Pseudomagic Quantum States.

Notions of nonstabilizerness, or "magic," quantify how nonclassical quantum states are in a precise sense: states exhibiting low nonstabilizerness preclude quantum advantage. We introduce "pseudomagic" ensembles of quantum states that, despite low nonstabilizerness, are computationally indistinguishable from those with high nonstabilizerness. Previously, such computational indistinguishability has been studied with respect to entanglement, introducing the concept of pseudoentanglement. However, we demonstrate that pseudomagic neither follows from pseudoentanglement nor implies it. In terms of applications, the study of pseudomagic offers fresh insights into the theory of quantum scrambling: it uncovers states that, even though they originate from nonscrambling unitaries, remain indistinguishable from scrambled states to any physical observer. Additional applications include new lower bounds on state synthesis problems, property testing protocols, and implications for quantum cryptography. Our Letter is driven by the observation that only quantities measurable by a computationally bounded observer-intrinsically limited by finite-time computational constraints-hold physical significance. Ultimately, our findings suggest that nonstabilizerness is a "hide-able" characteristic of quantum states: some states are much more magical than is apparent to a computationally bounded observer.

Roadmap for Optical Metasurfaces.

Metasurfaces have recently risen to prominence in optical research, providing unique functionalities that can be used for imaging, beam forming, holography, polarimetry, and many more, while keeping device dimensions small. Despite the fact that a vast range of basic metasurface designs has already been thoroughly studied in the literature, the number of metasurface-related papers is still growing at a rapid pace, as metasurface research is now spreading to adjacent fields, including computational imaging, augmented and virtual reality, automotive, display, biosensing, nonlinear, quantum and topological optics, optical computing, and more. At the same time, the ability of metasurfaces to perform optical functions in much more compact optical systems has triggered strong and constantly growing interest from various industries that greatly benefit from the availability of miniaturized, highly functional, and efficient optical components that can be integrated in optoelectronic systems at low cost. This creates a truly unique opportunity for the field of metasurfaces to make both a scientific and an industrial impact. The goal of this Roadmap is to mark this "golden age" of metasurface research and define future directions to encourage scientists and engineers to drive research and development in the field of metasurfaces toward both scientific excellence and broad industrial adoption.

Enhancing detection of topological order by local error correction.

The exploration of topologically-ordered states of matter is a long-standing goal at the interface of several subfields of the physical sciences. Such states feature intriguing physical properties such as long-range entanglement, emergent gauge fields and non-local correlations, and can aid in realization of scalable fault-tolerant quantum computation. However, these same features also make creation, detection, and characterization of topologically-ordered states particularly challenging. Motivated by recent experimental demonstrations, we introduce a paradigm for quantifying topological states-locally error-corrected decoration (LED)-by combining methods of error correction with ideas of renormalization-group flow. Our approach allows for efficient and robust identification of topological order, and is applicable in the presence of incoherent noise sources, making it particularly suitable for realistic experiments. We demonstrate the power of LED using numerical simulations of the toric code under a variety of perturbations. We subsequently apply it to an experimental realization, providing new insights into a quantum spin liquid created on a Rydberg-atom simulator. Finally, we extend LED to generic topological phases, including those with non-abelian order.

Chemical reactivity under collective vibrational strong coupling.

Recent experiments of chemical reactions in optical cavities have shown great promise to alter and steer chemical reactions, but still remain poorly understood theoretically. In particular, the origin of resonant effects between the cavity and certain vibrational modes in the collective limit is still subject to active research. In this paper, we study the unimolecular dissociation reactions of many molecules, collectively interacting with an infrared cavity mode, through their vibrational dipole moment. We find that the reaction rate can slow down by increasing the number of aligned molecules, if the cavity mode is resonant with a vibrational mode of the molecules. We also discover a simple scaling relation that scales with the collective Rabi splitting, to estimate the onset of reaction rate modification by collective vibrational strong coupling and numerically demonstrate these effects for up to 104 molecules.

Beam steering at the nanosecond time scale with an atomically thin reflector.

Techniques to mold the flow of light on subwavelength scales enable fundamentally new optical systems and device applications. The realization of programmable, active optical systems with fast, tunable components is among the outstanding challenges in the field. Here, we experimentally demonstrate a few-pixel beam steering device based on electrostatic gate control of excitons in an atomically thin semiconductor with strong light-matter interactions. By combining the high reflectivity of a MoSe2 monolayer with a graphene split-gate geometry, we shape the wavefront phase profile to achieve continuously tunable beam deflection with a range of 10°, two-dimensional beam steering, and switching times down to 1.6 nanoseconds. Our approach opens the door for a new class of atomically thin optical systems, such as rapidly switchable beam arrays and quantum metasurfaces operating at their fundamental thickness limit.

Entangled photons from composite cascade emitters.

One of the most versatile sources for entangled photons are emitters that interact via more than one tunable mechanism. Here, we demonstrate how hybridization and dipole-dipole interactions-potentially simultaneously available in colloidal quantum dots and molecular aggregates-leveraged in conjunction can couple simple, well understood emitters into composite emitters with flexible control over the level structure. We show that cascade decay through carefully designed level structures can result in emission of frequency-entangled photons with Bell states and three-photon GHZ states as example cases. These results pave the way toward rational design of quantum optical emitters of entangled photons.

Cavity-Modified Unimolecular Dissociation Reactions via Intramolecular Vibrational Energy Redistribution.

