Evaluation of long-term carbon sequestration of biochar in soil with biogeochemical field model.

Return of biomass-derived biochar (BC) into soil has been considered as one of the carbon sequestration (CS) methods. It is important to evaluate the long-term biochar CS potential by integrating the complex physical interferences and biochemical reactions in real soil. This study incorporated biochar into a biogeochemical field model and established a daily-resolution simulator to assess 5-, 50-, 500-year CS potential upon Soil-Biochar-Plant interaction. Through the scenario simulation of burying 7.5-75 t/ha BC-C in a 50 cm-depth rainfed cropland soil with corn planted, we found biochar could retain 483-557 kg C/t BC-C after 500 years' natural decomposition, although soil pedoturbation and plant erosion accelerated its mineralization. Moreover, biochar provided labile-C to compensate microbial decomposition and modified long-term soil climate, resulting in a decrease in soil organic carbon degradation of 44-265 kg C/t BC-C. Furthermore, biochar promoted plant photosynthetic performance by offering exogenous nutrients, equivalent to capturing 66-1039 kg C/t BC-C over 50 years. But biochar limited endogenous nutrient release and inhibited plant growth after exogenous nutrients exhausted, so total CS decreases yearly after reaching an upper limit (1030-1722 kg C/t BC-C). A total of 651-725 kg C/t BC-C could be sequestered after 500 years. And biochar is more potential in infertile and arid soils. Overall, this study indicates the necessity of taking the biogeochemical reactions into consideration to assess biochar long-term CS, and it further demonstrates biochar soil implementation is a prospective carbon-negative strategy.

Pyrolysis temperature-dependent carbon retention and stability of biochar with participation of calcium: Implications to carbon sequestration.

Converting biomass waste into biochar by slow pyrolysis with subsequent soil amendment is a prospective approach with multiple environmental benefits including soil contamination remediation, soil amelioration and carbon sequestration. This study selected cow manure as precursor to produce biochar under 300 °C, 400 °C, 500 °C and 600 °C, and a remarkable promotion of carbon (C) retention in biochar by incorporation of exogenous Ca was achieved at all investigated pyrolysis temperatures. The C retention was elevated from 49.2 to 68.3% of pristine biochars to 66.1-79.7% of Ca-composite biochars. It was interesting that extent of this improvement increased gradually with rising of pyrolysis temperature, i.e., doping Ca in biomass promoted pyrolytic C retention in biochar by 16.6%, 23.4%, 29.1% and 31.1% for 300 °C, 400 °C, 500 °C and 600 °C, respectively. Thermogravimetric-mass spectrometer (TG-MS) and X-ray photoelectron spectroscopy (XPS) showed that Ca catalyzed thermal-chemical reactions and simultaneously suppressed the release of small organic molecular substances (C2-C7) via physical blocking (CaO, CaCO3, and CaClOH) and chemical bonding (CO and OC-O). The catalyzation mainly occurred at 200-400 °C, while the suppression was more prominent at higher temperatures. Raman spectra and 2D FTIR analysis on biochar microstructure showed that presence of Ca had negative influence on carbon aromatization and thus weakened biochar's stability, while increasing pyrolysis temperature enhanced the stability of carbon structure. Finally, with integrating "C retention" during pyrolysis and "C stability" in biochar, the maximum C sequestration (56.3%) was achieved at 600 °C with the participation of Ca. The study highlights the importance of both Ca and pyrolysis temperature in enhancing biochar's capacity of sequestrating C.

Acoustic Emission Detection and Analysis Method for Health Status of Lithium Ion Batteries.

The health detection of lithium ion batteries plays an important role in improving the safety and reliability of lithium ion batteries. When lithium ion batteries are in operation, the generation of bubbles, the expansion of electrodes, and the formation of electrode cracks will produce stress waves, which can be collected and analyzed by acoustic emission technology. By building an acoustic emission measurement platform of lithium ion batteries and setting up a cycle experiment of lithium ion batteries, the stress wave signals of lithium ion batteries were analyzed, and two kinds of stress wave signals which could characterize the health of lithium ion batteries were obtained: a continuous acoustic emission signal and a pulse type acoustic emission signal. The experimental results showed that during the discharge process, the amplitude of the continuous acoustic emission signal decreased with the increase of the cycle times of batteries, which could be used to characterize performance degradation; there were more pulse type acoustic emission signals in the first cycle of batteries, less in the small number of cycles, and slowly increased in the large number of cycles, which was in line with the bathtub curve and could be used for aging monitoring. The research on the health of lithium ion batteries by acoustic emission technology provides a new idea and method for detecting the health lithium ion batteries.