it needed much more heat. CaCO3 minerals were dominated by rhombohedral calcite while CaCO3 minerals were mainly shaped as spherical vaterite at 0.5‰ salinity and rhombohedral calcite at 70‰ salinity. The crystal phase changed during CaCO3 precipitation at 0.5‰ salinity. In conclusion, the presence of DOM had substantial impact on the micrograph of the CaCO3 minerals. The percentage of flawed crystals with rough surface increased significantly with increased DOM concentration.