Kinetic and mechanistic investigations of the degradation of propranolol in heat activated persulfate process.

This study investigated the heat activated persulfate (heat/PS) process in the degradation of propranolol from water. Various factors (e.g., temperature, persulfate dose, initial pH and natural water constituent) on PRO degradation kinetics have been investigated. The results showed that the PRO degradation followed a pseudo-first-order kinetics pattern. As temperature rises, the pseudo-first-order rate constant (k obs) was improved significantly, and the k obs determined at 40-70 °C satisfied the Arrhenius equation, yielding an activation energy of 99.0 kJ mol-1. The radical scavenging experiments and the EPR tests revealed that both SO4˙- and ·OH participated in degrading PRO, with SO4˙- playing a dominant role. Higher PS concentration and neutral pH favored PRO degradation. The impact of Cl- and HCO3 - were concentration-dependent. A lower concentration of Cl- and HCO3 - could accelerate PRO degradation, while the presence of HA showed inhibitory effects. Seven degradation products were recognized through LC/MS/MS analysis. Cleavage of ether bond, hydroxylation, and ring-opening of naphthol moiety are involved in the PRO's degradation pathway. Finally, the formation of disinfection byproducts (DBPs) before and after pre-treated by heat/PS was also evaluated. Compared with direct chlorination of PRO, the heat/PS pre-oxidation greatly impacted the DBPs formation. The higher PRO removal efficiency in natural water indicated the heat/PS process might be capable of treating PRO-containing water samples, however, its impacts on the downstream effect on DBPs formation should be also considered.

Two-phase anaerobic co-digestion of food waste and sewage sludge.

The feasibility and performance of food waste and sewage sludge co-digestion were investigated to gain insight into their resource utilization. In this study, two-phase anaerobic digestion (TPAD) was operated under a total solids mixing ratio of 1:1 and different sludge retention times (SRTs). Results show that an acidogenic reactor with a 5-day SRT obtained the highest acidification efficiency, and its acetic acid content was dominant. The organic removal rate of a methanogenic reactor (MR) with a 20-day SRT and its corresponding TPAD system with a 25-day SRT were both the highest among the MRs and TPAD systems. Volatile solids and total chemical oxygen demand average removal efficiencies of the TPAD system with a 25-day SRT reached 64.7 and 60.8%, respectively. The MR with a 30-day SRT obtained the minimum ratio of volatile fatty acid to alkalinity (0.12). The methane content generated from the different MRs fluctuated at around 70%. All of the above results can provide reference for future research.