1.
Org Biomol Chem
; 20(35): 7001-7005, 2022 09 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36000329
RESUMO
Aqueous microdroplets exhibit unique properties and can trigger reactions that do not occur in bulk solution. Herein, we have demonstrated that water, in microdroplets, can reduce the energy barrier for the lone H transfer of 9-fluorenylmethyloxycarbonyl and promote its detachment from the amino group. This strategy works on various amino acids and opens opportunities of aqueous microdroplets in triggering organic reactions.