Well-Separated Photoinduced Charge Carriers on Hydrogen Production Using NiS2/TiO2 Nanocomposites.

Photocatalytic hydrogen production is a sustainable and greenhouse-gas-free method that requires an efficient and abundant photocatalyst, which minimizes energy consumption. Currently, interests in transition metal chalcogenide materials have been utilized in different applications due to their quantum confinement effect and low band gaps. In this study, different wt % of NiS2-embedded TiO2 nanocomposites were synthesized by a facile hydrothermal method and utilized for photocatalytic hydrogen production under extended solar irradiation. Among the materials studied, the highest amount (4.185 mmol g-1) of hydrogen production was observed with 15 wt % of the NiS2/TiO2 nanocomposite. The highest photocatalytic activity may be due to the well separation of photoinduced charge carriers on the catalyst, which was confirmed by the electrochemical studies. Thus, we believe that these photocatalysts are promising candidates for future applications.

Natural sensitizer extracted from Mussaenda erythrophylla for dye-sensitized solar cell.

In this study, a natural dye from the flowers of Mussaenda erythrophylla extracted separately in ethanol and de-ionized water was employed as a photosensitizer in DSSCs. The quantitative phytochemical analyses were performed on both extracts. The existence of flavonoids (anthocyanin) and chlorophyll a pigments in the ethanol extract of the dye was confirmed by the UV-Visible spectroscopy. The stability study performed on the said ethanol extract confirmed that the dye extracted in ethanol was stable in the dark and did not degrade for nearly 50 days. The presence of the dye molecules and uniform adsorption of them on the P25-TiO2 surface were confirmed by fourier transform infrared spectroscopy and atomic force microscopy, respectively. Moreover, the influence of dye concentration and pH on the optical properties of the dye was also studied. The natural dye extracted in ethanol was employed in DSSCs, fabricated by utilizing the said dye sensitized P25-TiO2 photoanodes, [Formula: see text]/[Formula: see text] electrolyte, and Pt counter electrode. Photovoltaic performances of the fabricated devices were determined under simulated irradiation with the intensity of 100 mWcm-2 using AM 1.5 filter. The device fabricated with the P25-TiO2 photoanode sensitized by the dye extracted in ethanol at pH = 5 exhibited the best power conversion efficiency (PCE) of 0.41% with the JSC of 0.98 mAcm-2 which could be attributed to the optimum light absorption in the visible region of solar spectrum by the chlorophyll a and anthocyanin molecules in the extracted natural dye.

Potential transition and post-transition metal sulfides as efficient electrodes for energy storage applications: review.

Electrochemical energy storage has attracted much attention due to the common recognition of sustainable energy development. Transition metal sulfides and post-transition metal sulfides have been intensively been focused on due to their potential as electrode materials for energy storage applications in different types of capacitors such as supercapacitors and pseudocapacitors, which have high power density and long cycle life. Herein, the physicochemical properties of transition and post-transition metal sulfides, their typical synthesis, structural characterization, and electrochemical energy storage applications are reviewed. Various perspectives on the design and fabrication of transition and post-transition metal sulfides-based electrode materials having capacitive applications are discussed. This review further discusses various strategies to develop transition and/or post-transition metal sulfide heterostructured electrode-based self-powered photocapacitors with high energy storage efficiencies.

TiO2 as a Photocatalyst for Water Splitting-An Experimental and Theoretical Review.

Hydrogen produced from water using photocatalysts driven by sunlight is a sustainable way to overcome the intermittency issues of solar power and provide a green alternative to fossil fuels. TiO2 has been used as a photocatalyst since the 1970s due to its low cost, earth abundance, and stability. There has been a wide range of research activities in order to enhance the use of TiO2 as a photocatalyst using dopants, modifying the surface, or depositing noble metals. However, the issues such as wide bandgap, high electron-hole recombination time, and a large overpotential for the hydrogen evolution reaction (HER) persist as a challenge. Here, we review state-of-the-art experimental and theoretical research on TiO2 based photocatalysts and identify challenges that have to be focused on to drive the field further. We conclude with a discussion of four challenges for TiO2 photocatalysts-non-standardized presentation of results, bandgap in the ultraviolet (UV) region, lack of collaboration between experimental and theoretical work, and lack of large/small scale production facilities. We also highlight the importance of combining computational modeling with experimental work to make further advances in this exciting field.