Design of P-decorated POSS towards flame-retardant, mechanically-strong, tough and transparent epoxy resins.

Epoxy resins (EPs) are known for their durability, strength, and adhesive properties, which make them a versatile and popular material for use in a variety of applications, including chemical anticorrosion, small electronic devices, etc. However, EP is highly flammable due to its chemical nature. In this study, phosphorus-containing organic-inorganic hybrid flame retardant (APOP) was synthesized by introducing 9, 10-dihydro-9-oxa-10­phosphaphenathrene (DOPO) into cage-like octaminopropyl silsesquioxane (OA-POSS) via Schiff base reaction. The improved flame retardancy of EP was achieved by combining the physical barrier of inorganic Si-O-Si with the flame-retardant capability of phosphaphenanthrene. EP composites containing 3 wt% APOP passed the V-1 rating with a value of LOI of 30.1% and showed an apparent reduction in smoke release. Additionally, the combination of the inorganic structure and the flexible aliphatic segment in the hybrid flame retardant provides EP with molecular reinforcement, while the abundance of amino groups facilitates a good interface compatibility and outstanding transparency. Accordingly, EP containing 3 wt% APOP increased in tensile strength, impact strength, and flexural strength by 66.0 %, 78.6 %, and 32.3 %, respectively. The EP/APOP composites had a bending angle lower than 90°, and their successful transition to a tough material highlights the potential of this innovative combination of the inorganic structure and the flexible aliphatic segment. In addition, the relevant flame-retardant mechanism revealed that the APOP promoted the formation of a hybrid char layer containing P/N/Si for EP and produced phosphorus-containing fragments during combustion, showing flame-retardant effects in both condensed and vapor phases. This research offers innovative solutions for reconciling flame retardancy & mechanical performances and strength & toughness for polymers.

Growth of copper organophosphate nanosheets on graphene oxide to improve fire safety and mechanical strength of epoxy resins.

With the high integration of electronic products in our daily life, high-performance epoxy resins (EP) with excellent flame retardancy, smoke suppression, and mechanical strength are highly desired for applications. In this study, copper organophosphate nanosheets were evenly grown on the surface of graphene oxide (GO) via a self-assembly process based on coordination bonding and electrostatic interactions. The resultant nanohybrid endowed EP with satisfactory flame retardant effect and improved mechanical properties. Incorporating functionalized nanosheets of merely 1 wt% loading, the impact strength of the EP nanocomposites improved by 147% when compared to 1% EP-GO. Additionally, the nanosheets inhibited the smoke and heat release of EP, and the limiting oxygen value of EP-EGOPC reached ∼29%. The mechanism analysis verified that the existence of organophosphate and copper-containing components associated with the physical barrier of GO promoted the hybrid aromatization of the char layer, thereby improving the fire safety of epoxy matrix. This research offers a new interfacial method for designing functional nanosheets with good interface compatibility and high flame-retardant efficiency in polymers.

Interfacial engineering to construct P-loaded hollow nanohybrids for flame-retardant and high-performance epoxy resins.

Nano flame retardants, as one of the key flame retardants in recent years, have been limited by poor efficiency and weak compatibility. In this study, we propose an interfacial hollow engineering strategy to tackle this problem by assembling P-phytic acid into the hollow cavity of mesoporous SiO2 grafted with a polydopamine transition metal. In this design, the grafted polydopamine-metal coatings on the hybrids can greatly improve their interface compatibility with the polymer matrix, while the loaded phytic acid in the cavity contributes to enhance flame retardancy. Consequently, the resultant hierarchical P-loaded nanohybrids show both high flame retardancy and mechanical reinforcement for the polymer. Taking epoxy resin (EP, a typical thermosetting resin used in large quantities) as a representative, at only 1 wt% loading of the nanohybrids, the impact strength of the nanocomposites improved by 35.7% compared to pure EP. Remarkably, the hybrids can simultaneously endow EP with high flame retardancy (low heat release rate) and satisfactory smoke inhibition. Additionally, the flame-retardant mechanism analysis confirmed that the nanohybrid had a better catalytic carbonization effect on promoting the highly graphitized carbon layer, thereby suppressing the fire hazard of epoxy resins. This research offers a new interfacial hollow engineering method for the construct and design of high-performance EP with nanohybrids.