Short-chain fatty acids recovery from sewage sludge via acidogenic fermentation as a carbon source for denitrification: A review.

Wastewater treatment plants face the problem of a shortage of carbon source for denitrification. Acidogenic fermentation is an effective method for recovering short-chain fatty acids (SCFAs) as a carbon source from sewage sludge. Herein, the most recent advances in SCFAs production from primary sludge and waste activated sludge are systematically summarised and discussed. New technologies and problems pertaining to the improvement in SCFAs availability in fermentation liquids, including removal of ammoniacal nitrogen and phosphate and extraction of SCFAs from fermentation liquids, are analysed and evaluated. Furthermore, studies on the use of recovered SCFAs as a carbon source for denitrification are reviewed. Based on the above summarisation and discussion, some conclusions as well as perspectives on future studies and practical applications are presented. In particular, the recovery of carbon source/bioenergy from sewage sludge must be optimised considering nutrient removal/recovery simultaneously.

Using an expended granular sludge bed reactor for advanced anaerobic digestion of food waste pretreated with enzyme: The feasibility and its performance.

The high content of solid organics in food waste (FW) results in a low and unstable anaerobic digestion (AD) efficiency. Improving methane production rate and process stability is attracting much attention towards advanced AD of FW. The feasibility of advanced AD of FW pretreated with enzyme was investigated by batch experiments and 164 days running of an expanded granular sludge bed (EGSB) reactor. Simulation study based on the results of batch experiments indicates it is possible to treat enzymatically pretreated FW using an EGSB reactor. During the running of an EGSB reactor, the organic loading rate went up to 20 g chemical oxygen demand (COD)/L.d, and the total COD removal rate reached 88%. The significance of this study is to achieve an advanced AD of enzymatically pretreated FW with a stable and efficient methane production with biogas residue being reduced greatly.

Bioenergy, ammonia and humic substances recovery from municipal solid waste leachate: A review and process integration.

High strength of organic matters and nitrogen are the most concerns in treatment of municipal solid waste leachate, but can be removed and recovered as bioenergy and fertilizer. A few review papers on leachate treatment technologies and single resource recovery have been published. However, none practical leachate treatment process towards multiple resources recovery has been worked out. In this paper, technologies of bioenergy, ammonia and humic substances recovery from municipal solid waste leachate are summarized. A two-stage anaerobic digestion comprising an expanded granular sludge bed reactor and an anaerobic membrane bioreactor is suggested to maximize methane production as bioenergy. Ammonia recovery by biogas recirculation with simultaneous calcium removal is proposed for the first time. Humic substances are suggested to be recovered as fertilizer from nanofiltration concentrate by membrane technology. A novel integrated leachate treatment process is proposed for resources recovery from leachate, with more environmental and economic benefits.

Alkaline fermentation of waste activated sludge with calcium hydroxide to improve short-chain fatty acids production and extraction efficiency via layered double hydroxides.

Ca(OH)2 addition was proposed to improve short chain fatty acids (SCFAs) production via alkaline fermentation of waste activated sludge (WAS), with CO32- and PO43- being removed simultaneously, so that the SCFAs extraction efficiency could be improved. Alkaline fermentation of WAS with Ca(OH)2 and NaOH addition were performed respectively, and the efficiencies of SCFAs extraction from the fermentation liquids via in situ layered double hydroxides (LDHs) were investigated. The results showed that, the SCFAs production was much more improved with NaOH addition than that with Ca(OH)2 addition. However, the SCFAs contents in the synthesized SCFAs-LDH were 6.7 ±â€¯0.4 mg COD/L (control), 12.4 ±â€¯0.5 mg COD/L (with NaOH addition) and 17.4 ±â€¯0.4 mg COD/L (with Ca(OH)2 addition), respectively. This means that Ca(OH)2 addition is an effective way to improve SCFAs extraction from fermentation liquid of WAS.

Reusing effluent of flue gas desulfurization wastewater treatment process as an economical calcium source for phosphorus removal.

Flue gas desulfurization (FGD) wastewater treatment by conventional neutralization, chemical precipitation and coagulation process removes most suspended solids and heavy metals, and provides an effluent rich in calcium, alkalinity and chloride, which obstructs its reclamation and reuse but is in favor of phosphorus (P) precipitation. The goals of this study were to investigate feasibility of reusing FGD effluent as a calcium source for P removal from P-rich wastewater. Results revealed that increasing the volumetric ratio between FGD effluent and P-rich wastewater achieved higher pH value and Ca/P ratio, and thus enhanced P removal efficiency to 94.3% at the ratio of 40%. X-ray diffraction and scanning electron microscope analysis of harvested precipitates showed that increasing pH from 8 to 10 induced the conversion of hydroxyapatite to tri-calcium phosphate, and then to whitlockite. This study demonstrated that for reusing FGD effluent for P removal was highly feasible, both technically and economically. This process not only saves the cost of precipitants for P removal, but also provides an economical alternative for current zero liquid discharge technology for FGD wastewater, which requires high energy consumption and capital costs.