Degradation and Recondensation of Metal Oxide Nanoparticles in Laminar Premixed Flames.

The behavior of technical nanoparticles at high temperatures was measured systematically to detect morphology changes under conditions relevant to the thermal treatment of end-of-life products containing engineered nanomaterials. The focus of this paper is on laboratory experiments, where we used a Bunsen-type burner to add titania and ceria particles to a laminar premixed flame. To evaluate the influence of temperature on particle size distributions, we used SMPS, ELPI and TEM analyses. To measure the temperature profile of the flame, we used coherent anti-Stokes Raman spectroscopy (CARS). The comprehensible data records show high temperatures by measurement and equilibrium calculation for different stoichiometries and argon admixtures. With this, we show that all technical metal oxide nanoparticle agglomerates investigated reform in flames at high temperatures. The originally large agglomerates of titania and ceria build very small nanoparticles (<10 nm/"peak 2") at starting temperatures of <2200 K and <1475 K, respectively (ceria: Tmelt = 2773 K, Tboil = 3873 K/titania: Tmelt = 2116 K, Tboil = 3245 K). Since the maximum flame temperatures are below the evaporation temperature of titania and ceria, enhanced vaporization of titania and ceria in the chemically reacting flame is assumed.

Surface defect measurement of ICF capsules under a limited depth of field.

A surface defect detection device based on null interferometric microscopy (NIM) enables the measurement of surface defects in inertial confinement fusion (ICF) capsules. However, the microscope objective with a large numerical aperture in NIM causes the depth of field (DOF) of the system to be shallow, limiting the field of view (FOV) of the measurement. To expand the measurement FOV, a reconstruction method for the defocused surface defects in the FOV is presented, the angular spectrum diffraction model from the surface to the tilted plane is established, and the phase recovery method of the defocused surface defects is proposed by the theory of angular spectrum diffraction. Both the simulated and experimental results show that the proposed method can achieve the phase recovery of the surface defects in the defocused state and expand the measurement FOV, which improves the measurement accuracy and efficiency of the surface defects of the ICF capsules.

Dynamic wavefront measurement with a point diffraction interferometer based on birefringence polarization beam splitting.

In this study, we proposed a point diffraction interferometer based on birefringence polarization beam splitting (BPBS-PDI) for transmission wavefront measurements. Using the polarization beam splitting property of birefringent crystals and a specially designed calcite crystal as a polarization beam splitter, two beams of linearly polarized light with orthogonal polarization directions and a small angular separation can be obtained to produce the reference and test beams with perpendicular polarization directions through a pinhole point diffraction plate. By introducing spatial synchronization phase-shifting technology, influencing factors such as environmental vibrations on the measurement results, are reduced. Subsequently, the birefringent crystal and system error calibration methods were studied. Finally, a BPBS-PDI experimental device was set up to obtain the wavefront distribution of the lens to be tested. The experimental results are consistent with those of the ZYGO interferometer, indicating that the BPBS-PDI wavefront measurement method can be used to measure a lens transmission wavefront with high accuracy.

Fiber-coupled ultraviolet planar laser-induced fluorescence for combustion diagnostics.

Multimode silica step-index optical fibers are examined for use in planar laser-induced fluorescence (PLIF) for combustion diagnostics using ultraviolet (UV) laser sources. The multimode step-index fibers are characterized at UV wavelengths by examining their energy damage thresholds and solarization performance. The beam quality achievable with large clad step-index multimode fibers is also studied. Emphasis is placed on simultaneously achieving high output energy and beam quality (low output M(2)). The use of multimode fibers to deliver UV pulses at 283 nm for PLIF measurements of OH radicals in a Hencken burner is demonstrated. The fiber delivery capability of UV light will benefit combustion diagnostics in hostile environments, such as augmentor and combustor rigs.