Evaluating iron remediation with limestone using spectral induced polarization and microscopic techniques.

Groundwater contamination with iron caused by mining and landfill activities has fueled the development of remediation strategies. Permeable reactive barriers (PRBs) are commonly applied in subsurface remediation because of their high removal effect and low costs. Spectral induced polarization (SIP) technique has been approved for its nondestructive ability to monitor the geochemical processes in porous media. In this study, SIP technique was applied for monitoring iron remediation by limestone at column scale. The chemical analysis showed the pH of the porous fluid increased - attributed to the dissolution of limestone, which promoted the precipitation of iron. The precipitate phases included both γ-FeOOH and Fe2O3 based on X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) results. The micro computed tomography (CT) technique investigated the uneven distribution of the precipitates in the column, which indicated the existence of preferential flow. SIP signals revealed the quantity of the accumulated iron precipitates, which was proved by the chemical measurement and calculation. SIP signals also derived the time evolution of both the average precipitate size and size distribution, which elucidated the processes of precipitate crystal growth and aggregation during Fe flow-through. Above results suggest that SIP holds the promise of monitoring the engineering barrier performance.

Content and morphology of lead remediated by activated carbon and biochar: A spectral induced polarization study.

Soil and groundwater contamination with lead (Pb) poses serious challenges for the environment. Activated carbon (AC) and biochar have huge potential application in the in-situ remediation processes through permeable reactive barriers (PRB). Spectral induced polarization (SIP) technique recently showed promises in nondestructively monitoring the spatio-temporal characteristics of physical, chemical and biological processes in porous media. In this study SIP technique was used for monitoring Pb remediation by AC and biochar in column scale. The calculated characteristic grain/pore size evolutions from SIP signals on AC, agreed well with the size of precipitates measured by SEM and mercury intrusion porosimetry (MIP) methods. The content increment process of the retained Pb on AC was also recorded via the magnitude increment of the imaginary conductivity. The mechanisms of Pb-AC and Pb-biochar interactions were investigated using SEM-EDS, TEM, FTIR, XRD, and XPS measurements. It showed that AC immobilizes through physical adsorption and precipitation, whereas complexation with functional groups is the remediation mechanism for biochar. Furthermore, the observed SIP responses of both AC and biochar are two orders of magnitude higher than those of typical natural soils or silica materials. This distinct difference is an additional advantage for the field application of SIP technique in PRB scenarios.

Emerging sustainable technologies for remediation of soils and groundwater in a municipal solid waste landfill site -- A review.

Remediation of soils and groundwater in a municipal solid wastes (MSW) landfill site emerges as a global challenge to the living environment on earth with significant market potential. Unlike contaminants in an industry or agricultural site, contaminants from MSW landfills are diverse, primarily consisting of chemical oxygen demand (COD), inorganic matter (ammonia-nitrogen, nitrate-nitrogen, total phosphorus) and heavy metals. This renders new challenges to remediation contaminants of different characters altogether. A status quo of existing technologies, including permeable reactive barriers, electrokinetic remediation, microbial remediation, and injection of either solubilizing agents or micro or nanobubbles were thoroughly reviewed, with an emphasis on removal efficiency based on existing projects at lab, pilot or field scales. A design chart tailored for the remediation of a landfill contaminated site was developed, verified by a few case studies, which supplement the chart. Future trends of technical innovation (such as multi-layer permeable reactive barriers (PRBs)) and challenges (such as flow pattern) were identified.