While the emerging field of vibrational polariton chemistry has the potential to overcome traditional limitations of synthetic chemistry, the underlying mechanism is not yet well understood. Here, we explore how the dynamics of unimolecular dissociation reactions that are rate-limited by intramolecular vibrational energy redistribution (IVR) can be modified inside an infrared optical cavity. We study a classical model of a bent triatomic molecule, where the two outer atoms are bound by anharmonic Morse potentials to the center atom coupled to a harmonic bending mode. We show that an optical cavity resonantly coupled to particular anharmonic vibrational modes can interfere with IVR and alter unimolecular dissociation reaction rates when the cavity mode acts as a reservoir for vibrational energy. These results lay the foundation for further theoretical work toward understanding the intriguing experimental results of vibrational polaritonic chemistry within the context of IVR.

Defect Polaritons from First Principles.

Control over the optical properties of defects in solid-state materials is necessary for their application in quantum technologies. In this study, we demonstrate, from first principles, how to tune these properties via the formation of defect polaritons in an optical cavity. We show that the polaritonic splitting that shifts the absorption energy of the lower polariton is much higher than can be expected from a Jaynes-Cummings interaction. We also find that the absorption intensity of the lower polariton increases by several orders of magnitude, suggesting a possible route toward overcoming phonon-limited single-photon emission from defect centers. These findings are a result of an effective continuum of electronic transitions near the lowest-lying electronic transition that dramatically enhances the strength of the light-matter interaction. We expect our findings to spur experimental investigations of strong light-matter coupling between defect centers and cavity photons for applications in quantum technologies.

Controlling Interactions between Quantum Emitters Using Atom Arrays.

We investigate the potential for two-dimensional atom arrays to modify the radiation and interaction of individual quantum emitters. Specifically, we demonstrate that control over the emission linewidths, resonant frequency shifts, and local driving field enhancement in impurity atoms is possible due to strong dipole-dipole interactions within ordered, subwavelength atom array configurations. We demonstrate that these effects can be used to dramatically enhance coherent dipole-dipole interactions between distant impurity atoms within an atom array. Possible experimental realizations and potential applications are discussed.

Cooperative Breakdown of the Oscillator Blockade in the Dicke Model.

The Dicke model, which describes the coupling of an ensemble of spins to a harmonic oscillator, is known for its superradiant phase transition, which can both be observed in the ground state in a purely Hamiltonian setting, as well as in the steady state of an open-system Dicke model with dissipation. We demonstrate that, in addition, the dissipative Dicke model can undergo a second phase transition to a nonstationary phase, characterized by unlimited heating of the harmonic oscillator. Identifying the mechanism of the phase transition and deriving the scaling of the critical coupling with the system size we conclude that the novel phase transition can be understood as a cooperative breakdown of the oscillator blockade which otherwise prevents higher excitation of the system. We discuss an implementation with trapped ions and investigate the role of cooling, by which the breakdown can be suppressed.

Quantum Nonlinear Optics in Atomically Thin Materials.

We show that a nonlinear optical response associated with a resonant, atomically thin material can be dramatically enhanced by placing it in front of a partially reflecting mirror, rendering otherwise weakly nonlinear systems suitable for experiments and applications involving quantum nonlinear optics. Our approach exploits the nonlinear response of long-lived polariton resonances that arise at particular distances between the material and the mirror. The scheme is entirely based on free-space optics, eliminating the need for cavities or complex nanophotonic structures. We analyze a specific implementation based on exciton-polariton resonances in two-dimensional semiconductors and discuss the role of imperfections and loss.

Cooperative Resonances in Light Scattering from Two-Dimensional Atomic Arrays.

We consider light scattering off a two-dimensional (2D) dipolar array and show how it can be tailored by properly choosing the lattice constant of the order of the incident wavelength. In particular, we demonstrate that such arrays can operate as a nearly perfect mirror for a wide range of incident angles and frequencies, and shape the emission pattern from an individual quantum emitter into a well-defined, collimated beam. These results can be understood in terms of the cooperative resonances of the surface modes supported by the 2D array. Experimental realizations are discussed, using ultracold arrays of trapped atoms and excitons in 2D semiconductor materials, as well as potential applications ranging from atomically thin metasurfaces to single photon nonlinear optics and nanomechanics.

Rydberg atom mediated polar molecule interactions: a tool for molecular-state conditional quantum gates and individual addressability.

We study the possibility to use interaction between a polar molecule in the ground electronic and vibrational state and a Rydberg atom to construct two-qubit gates between molecular qubits and to coherently control molecular states. A polar molecule within the electron orbit in a Rydberg atom can either shift the Rydberg state, or form a Rydberg molecule. Both the atomic shift and the Rydberg molecule states depend on the initial internal state of the polar molecule, resulting in molecular state dependent van der Waals or dipole-dipole interaction between Rydberg atoms. Rydberg atoms mediated interaction between polar molecules can be enhanced up to 10(3) times. We describe how the coupling between a polar molecule and a Rydberg atom can be applied to coherently control molecular states, and specifically, to individually address molecules in an optical lattice, and to non-destructively readout molecular qubits.

Tunable negative refraction without absorption via electromagnetically induced chirality.

We show that negative refraction with minimal absorption can be obtained by means of quantum interference effects similar to electromagnetically induced transparency (EIT). Coupling a magnetic dipole transition coherently with an electric dipole transition leads to electromagnetically induced chirality, which can provide negative refraction without requiring negative permeability and also suppress absorption. This technique allows negative refraction in the optical regime at densities where the magnetic susceptibility is still small and with refraction/absorption ratios that are orders of magnitude larger than those achievable previously. Furthermore, the refractive index can be fine-tuned, which is essential for practical realization of subdiffraction-limit imaging. As with EIT, electromagnetically induced chirality should be applicable to a wide range of systems.