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1.
Nat Commun ; 14(1): 2785, 2023 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-37188687

RESUMO

Conductive yarns have emerged as a viable alternative to metallic wires in e-Textile devices, such as antennas, inductors, interconnects, and more, which are integral components of smart clothing applications. But the parasitic capacitance induced by their micro-structure has not been fully understood. This capacitance greatly affects device performance in high-frequency applications. We propose a lump-sum and turn-to-turn model of an air-core helical inductor constructed from conductive yarns, and systematically analyze and quantify the parasitic elements of conductive yarns. Using three commercial conductive yarns as examples, we compare the frequency response of copper-based and yarn-based inductors with identical structures to extract the parasitic capacitance. Our measurements show that the unit-length parasitic capacitance of commercial conductive yarns ranges from 1 fF/cm to 3 fF/cm, depending on the yarn's microstructure. These measurements offer significant quantitative estimation of conductive yarn parasitic elements and provide valuable design and characterization guidelines for e-Textile devices.

2.
RSC Adv ; 12(43): 27687-27697, 2022 Sep 28.
Artigo em Inglês | MEDLINE | ID: mdl-36320245

RESUMO

Poly-l-lactic acid (PLLA) is a synthetic, biocompatible, biodegradable polymer with good piezoelectric properties. The prepared PLLA films were annealed in the oven at 140 °C for 0 h, 3 h, 12 h, and 24 h, respectively. The influences of temperature treatment time on the optoelectronic properties of the PLLA films and piezoelectric sensors based on them were investigated. The morphology and crystal structure of the PLLA films obtained under various post-processing conditions were examined by scanning electron microscopy, X-ray diffraction, Raman spectroscopy, and ATR-FTIR spectroscopy. The micromechanical equipment for tension-compression measurements was built in the laboratory for the tested piezoelectric sensors. The analysis of the structure shows that the increase in the crystallite size of the PLLA film influences the growth of the piezoelectric signal of the sensors based on them. The vibrational analysis of the PLLA films confirmed their crystal structure. The improvement in the structure and the stretching of the dipole C[double bond, length as m-dash]O for the film obtained after 3 h treatment increased the piezoelectric properties of the PLLA films. The analysis of Raman mapping added information that the area of the ordered phase of the PLLA films depends on the time of temperature treatment. The maximum value of the piezoelectric signal was 0.98 mV for sensors prepared on films annealed for 3 h at a load of 20 N. For films without temperature annealing at the same load, the maximum value was 0.45 mV. Thus, efficient converters of mechanical energy into electrical energy were obtained, which opens new innovative perspectives for the creation of flexible pressure sensors based on PLLA.

3.
Nano Lett ; 22(16): 6647-6654, 2022 08 24.
Artigo em Inglês | MEDLINE | ID: mdl-35943807

RESUMO

Wearable sweat monitoring represents an attractive opportunity for personalized healthcare and for evaluating sports performance. One of the limitations with such monitoring, however, is water layer formation upon cycling of ion-selective sensors, leading to degraded sensitivity and long-term instability. Our report is the first to use chemical vapor deposition-grown, three-dimensional, graphene-based, gradient porous electrodes to minimize such water layer formation. The proposed design reduces the ion diffusion path within the polymeric ion-selective membrane and enhances the electroactive surface for highly sensitive, real-time detection of Na+ ions in human sweat with high selectivity. We obtained a 7-fold enhancement in electroactive surface against 2D electrodes (e.g., carbon, gold), yielding a sensitivity of 65.1 ± 0.25 mV decade-1 (n = 3, RSD = 0.39%), the highest to date for wearable Na+ sweat sensors. The on-body sweat sensing performance is comparable to that of ICP-MS, suggesting its feasibility for health evaluation through sweat.


Assuntos
Técnicas Biossensoriais , Grafite , Dispositivos Eletrônicos Vestíveis , Técnicas Biossensoriais/métodos , Humanos , Íons , Porosidade , Sódio , Suor , Água
4.
ACS Appl Mater Interfaces ; 14(21): 24946-24954, 2022 Jun 01.
Artigo em Inglês | MEDLINE | ID: mdl-35593079

RESUMO

Keypads constructed from fabric materials are the ideal input devices for smart clothing applications. However, multi-modal reaction problems have to be addressed before they can be of practical use on apparels, i.e., the fabric-based keypads need to distinguish between the legitimate actions by the fingertips and the illegitimate deformations and stresses caused by human movements. In this paper, we propose to use the humidity sensor functionalized from graphene oxide (GO)-coated polyester fibers to construct the e-textile keypads. As the moisture level in the proximity of human fingertips is much higher (over 70%) than other parts of the human body, humidity sensing has many advantages over other tactility mechanisms. Experiments have demonstrated that the GO-functionalized fabric keypad has a stable uni-modal tactility only to fingertip touches, and it is not sensitive to deformation, pressure, temperature variation, and other ambient interferences. With biasing and sensing circuits, the keypad exhibits a quick response and recovery time (around 0.1 s), comparable to mechanical keyboards. To demonstrate its application on smart clothing, the keypad was sewn on a sweater and embroidered conductive yarns were used to control an MP3 player in the pocket.

