Post-processing phase-correction algorithm in two-dimensional electronic spectroscopy.

In a typical two-dimensional electronic spectroscopy (2DES) experiment, the timing errors of the coherence and emission time when determining the absolute time zeros usually introduce extraneous spectral phase slopes and distort the 2D spectrum. In this work, a phase-correction method that merely relies on the data post-processing algorithm is proposed. The method allows reconstructing the spectrum by simply subtracting the artificial linear spectral-phase slopes from the phase component of the 2D spectrum along both coherence and emission frequency axes. The new method has the advantages of ease of implementation and no need for the supplementary experiments and iterative fitting algorithm as commonly-used phasing methods, which may improve the phasing issue in 2DES and serve as a cross-check of now available phasing methods.

Precise phase determination with the built-in spectral interferometry in two-dimensional electronic spectroscopy.

A new method determining the precise phase of pulse sequences in two-dimensional electronic spectroscopy (2DES) is proposed merely using the already built-in spectral interferometry. The approach is easily implemented without the supplementary instrumental construction, only at the expense of a few additional scanning and data-fitting processes. This method is executed with the sample in place, effectively avoiding the phase ambiguities of the beam propagation in samples, thus calibrating the absolute phase at the exact interaction region. The new proposed method is expected to improve the phasing procedure in 2DES in a more convenient way.

Scaling laws for photoelectron holography in the midinfrared wavelength regime.

Midinfrared strong-field laser ionization offers the promise of measuring holograms of atoms and molecules, which contain both spatial and temporal information of the ion and the photoelectron with subfemtosecond temporal and angstrom spatial resolution. We report on the scaling of photoelectron holographic interference patterns with the laser pulse duration, wavelength, and intensity. High-resolution holograms for the ionization of metastable xenon atoms by 7-16 µm light from the FELICE free electron laser are presented and compared to semiclassical calculations that provide analytical insight.

Interference carpets in above-threshold ionization: from the Coulomb-free to the Coulomb-dominated regime.

The velocity map recorded in above-threshold ionization of xenon at 800 nm exhibits a distinct carpetlike pattern of maxima and minima for emission in the direction approximately perpendicular to the laser polarization. The pattern is well reproduced by a numerical solution of the time-dependent Schrödinger equation. In terms of the simple-man model and the strong-field approximation, it is explained by the constructive and destructive interference of the contribution of the long and the short orbit. Strictly perpendicular emission is caused by ionization at the two peaks of the laser field per cycle, which results in a 2hω separation of the above-threshold ionization rings.