5.
Microorganisms ; 10(1)2021 Dec 27.
Artigo em Inglês | MEDLINE | ID: mdl-35056495

RESUMO

Through recent decades, the subtherapeutic use of antibiotics within agriculture has led to the widespread development of antimicrobial resistance. This problem not only impacts the productivity and sustainability of current agriculture but also has the potential to transfer antimicrobial resistance to human pathogens via the food supply chain. An increasingly popular alternative to antibiotics is bacteriophages to control bacterial diseases. Their unique bactericidal properties make them an ideal alternative to antibiotics, as many countries begin to restrict the usage of antibiotics in agriculture. This review analyses recent evidence from within the past decade on the efficacy of phage therapy on common foodborne pathogens, namely, Escherica coli, Staphylococcus aureus, Salmonella spp., and Campylobacter jejuni. This paper highlights the benefits and challenges of phage therapy and reveals the potential for phages to control bacterial populations both in food processing and livestock and the possibility for phages to replace subtherapeutic usage of antibiotics in the agriculture sector.

6.
ACS Appl Mater Interfaces ; 12(11): 13265-13274, 2020 Mar 18.
Artigo em Inglês | MEDLINE | ID: mdl-32105063

RESUMO

E-textile consisting of natural fabrics has become a promising material to construct wearable sensors due to its comfortability and breathability on the human body. However, the reported fabric-based e-textile materials, such as graphene-treated cotton, silk, and flax, generally suffer from the electrical and mechanical instability in long-term wearing. In particular, fabrics on the human body have to endure heat variation, moisture evaporation from metabolic activities, and even the immersion with body sweat. To face the above challenges, here we report a wool-knitted fabric sensor treated with graphene oxide (GO) dyeing followed by l-ascorbic acid (l-AA) reduction (rGO). This rGO-based strain sensor is highly stretchable, washable, and durable with rapid sensing response. It exhibits excellent linearity with more than 20% elongation and, most importantly, withstand moisture from 30 to 90% (or even immersed with water) and still maintains good electrical and mechanical properties. We further demonstrate that, by integrating this proposed material with the near-field communication (NFC) system, a batteryless, wireless wearable body movement sensor can be constructed. This material can find wide use in smart garment applications.


Assuntos
Grafite/química , Dispositivos Eletrônicos Vestíveis , Fibra de Lã , Teste de Materiais , Fenômenos Mecânicos , Molhabilidade
7.
Sci Rep ; 7: 45108, 2017 03 21.
Artigo em Inglês | MEDLINE | ID: mdl-28322338

RESUMO

Metamaterials have attracted more and more research attentions recently. Metamaterials for electromagnetic applications consist of sub-wavelength structures designed to exhibit particular responses to an incident EM (electromagnetic) wave. Traditional EM (electromagnetic) metamaterial is constructed from thick and rigid structures, with the form-factor suitable for applications only in higher frequencies (above GHz) in microwave band. In this paper, we developed a thin and flexible metamaterial structure with small-scale unit cell that gives EM metamaterials far greater flexibility in numerous applications. By incorporating ferrite materials, the thickness and size of the unit cell of metamaterials have been effectively scaled down. The design, mechanism and development of flexible ferrite loaded metamaterials for microwave applications is described, with simulation as well as measurements. Experiments show that the ferrite film with permeability of 10 could reduce the resonant frequency. The thickness of the final metamaterials is only 0.3mm. This type of ferrite loaded metamaterials offers opportunities for various sub-GHz microwave applications, such as cloaks, absorbers, and frequency selective surfaces.

8.
Materials (Basel) ; 9(12)2016 Dec 13.
Artigo em Inglês | MEDLINE | ID: mdl-28774128

RESUMO

Electromagnetic metamaterials are constructed with sub-wavelength structures that exhibit particular electromagnetic properties under a certain frequency range. Because the form-factor of the substructures has to be comparable to the wavelength of the operating frequency, few papers have discussed the metamaterials under GHz frequency. In this paper, we developed an innovative method to reduce the resonant frequency of metamaterals. By integrating the meta-structures with ferrite materials of higher permeability, the cell size of the meta-structure can be scaled down. This paper describes the methodology, design, and development of low-profile GHz ferrite loaded metamaterials. A ferrite film with a permeability of 20 could reduce the resonant frequency of metamaterials by up to 50%. A prototype has been fabricated and the measurement data align well with the simulation results. Because of the lowered operational frequency, the proposed ferrite loaded metamaterials offer more flexibility for various sub-GHz microwave applications, such as cloaks, absorbers, and frequency selective surfaces.

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